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Macrocyclizations of organic compounds with two terminal 1,3-diynes are somewhat more germane to the new reactions presented herein. Although these are less common, there are many examples. For a recent report, see: M. A. Heuft, S. K. Collins, G. P. A. Yap, A. G. Fallis, Org. Lett. 2001, 3, 2883-2886.
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2] species has also been studied by cyclic voltammetry: K.-T. Wong, J.-M. Lehn, S-M. Peng, G.-H. Lee, Chem. Commun. 2000, 2259-2260.
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85163236751
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48
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85163241011
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-
note
-
13C NMR signals in this study.
-
-
-
-
49
-
-
85163239485
-
-
note
-
+ ions represent the most intense peak in the isotope envelope.
-
-
-
-
50
-
-
85163238673
-
-
note
-
The assignments follow from coupling constant and chemical shift patterns established earlier.
-
-
-
-
51
-
-
85163237440
-
-
note
-
These signals are for the major and minor rotamers, respectively.
-
-
-
-
52
-
-
85163240547
-
-
note
-
A correct microanalysis was not obtained for this compound.
-
-
-
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