Electron radiation damage of MCM-41 and related materials

Microscopy and Microanalysis

Volumn 9, Issue 3, 2003, Pages 245-263

  Blanford, Christopher F ^a,c   Carter, C Barry ^b  

^a University of Minnesota   (United States)

^b UNIVERSITY OF MINNESOTA   (United States)

^c UNIVERSITY OF OXFORD   (United Kingdom)

Author keywords

Beam damage; Electron radiation; M41S; MCM 41; Mesoporous; Silicate; TEM

Indexed keywords

SILICATE; SURFACTANT;

ARTICLE; CATALYSIS; CHEMISTRY; COMPARATIVE STUDY; CONFORMATION; ELECTRON; ELECTRON MICROSCOPY; MATHEMATICS; POROSITY; RADIATION EXPOSURE;

CATALYSIS; ELECTRONS; MATHEMATICS; MICROSCOPY, ELECTRON; MOLECULAR CONFORMATION; POROSITY; SILICATES; SURFACE-ACTIVE AGENTS;

EID: 0037591373     PISSN: 14319276     EISSN: None     Source Type: Journal    
DOI: 10.1017/S1431927603030447     Document Type: Article

References (63)

1. ACOSTA, D.R., VÁSQUEZ-POLO, G., GARCIA, R. & CASTAÑO, V.M. (1993). Electron beam degradation of Ca-A zeolite. Radiat Eff Defects S 127, 37-43.
2. ALFREDSSON, V., KEUNG, M., MONNIER, A., STUCKY, G.D., UNGER, K.K. & SCHÜTH, F. (1994). High-resolution transmission electron microscopy of mesoporous MCM-41 type materials. J Chem Soc Chem Commun 8, 921-922.
3. ARMISTEAD, C.G. & HOCKEY, J.A. (1967). Reactions of chloromethyl silanes with hydrated Aerosil silicas. Trans Faraday Soc 63, 2549-2556.
4. ARONSON, B.J., BLANFORD, C.F. & STEIN, A. (1997). Solution-phase grafting of titanium dioxide onto the pore surface of mesoporous silicates: Synthesis and structural characterization. Chem Mater 9, 2842-2851.
5. BATSANOV, S.S. (1968). The concept of electronegativity. Conclusions and prospects. Russ Chem Rev 37, 332-351.
6. BECK, J.S. (1991). Method for synthesizing mesoporous crystalline material. U.S. Patent: 5,057,296, Mobil Oil Corp., Fairfax, VA.
7. BECK, J.S. & VARTULI, J.C. (1996). Recent advances in the synthesis, characterization and applications of mesoporous molecular sieves. Curr Opin Solid State Mater Sci 1, 76-87.
8. BECK, J.S., VARTULI, J.C., KENNEDY, G.J., KRESGE, C.T., ROTH, W.J. & SCHRAMM, S.E. (1994). Molecular or supramolecular templating - Defining the role of surfactant chemistry in the formation of microporous and mesoporous molecular sieves. Chem Mater 6, 1816-1821.
9. BECK, J.S., VARTULI, J.C., ROTH, W.J., LEONOWICZ, M.E., KRESGE, C.T., SCHMITT, K.D., CHU, C.T.-W., OLSON, D.H., SHEPPARB, E.W., MCCULLEN, S.B., HIGGINS, J.B. & SCHLENKER, J.L. (1992). A new family of mesoporous molecular sieves prepared with liquid crystal templates. J Am Chem Soc 114, 10834-10843.
10. BLANFORD, C.F., ARONSON, B.J., MCKERNAN, S., STEIN, A. & CARTER, C.B. (1997). The study of Ti-MCM-41 by transmission electron microscopy. Microsc Microanal 3 (suppl. 2), 1005-1006.
11. BLANFORD, C.F., BENTLEY, J., STEIN, A. & CARTER, C.B. (1998). An investigation into beam damage of mesoporous materials. Microsc Microanal 4(Suppl. 2), 712-713.
12. BONNEVIOT, L., BÉLAND, F., DANUMAH, C., GIASSON, S., KALIAGUINE, S. (EDs.). (1998). Mesoporous Molecular Sieves 1998, Vol. 117. Series title: Studies in Surface Science and Catalysis. New York: Elsevier.
13. BURSILL, L.A., LODGE, E.A. & THOMAS, J.M. (1980). Zeolitic structures as revealed by high-resolution electron microscopy. Nature 286, 111-113.
14. BURSILL, L.A., THOMAS, J.M. & RAO, K.J. (1981). Stability of zeolites under electron irradiation and imaging of heavy cations in silicates. Nature 289, 157-158.
15. CARTER, C.B. & KOHLSTEDT, D.L. (1981). Electron irradiation damage in natural quartz grains. Phys Chem Miner 7, 110-116.
16. CHAO, K.J., WU, C.N., CHANG, A.S. & HU, S.F. (1999). The study of MCM-41 molecular sieves by energy-filtering TEM. Micropor Mesopor Mater 27, 287-295.
17. CHON, H., IHM, S.-K. & UH, Y.S. (EDS.). (1997). Progress in Zeolite and Microporous Materials, Vol. 105A. Series title: Studies in Surface Science and Catalysis. New York: Elsevier.
18. CIESLA, U. & SCRÜTH, F. (1999). Ordered mesoporous materials. Micropor Mesopor Mater 27, 131-149.
19. CORMA, A., KAN, Q., NAVARRO, M.T., PÉREZ-PARIENTE, J. & REY, F. (1997). Synthesis of MCM-41 with different pore diameters without addition of auxiliary organics. Chem Mater 9, 2123-2126.
20. CORMA, A., MELO, F.V., MENDIOROZ, S. & FIERRO, J.L.G. (EDS.). (2000). 12th International Congress on Catalysis, Vol. 130C. New York: Elsevier.
21. CSENCSITS, R. & GRONSKY, R. (1987). Damage of zeolite Y in the TEM and its effects on TEM images. Ultramicroscopy 23, 421-432.
22. CURTHOYS, G., DAVYDOV, V., KISELEV, A.V., KISELEV, S.A., KUZNETSOV, B.V. (1974). Hydrogen bonding in adsorption on silica. J Colloid Interf Sci 48, 58-72.
23. DAS, G. & MITCHELL, T.E. (1974). Electron irradiation damage in quartz. Radiat Eff 23, 49-52.
24. DENATALE, J.F. & HOWITT, D.G. (1984). A mechanism for radiation damage in silicate glasses. Nucl Instrum Methods Phys Res B 229, 489-497.
25. FENG, J., HUO, Q., PETROFF, P.M. & STUCKY, G.D. (1997). Morphology definition by disclinations and dislocations in a mesostructured silicate crystal. Appl Phys Lett 71, 620-622.
26. HOBBS, L. (1985). Radiation effects in the electron microscope. EMSA Bull 15, 51-63.
27. HOBBS, L.W. (1979). Radiation effect in analysis of inorganic specimens by TEM. In Introduction to Analytical Electron Microscopy, Hren, J.J., Goldstein, J. & Joy, D.C. (Eds.), pp. 437-480. New York: Plenum Press.
28. HOBBS, L.W. & PASCUCCI, M.R. (1980). Radiolysis and defect structure in electron-irradiated alpha-quartz. J Phys-Paris C 6, 237-242.
29. ILER, R.K. (1979). The Chemistry of Silica. New York: John Wiley and Sons.
30. INOKUTI, M., ITIKAWA, Y. & TURNER, J.E. (1978). Addenda: Inelastic collisions of fast charged particles with atoms and molecules - The Bethe theory revisited. [Rev Mod Phys 43, 297 (1971)] Rev Mod Phys 50(1, Pt. 1), 23-35.
31. INUI, H., MORI, H. & FUJITA, H. (1989). Electron irradiation-induced crystalline-amorphous transition in ceramics. Acta Metall 37, 1337-1342.
32. INUI, H., MORI, H., SAKATA, T. & FUJITA, H. (1990). Electron irradiation-induced crystalline-to-amorphous transition in quartz single crystals. J Non-Cryst Solids 116, 1-15.
33. KARGE, H.G. & WEITKAMP, J. (EDS.). (1995). Zeolite Science 1994: Recent Progress and Discussions. New York: Elsevier
34. KRESGE, C.T., LEONOWICZ, M.E., ROTH, W.J., VARTULI, J.C. & BECK, J.S. (1992). Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism. Nature 359, 710-712.
35. KRUK, M., JARONIEC, M., SAKAMOTO, Y., TERASAKI, O., RYOO, R. & KO, C.H. (2000a). Determination of pore size and pore wall structure of MCM-41 by nitrogen adsorption, transmission electron microscopy, and X-ray diffraction. J Phys Chem B 104, 292-301.
36. KRUK, M., JARONIEC, M. & SAYARI, A. (1999). A unified interpretation of high-temperature pore size expansion processes in MCM-41 mesoporous silicas. J Phys Chem B 103, 4590-4598.
37. KRUK, M., JARONIEC, M. & SAYARI, A. (2000b). New insights into pore-size expansion of mesoporous silicates using long-chain amines. Micropor Mesopor Mater 35-36, 545-553.
38. LIDE, D.R. (ED.). (1991). CRC Handbook of Chemistry and Physics. Ann Arbor, MI: CRC Press.
39. LIM, M.-H. (1999). Computational Study of Organophosphorus Compounds & Synthesis and Characterization of Inorganic-Organic Hybrid Mesoporous Materials. Unpublished Ph.D. dissertation, University of Minnesota, Minneapolis.
40. LIM, M.H., BLANFORD, C.F. & STEIN, A. (1998). Synthesis of ordered microporous silicates with organosulfur surface groups and their applications as solid acid catalysts. Chem Mater 10, 467-470.
41. LIN, H.-P., WONG, S.-T., MOU, C.-Y. & TANG, C.-Y. (2000). Extensive void defects in mesoporous aluminosilicate MCM-41. J Phys Chem B 104, 8967-8975.
42. LINDEN, M., SCHACHT, S., SCHÜTH, F., STEEL, A. & UNGER, K.K. (1998). Recent advances in nano- and macroscale control of hexagonal, mesoporous materials. J Porous Mater 5, 177-193.
43. MCKINLEY, W.A. & FESHBACH, H. (1948). The Coloumb scattering of relativistic electrons by nuclei. Phys Rev 74, 1759-1763.
44. MELDE, B.J., HOLLAND, B.T., BLANFORD, C.F. & STEIN, A. (1999). Mesoporous sieves with unified hybrid inorganic/organic frameworks. Chem Mater 11, 3302-3308.
45. NAGUIB, H.M. & KELLY, R. (1975). Criteria for bombardment-induced structural changes in non-metallic solids. Radiat Eff 25, 1-12.
46. OZKAYA, D., THOMAS, J.M., SHEPHARD, D.S., MASCHMEYER, T., JOHNSON, B.F.G., SANKAR, G. & OLDROYD, R. (1997). STEM analysis of bi-metallic catalysts in mesoporous MCM-41. Inst Phys Conf Ser 153, 403-406.
47. PASCUCCI, M.R., HUTCHISON, J.L. & HOBBS, L.W. (1983). The metamict transformation in alpha-quartz. Radiat Eff 74, 219-226.
48. PEDLEY, J.B. & MARSHALL, E.M. (1983). Thermochemical data for gaseous monoxides. J Phys Chem Ref Data 12, 967-1032.
49. PRASADA RAO, T.S.R. & MURALI DHAR, G. (EDS.). (1998). Recent Advances in Basic and Applied Aspects of Industrial Catalysis. New York: Elsevier.
50. RICE, S.B., KOO, J.Y., DISKO, M.M. & TREACY, M.M.J. (1990). On the imaging of Pt atoms in zeolite frameworks. Ultramicroscopy 34, 108-118.
51. RYOO, R., KO, C.H. & HOWE, R.F. (1997). Imaging the distribution of framework aluminum in mesoporous molecular sieve MCM-41. Chem Mater 9, 1607-1613.
52. SAYARI, A., JARONIEC, M. & PINNAVAIA, T.J. (EDS.). (2000). Nanoporous Materials II. New York: Elsevier.
53. SCHACHT, S., JANICKE, M. & SCHÜTH, F. (1998). Modeling X-ray patterns and TEM images of MCM-41. Micropor Mesopor Mater 22, 485-493.
54. SEITZ, F. & KOEHLER, J.S. (1956). Displacement of atoms during irradiation. In Solid State Physics, Seitz, F. & Koehler, J.S. (Eds.), Vol. 2, pp. 305-448. New York: Academic Press.
55. SHEPHARD, D.S., ZHOU, W., MASCHMEYER, T., MATTERS, J.M., ROPER, C.L., PARSONS, S., JOHNSON, B.F.G. & DUER, M.J. (1998). Site-directed surface derivatization of MCM-41: Use of high-resolution transmission electron microscopy and molecular recognition for determining the position of functionality within mesoporous materials. Angew Chem Int Ed 37, 2719-2723.
56. STEEL, A., CARR, S.W. & ANDERSON, M.W. (1995). 29Si solid-state NMR study of mesoporous M41s materials. Chem Mater 7, 1829-1832.
57. STEIN, A., MELDE, B.J. & SCHRODEN, R.C. (2000). Hybrid inorganic-organic mesoporous silicates - Nanoscopic reactors coming of age. Adv Mater 12, 1403-1419.
58. VANCE, E.R., CANS, C.D. & RICHARDSON, P.G. (1986). Electron irradiation-induced amorphism of some silicates. Radiat Eff 98, 71-81.
59. VARTULI, J.C., SHIH, S.S., KRESGE, C.T. & BECK, J.S. (1998). Potential applications for M41S type mesoporous molecular sieves. Stud Surf Sci Catal 117, 13-21.
60. VEBLEN, D.R. & BUSECK, P.R. (1983). Radiation effects on minerals in the electron microscope. In Proceedings of the 41st Annual Meeting of the EMSA, Bailey, G.W. (Ed.), pp. 350-353. San Francisco, CA: San Francisco Press.
61. WEITKAMP, J., KARGE, H.G., PFEIFER, H. & HOLDERICH, W. (EDS.). (1994). Zeolites and Related Microporous Materials: State of the Art 1994. New York: Elsevier.
62. WILLIAMS, D.B. & CARTER, C.B. (1996). Transmission Electron Microscopy: A Textbook for Materials Science. New York: Plenum Press.
63. YOKOTA, Y., HASHIMOTO, H. & YAMAGUCHI, T. (1994). Electron beam irradiation of natural zeolites at low and room temperatures. Ultramicroscopy, 54, 207-214.