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In fact, by using 1,4-benzenedicarboxylic acid (terephtalic acid, TPA), a molecule with two carboxylic groups at para positions, exactly the same MOCN structures can be fabricated, which proves that the side group does not play a significant role in the MOCN formation.
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This difference is attributed to the effective loss of Fe atoms in other surface chemical processes, that is, the entire amount of deposited Fe is not employed in coordination network formation. Decoration of substrate step edges, and in particular Fe island formation are frequently suggested from inspection of STM topographs. In addition, a small percentage of the Fe atoms might be lost in substrate atom-exchange processes.
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