Carboxylation of acetophenone with zinc(II) alkoxides/CO2 systems: A mechanistic study

European Journal of Inorganic Chemistry

Volumn , Issue 8, 2000, Pages 1803-1809

  Kunert, Michael ^a   Bräuer, Michael ^a   Klobes, Olaf ^b   Görls, Helmar ^a   Dinjus, Eckhard ^b   Anders, Ernst ^a  

^a FRIEDRICH SCHILLER UNIVERSITY JENA   (Germany)

^b KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

Author keywords

Ab initio calculations; Carbon dioxide fixation; Carboxylato complexes; CH acidic substrates; Zinc

Indexed keywords

CARBOXYLATION; DIMERS; KETONES; MONOMERS; REACTION INTERMEDIATES; ZINC COMPOUNDS;

AB INITIO CALCULATIONS; ACETOPHENONES; ACIDIC SUBSTRATES; ALKOXIDES; CARBON DIOXIDE FIXATION; CARBOXYLATO; CARBOXYLATO COMPLEX; CH-ACIDIC SUBSTRATE; MECHANISTIC STUDIES; ZINC;

CARBON DIOXIDE;

ACETOPHENONE; CARBON DIOXIDE; OXIDE; ZINC;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CARBOXYLATION; CHEMICAL BOND; COMPLEX FORMATION; CRYSTAL STRUCTURE; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; TEMPERATURE;

EID: 0037611369     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200008)2000:8<1803::aid-ejic1803>3.3.co;2-c     Document Type: Article

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51. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary puplication no. CCDC-136058 and CCDC-136059. Copies of the data can be obtained free of Charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK [Fax: (internat.)+44-1223/336.033; E-mail:deposit@ccdc.cam.ac.uk].
52. E. Burtscher, H. Bider, R. Concin, O. Bobleter, J. Chrom. 1982, 252, 167-175.