Enantioselective total synthesis of (+)-obtusenyne

Journal of the American Chemical Society

Volumn 125, Issue 25, 2003, Pages 7592-7595

  Crimmins, Michael T ^a   Powell, Mark T ^a  

^a UNIVERSITY OF NORTH CAROLINA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

SHARPLESS KINETIC RESOLUTION;

ALKYLATION; CONFORMATIONS; REACTION KINETICS; SYNTHESIS (CHEMICAL);

ORGANIC COMPOUNDS;

1,5 HEXADIEN 3 OL; ACETOGENIN; ALKADIENE; LAURENCIN; OBTUSENYNE; UNCLASSIFIED DRUG;

ALGA; ARTICLE; CHEMICAL STRUCTURE; CONFORMATION; ENANTIOSELECTIVITY; KINETICS; RING CLOSING METATHESIS; STRUCTURE ANALYSIS; SYNTHESIS;

ALGAE, RED; ALKYNES; ETHERS, CYCLIC;

EID: 0037532711     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja029956v     Document Type: Article

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28. For a discussion of conformational effects on rates of ring closing metathesis of medium ring ethers see: Crimmins, M. T.; Emmitte, K. A.; Choy, A. L. Tetrahedron 2002, 58, 1817- and references therein. For other applications of ring-closing metathesis in the synthesis of medium ring ethers see: Maier, M. C. Angew. Chem., Int. Ed. Engl. 2000, 39, 2073-2077. Fürstner, A. Angew. Chem. In. Ed. Engl. 2000, 39, 3012-3043. Clark, J. S.; Hamelin, O. Angew. Chem. In. Ed. Engl. 2000, 39, 372-374 and references therein.
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