Mechanism of the Stille reaction. 1. The transmetalation step. Coupling of R1I and R2SnBu3 catalyzed by trans-[PdR1IL2] (R1 = C6Cl2F3; R2 = vinyl, 4-methoxyphenyl; L = AsPh3)

Journal of the American Chemical Society

Volumn 120, Issue 35, 1998, Pages 8978-8985

  Casado, Arturo L ^a   Espinet, Pablo ^a  

^a UNIVERSITY OF VALLADOLID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

PALLADIUM;

ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; ISOMERISM; OXIDATION; SYNTHESIS;

EID: 0032500354     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9742388     Document Type: Article

References (10)

1. (a) Stanforth, S. P. Tetrahedron 1998, 54, 263-303.
2. (b) Farina, V.; Roth, G. P. Adv. Metalorg. Chem. 1996, 5, 1 -53.
3. (c) Curran, D. P.; Hoshino, M. J. Org. Chem. 1996, 61, 6480-6481.
4. (d) Mateo, C.; Cárdenas, D. J.; Fernández-Rivas, C.; Echavarren, A. M. Chem. Eur. J. 1996, 2, 1596-1606.
5. (e) Roth, G. P.; Farina, V.; Liebeskind, L. S.; Pena-Cabrera, E. Tetrahedron Lett. 1995, 36, 2191-2194.
6. (f) Mitchell, T. N. Synthesis 1992, 803-815.
7. (g) Scott, W. J.; Stille, J. K. J. Am. Chem. Soc. 1986, 108, 3033-3040.
8. (h) Stille, J. K. Angew. Chem., Int. Ed. Engl. 1986, 25, 508-524.
9. (i) Beletskaya, I. P. J. Organomet. Chem. 1983, 250, 551-564.
10. Lee, A. S.-Y.; Dai, W.-C. Tetrahedron 1997, 53, 859-868, and references therein.