Solvent and temperature effects on diastereofacial selectivity: Amines as co-solvents in n-butyllithium addition to α-chiral aldehydes

European Journal of Organic Chemistry

Volumn , Issue 10, 2003, Pages 1993-2000

  Cainelli, Gianfranco ^a   Giacomini, Daria ^a   Galletti, Paola ^a   Quintavalla, Arianna ^a  

^a UNIVERSITY OF BOLOGNA   (Italy)

Author keywords

Aldehydes; Amines; Entropy; Inversion temperature; Solvent effects; Solvent mixtures

Indexed keywords

ALDEHYDE; ALDEHYDE DERIVATIVE; ALIPHATIC HYDROCARBON; AMINE; HEXANE; LITHIUM DERIVATIVE; PHENYLPROPANOLAMINE; SOLVENT; TERTIARY AMINE;

ADDITION REACTION; ARTICLE; CHIRALITY; DIASTEREOISOMER; ENTHALPY; ENTROPY; HIGH TEMPERATURE; SOLVATION; SOLVENT EFFECT; STEREOCHEMISTRY; TEMPERATURE DEPENDENCE; THERMAL ANALYSIS;

EID: 0037573528     PISSN: 1434193X     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejoc.200200579     Document Type: Article

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