New seven- and eight-membered cyclic alkoxyamines for the living free radical polymerization

Macromolecules

Volumn 36, Issue 9, 2003, Pages 3078-3084

  Schulte, Tobias ^a   Studer, Armido ^a  

^a PHILIPPS UNIVERSITY MARBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

BUTYL ACRYLATE; CYCLIC ALKOXYAMINES; DIAZOMETHANE; LIVING FREE RADICAL POLYMERIZATION; NITROXIDES;

CHEMICAL BONDS; ELECTRON SPIN RESONANCE SPECTROSCOPY; FREE RADICAL POLYMERIZATION; INITIATORS (CHEMICAL); LIVING POLYMERIZATION; MASS SPECTROMETRY; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PYROLYSIS; RATE CONSTANTS; STYRENE; SYNTHESIS (CHEMICAL);

AMINES;

EID: 0038780533     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma025806t     Document Type: Article

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40. We also studied the thermal stability of the free nitroxides 10 and 14 in t-BuPh (0.06 mM) at 407 K using EPR spectroscopy. Experiments were stopped after 3 h. No decomposition was observed (within the error limits of the integration of the EPR signals) during that time. The t-BuPh solution of nitroxide 10 (0.06 mM) was further heated at 393 K for 9 days. EPR analysis revealed that still 5% of the nitroxide is present in the solution after 9 days, proving the high thermal stability of 10.