A New Phase of Oriented Mesoporous Silicate Thin Films

Chemistry of Materials

Volumn 9, Issue 9, 1997, Pages 1962-1967

  Tolbert, Sarah H ^a,b   Schäffer, Tilman E ^a   Feng, Jianglin ^a   Hansma, Paul K ^a   Stucky, Galen D ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000743737     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm960454o     Document Type: Article

References (25)

1. (1) Kresge, C. T.; Leonowitz, M. E.; Roth, W. J.; Vartuli, J. C.; Beck, J. S. Nature 1992, 359, 710. Beck, J. S.; Vartuli, J. C.; Roth, W. J.; Leonowicz, M. E.; Kresge, C. T.; Schmitt, K. T.; Chu, C. T.-W.; Olson, D. H.; Sheppard, E. W.; McCullen, S. B.; Higggins, J. B.; Schlenker, J. L. J. Am. Chem. Soc. 1992, 114, 10834.
2. Kresge, C. T.; Leonowitz, M. E.; Roth, W. J.; Vartuli, J. C.; Beck, J. S. Nature 1992, 359, 710. Beck, J. S.; Vartuli, J. C.; Roth, W. J.; Leonowicz, M. E.; Kresge, C. T.; Schmitt, K. T.; Chu, C. T.-W.; Olson, D. H.; Sheppard, E. W.; McCullen, S. B.; Higggins, J. B.; Schlenker, J. L. J. Am. Chem. Soc. 1992, 114, 10834.
3. Firouzi, A.; Kumar, D.; Bull, L. M.; Besier, T.; Sieger, P.; Huo, Q.; Walker, S. A.; Zasadzinski, J. A.; Glinka, C.; Nicol, J.; Margolese, D.; Stucky, G. D.; Chmelka, B. F. Science 1995, 267, 1138.
4. Huo, Q.; Margolese, D. I.; Stucky, G. D. Chem. Mater. 1996, 8, 1147.
5. Bein, T. Chem. Mater. 1996, 8, 1636.
6. Yang, H.; Kuperman, A.; Coombs, N.; Mamiche-Afara, S.; Ozin, G. A. Nature 1996, 379, 703.
7. Yang, H.; Coombs, N.; Sakolov, I.; Ozin, G. A. Nature 1996, 381, 589.
8. Aksay, I. A.; Trau, M.; Manne, S.; Honma, I.; Yao, N.; Zhou, L.; Fenter P.; Eisenberger, P. M.; Gruner, S. M. Science 1996, 273, 892.
9. Huo, Q.; Leon, R.; Petroff, P. M.; Stucky, G. D. Science 1995, 268, 1324.
10. (9) Zana, R.; Benrraou, M.; Rueff, R. Langmuir 1991, 7, 1072. Zana, R.; Talmon, Y. Nature 1993, 362, 228.
11. Zana, R.; Benrraou, M.; Rueff, R. Langmuir 1991, 7, 1072. Zana, R.; Talmon, Y. Nature 1993, 362, 228.
12. Huo, Q.; Margolese, D. I.; Ciesla, U.; Feng, P.; Gier, T. E.; Sieger, P.; Leon, R.; Petroff, P. M.; Schüth, F.; Stucky, G. D. Nature 1994, 368, 317.
13. Huo, Q.; Margolese, D. I.; Ciesla, U.; Demuth, D. G.; Feng, P.; Gier, T. E.; Sieger, P.; Firouzi, A.; Chmelka, B. F.; Schüth, F.; Stucky, G. D. Chem. Mater. 1994, 6, 1179.
14. Attard, G. S.; Glyde, J. C.; Göltner, C. G. Nature 1995, 378, 366.
15. (13) Schacht, S.; Huo, Q.; Voigt-Martin, I. G.; Stucky, G. D.; Schüth, F. Science 1996, 273, 768. Huo, Q. S.; Zhao, O.; Feng, J. L.; Weston, K.; Buratto, S.; Stucky, G. D.; Schact, S.; Schüth, F. Adv. Mater., in press.
16. Schacht, S.; Huo, Q.; Voigt-Martin, I. G.; Stucky, G. D.; Schüth, F. Science 1996, 273, 768. Huo, Q. S.; Zhao, O.; Feng, J. L.; Weston, K.; Buratto, S.; Stucky, G. D.; Schact, S.; Schüth, F. Adv. Mater., in press.
17. Digital Instruments, Santa Barbara, CA.
18. A very faint (004) diffraction peak can be observed in some samples. This peak is too weak to be seen in the bulk material, however.
19. The (0111) diffraction peak in the four index hexagonal notation is equivalent to the (101) diffraction peak in three hexagonal index notation shown in Figure 1.
20. Manne, S.; Schäffer, T. E.; Huo, Q.; Hansma, P. K.; Morse, D. E.; Aksay, I. A.; Stucky, G. D., submitted.
21. Tolbert, S. H.; Schäffer, T. E., unpublished results.
22. (19) Manne, S.; Cleveland, J. P.; Gaub, H. E.; Stucky, G. D.; Hansma, P. K. Langmuir 1994, 10, 4409. Manne, S.; Gaub, H. E. Science 1995, 270, 1480.
23. Manne, S.; Cleveland, J. P.; Gaub, H. E.; Stucky, G. D.; Hansma, P. K. Langmuir 1994, 10, 4409. Manne, S.; Gaub, H. E. Science 1995, 270, 1480.
24. 10 has been reported as a silicate/surfactant composite, and this phase does not have the correct symmetry to nucleate on a hexagonally close packed monolayer of spherical micelles. If it could be made as a silicate/surfactant composite, a cubic phase such as the Fm3m could nucleate from a surfactant layer like that shown in Figure 4.
25. Clerc, M. J. Phys. II France 1996, 6, 961.