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0344208325
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note
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In the oxepane-fused nine-membered dienyl ethereal system, the selective epoxidation on the normal olefinic double bond rather than the double bond of the enol ether has been reported. See ref 5d.
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54
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0345502058
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note
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2.
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56
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61
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0344639897
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note
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13C NMR, broadening of the signals was observed in both samples. We found slow exchange between the two conformers of 1 and estimated its activating ΔG to be 12.9 kcal/mol from the coalescence temperature (-5 °C).
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