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14
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0038551828
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note
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2 and 3 equiv of PN, which had been heated at 60 °C for 24 h. See the Supporting Information for more details.
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17
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37049077710
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H-Pt = 1272 Hz): Crespo, M.; Sales, J.; Solans, X.; Altaba, M. F. J. Chem. Soc., Dalton Trans. 1988, 1617.
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18
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0038551829
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note
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w = 0.060.
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19
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0038213011
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note
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The average of three measurements for mixtures containing different concentrations of 1 and PN.
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22
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0038213010
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note
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The dependence of the rate of the disappearance of 1 on [PN] may be similar for two kinetic schemes; one involves a rapid preequilibrium for dissociation of PN from 1 to form 4 followed by slow C-H oxidative addition, and the other, steady-state formation of 4. No discrimination is possible at the moment.
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23
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11744326498
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