Phosphine Adducts of Monomeric Zinc(bis-phenoxides): Solution and Solid-State Structures of (2,6-Di-tert-butylphenoxide)ZnL Complexes (L = PMePh2 and PCy3)

Inorganic Chemistry

Volumn 37, Issue 12, 1998, Pages 2852-2853

  Darensbourg, Donald J ^a   Zimmer, Marc S ^a   Rainey, Patrick ^a   Larkins, David L ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000514596     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic980185z     Document Type: Article

References (21)

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3. Darensbourg, D. J.; Holtcamp, M. W.; Struck, G. E.; Zimmer, M. S.; Niezgoda, S. A.; Rainey, P.; Robertson, J. B.; Draper, J. D.; Reibenspies, J. H. To be submitted for publication.
4. Darensbourg, D. J.; Holtcamp, M. W.; Khandelwal, B.; Klausmeyer, K. K.; Reibenspies, J. H. J. Am. Chem. Soc. 1995, 117, 538.
5. Darensbourg, D. J.; Niezgoda, S. A.; Holtcamp, M. W.; Draper, J. D.; Reibenspies, J. H. Inorg. Chem. 1997, 36, 2426.
6. Nevertheless, the binding of these various oxygen donor bases is dependent upon the nature of the substituents on the phenoxide ligands.
7. (a) Goel, R. G.; Henry, W. P.; Jha, N. K. Inorg. Chem. 1982, 21, 2551
8. (b) Goel, R. G.; Ogini, W. O. Inorg. Chem. 1977, 16, 1968.
9. Bricklebank, N.; Godfrey, S. M.; McAuliffe, C. A.; Mackie, A. G.; Pritchard, R. G. J. Chem, Soc., Chem. Commun. 1992, 944.
10. Bochmann, M.; Bwembya, G. C.; Grinter, R.; Powell, A. K.; Webb, K. J.; Hursthouse, M. B.; Abdul Malik, K. M.; Mazid, M. A. Inorg. Chem. 1994, 33, 2290.
11. Zeng, D.; Hampden-Smith, M. J.; Alam, T. M.; Rheingold, A. L. Polyhedron 1994, 13, 2715.
12. 3).
13. 7a has suggested that zinc complexes actually catalyze aerobic oxidation of phosphines.
14. w = 0.1856.
15. w = 0.2087.
16. Niezgoda, S. A. Ph.D. Dissertation, Texas A&M University, 1997.
17. Tolman, C. Chem. Rev. 1977, 77, 313.
18. Drago, R. S. Organometallics 1995, 14, 3408.
19. 3, respectively.
20. -1 at 298 K for complexes 1 and 2, respectively.
21. 3 in deuterated toluene was observed at -62.3 ppm.