Decelerating effect of alkenes in the oxidative addition of phenyl iodide to palladium(0) complexes in heck reactions

Organometallics

Volumn 21, Issue 21, 2002, Pages 4540-4545

  Amatore, Christian ^a   Carré, Emmanuelle ^a   Jutand, Anny ^a   Medjour, Youcef ^a  

^a ECOLE NORMALE SUPÉRIEURE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CYCLIC VOLTAMMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLEFINS; OXIDATION; PALLADIUM COMPOUNDS; PHASE EQUILIBRIA; RATE CONSTANTS; REGRESSION ANALYSIS; STOICHIOMETRY;

OXIDATIVE ADDITION;

ORGANOMETALLICS;

EID: 0038488809     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020439v     Document Type: Article

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21. 3. Since this simplifies greatly the presentation of the kinetics analysis given here, without introducing any significant bias in the kinetic treatment of the experimental data (see above), this simplification was used everywhere in the presentation of this paper.
22. Due to the complexity of the kinetics laws in the presence of styrene, we use eq 11 but we consider a constant value of [L] in its integration (see note in ref 9). In eq 12, the value of [L] is thus considered as constant and equal to its average value of 2.6 mM over the reaction (see note in ref 9).
23. 8b
24. 0 complexes ligated by methyl acrylate, see also ref 5.
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26. 2d
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