Mangnetically induced large mesoporous single-domain monoliths using a mineral liquid crystal as a template

Advanced Functional Materials

Volumn 13, Issue 5, 2003, Pages 377-381

  Camerel, Franck ^a,b   Gabriel, Jean Christophe P ^a   Batail, Patrick ^a  

^a CNRS   (France)

^b Nanomix Inc   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHROMOPHORES; ENERGY DISPERSIVE SPECTROSCOPY; FLUORESCENCE; MAGNETIC ANISOTROPY; MESOPOROUS MATERIALS; METALLIC MATRIX COMPOSITES; MICELLES; POROUS SILICON; SURFACE ACTIVE AGENTS; VANADIUM COMPOUNDS;

PRECURSORS;

NEMATIC LIQUID CRYSTALS;

EID: 0038136966     PISSN: 1616301X     EISSN: None     Source Type: Journal    
DOI: 10.1002/adfm.200304274     Document Type: Article

References (63)

1. C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli, J. S. Beck, Nature 1992, 359, 710.
2. a) F. Schuth, W. Schmidt, Adv. Mater.2002, 14, 629.
3. b) A. Davidson, Curr. Opin. Colloid Interface Sci. 2002, 7, 92.
4. c) B. J. Scott, G. Wirnsberger, G. D. Stucky, Chem. Mater 2001, 13, 3140.
5. d) A. Corma, Chem. Rev. 1997, 97, 2373.
6. T. J. Barton, L. M. Bull, W. G. Klemperer, D. A. Loy, B. MCEnaney, M. Misono, P. A. Monson, G. Pez, G. W. Scherer, J. C. Vartuli, O. M. Yaghi, Chem. Mater. 1999, 11, 2633.
7. a) P. Davidson, P. Batail, J.-C. P. Gabriel, J. Livage, C. Sanchez, C. Bourgaux, Prog. Polym. Sci. 1997, 22, 913.
8. b) J.-C. P. Gabriel, P. Davidson, Adv. Mater. 2000, 12, 9.
9. c) J.-C. Gabriel, P. Davidson, Top. Curr. Chem. 2003, 226, 119.
10. F. Camerel, J.-C. P. Gabriel, P. Batail, Chem. Commun. 2002, 17, 1926.
11. a) S. H. Tolbert, A. Firouzi, G. D. Stucky, B. F. Chmelka, Science 1997, 278, 264.
12. b) A. Firouzi, D. J. Schaefer, S. H. Tolbert, G. D. Stucky, B. F. Chmelka, J. Am. Chem. Soc. 1997, 119, 9466.
13. c) M. Templin, A. Franck, A. Du Chesne, H. Leist, Y. Zhang, R. Ulrich, V. Schädler, U. Wiesner, Science 1997, 275, 1795.
14. d) M. E. Raimondi, T. Maschmeyer, R. H. Templer, J. M. Seddon, Chem. Commun. 1997, 1843.
15. e) C. Göltner, S. Henke, M. C. Weissenberger, M. Antonietti, Angew. Chem. Int. Ed. 1998, 37, 613.
16. a) S. Schacht, O. Huo, I. G. Voigt-Martin, G. D. Stucky, F. Schüth, Science 1996, 273, 766.
17. b) H. Yang, A. Kuperman, N. Coombs, S. Mamiche-Afara. G. Ozin, Nature 1996, 379, 703.
18. c) Y. Lu, R. Ganguli, C. A. Drewlen, M. T. Anderson, C. J. Brinker, W. Gong, Y. Guo, H. Soyez, B. Dunn, M. H. Huang, J. I. Zink, Nature 1997, 389, 364.
19. d) G. S. Attard, P. N. Bartlett,N. R. B. Coleman, J. M. Elliott, J. R. Owen, I H. Wang. Science 1997, 278, 838.
20. P. Yang, D. Zhao, B. F. Chmelka, G. D. Stucky, Chem. Mater. 1998, 10.2033.
21. Y. Lu, H. Fan, A. Stump, T. L. Ward, T. Rieker, J. Brinker, Nature 1999, 598, 223.
22. a) N. A. Melosh, P. Davidson, B. F. Chmelka, J. Am. Chem. Soc. 2000, 122, 823.
23. b) R. Ryoo, C. H. Ko, S. J. Cho, J. M. Kim, J. Phys. Chem. B 1997, 707. 10610.
24. c) N. A. Melosh, P. Davidson, P. Feng, D. J. Pine, B. F. Chmelka, J. Am. Chem. Soc. 2001, 123, 1240.
25. P. Davidson, C. Bourgaux, L. Sohoutteten, P. Sergot, C. Williams, J. Livage, J. Phys. II 1995, 5, 1577.
26. 3 groups under electric field: G. Cerveau, R. J. P. Corriu, E. Framery, S. Ghosh, M. Nobili. Angew. Chem. Int. Ed. 2002, 41, 594.
27. 5 xerogels in film form: C. A. Brunello, C. F. O. Graeff, J. Non-Cryst. Solids 2002, 304, 265.
28. J. Livage, Chem. Mater. 1991, 3, 578.
29. a) B. V. Deryagin, L. Landau, Acta Physicochim, URSS 1941, 333, 55.
30. b) E. J. W. Verwey, J. T. G. Overbeek. Theory of the Stability of Lyophobic Colloids, Elsevier, Amsterdam 1948.
31. O. Pelletier, C. Bourgaux, O. Diat, P. Davidson, J. Livage. Eur. Phys. J. E 2000, 2, 191.
32. O. Pelletier, P. Davidson, C. Bourgaux, C. Coulon, S. Regnault, J. Livage Langmuir 2000, 75, 5295.
33. TMOS is widely used for the preparation of mesoporous silica in the presence of lyotropic organic mesophases of neutral or charged surfactants or block copolymers: K. C. Chen, T. Tsuchiya, J. D. Mackenzie, J. Non-Cryst. Solids 1986, 81, 227.
34. 5, is colorless and isotropic when observed under cross polarizers.
35. a) C. Sanchez, J. Livage, G. Lucazeau, J. Raman Spectrosc. 1982, 12, 68.
36. b) M. T. Vandenborre, R. Prost. E. Huard, J. Livage, Mater, Res. Bull 1983, 75, 1133.
37. c) L. Abello, G. Lucazeau, J. Chem. Phys. 1984. 81, 539.
38. d) L. Abello, E. Husson, Y. Repelin, G. Lucazeau, J. Solid State Chem. 1985, 56, 379.
39. P. Aldebert, N. Baffler, N. Gharbi, J. Livage, Mater. Res. Bull. 1981, 16, 669.
40. a) X. Commeinhes, P. Davidson, C. Bourgaux, J. Livage, Adv. Mater. 1997, 9, 900.
41. b) Note that similar results have also been obtained using an electric field: S. Lamarque-Forget, O. Pelletier, I. Dozov, P. Davidson, P. Martinot-Lagarde, J. Livage, Adv. Mater. 2000, 72, 1267.
42. Macroscopic single domains of mineral liquid crystals have also been obtained in the case of aqueous suspensions of clays, phosphatoantimonic acid, and goethite: a) J.-C. P. Gabriel, C. Sanchez, P. Davidson. J. Phys. Chem. 1996, 100, 11139.
43. b) B. J. Lemaire, P. Panine, J.-C. P. Gabriel, P. Davidson, Europhys. Lett. 2002, 59, 55.
44. c) J.-C. P. Gabriel, F. Camerel, P. Batail, P. Davidson, B. Lemaire, H. Desvaux, Nature 2001, 413, 504.
45. d) B. J. Lemaire, P. Davidson, J. Ferre, J. P. Jamet, P. Panine, I. Dozov, J. P. Jolivet, Phys. Rev. Lett. 2002, 8812, U185.
46. S = 0 for an Isotropic suspension and S = 1 for a perfectly aligned nematic phase.
47. a) A. Firouzi, D. J. Schaefer, S. H. Tolbert, G. D. Stucky, B. F. Chmelka, J. Am. Chem. Soc. 1997, 119, 9466.
48. b) S. H. Tolbert, A. Firouzi, G. D. Stucky, B. F. Chmelka, Science 1997, 278, 264.
49. a) A. Guinier, G. Fournet, Small Angle Scattering of X-rays, Wiley, New York 1955.
50. b) P. Lindner, T. Zemb, Neutron, X-rays and Light Scattering: Introduction to an Investigative Tool for Colloidal and Polymeric Systems, North-Holland, Amsterdam 1991.
51. c) J. S. Pedersen, Adv. Colloid Interface Sci. 1997, 70, 171.
52. a) P. Davidson, D. Petermann, A. M. Levelut, J. Phys. II 1995, 5, 113.
53. b) P. Davidson, C. Bourgaux, P. Sergot, J. Livage, J. Appl. Crystallogr. 1997, 30, 727.
54. This observation is also compatible with a 90° rotation of the director. However, this is very unlikely since it would imply major reorganization of the framework. Also, no change of orientation of the director has ever been observed, even on samples in which the ribbons were only partially removed.
55. 5, presents only a microporous specific surface area before or after treatment in neutral or basic NaOH aqueous solutions.
56. Lots of efforts have been put in trying to directly observe the pores by transmission electron microscopy (TEM). These efforts were hindered by the lack of positional order of the pores, which is intrinsic to the nematic order. In that respect, these samples are different from usual mesoporous materials which show good positional as well as orientational ordering.
57. a) S. H. Tolbert, T. E. Schaffer, J. L. Feng, P. K. Hansma, G. D. Stucky, Chem. Mater. 1997, 9, 1962.
58. b) D. Grosso, F. Babonneau, P. A. Albouy, H. Amenitsch, A. R. Balkenende, A. Brunet-Bruneau, J. Rivory, Chem. Mater. 2002, 14, 931.
59. G. S. Attard, J. C. Glyde, C. G. Göltner, Nature 1995, 378, 366.
60. M. Imperor-Clerc, P. Davidson, Eur. Phys. J. B 1999, 19, 93.
61. J. M. Dubuisson, J. M. Dauvergne, C. Depautex, P. Vachette, C. E. Williams, Nucl. Instrum. Methods Phys. Res. 1986, A246, 636.
62. S. Brunauer, P. H. Emmett, E. Teller, J. Am. Chem. Soc. 1938, 60, 309.
63. E. P. Barren, L. G. Joyner, P. H. Halenda, J. Am. Chem. Soc. 1951, 73, 373.