C-H and Si-C bond activation on diruthenium bridging methylene complexes: Evidence for reversible oxidative addition of Si-C(sp3) bonds

Chemical Communications

Volumn , Issue 4, 1996, Pages 541-542

  Hua, Ruimao ^a   Akita, Munetaka ^a   Moro oka, Yoshihiko ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0011486965     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/CC9960000541     Document Type: Article

References (9)

1. The Chemistry of Organosilicon Compounds, ed. S. Patai and Z. Rappoport, Wiley, Chichester, 1989, vols. 1 and 2; Comprehensive Organometallic Chemistry I and II, ed. E. W. Abel, F. G. A. Stone and G. Wilkinson, Pergamon, Oxford, 1982, 1995.
2. The Chemistry of Organosilicon Compounds, ed. S. Patai and Z. Rappoport, Wiley, Chichester, 1989, vols. 1 and 2; Comprehensive Organometallic Chemistry I and II, ed. E. W. Abel, F. G. A. Stone and G. Wilkinson, Pergamon, Oxford, 1982, 1995.
3. See for example, L. G. Bell, W. A. Gustavson, S. Thanedar and M. D. Curtis, Organometallics, 1983, 2, 740.
4. For intermoleeular reactions, see: H. Yamashita, M. Tanaka and K. Honda, J. Am. Chem. Soc., 1995, 117, 8873, some examples of catalytic redistribution of functionalized alkylsilanes (e.g. halosilanes) are also known; M. D. Curtis and P. S. Epstein, Adv. Organomet. Chem., 1981, 19, 213. For intramolecular reactions, see: W. Lin, S. R. Wilson and G. S. Girolami, Organometallics, 1994, 13, 2309.
5. For intermoleeular reactions, see: H. Yamashita, M. Tanaka and K. Honda, J. Am. Chem. Soc., 1995, 117, 8873, some examples of catalytic redistribution of functionalized alkylsilanes (e.g. halosilanes) are also known; M. D. Curtis and P. S. Epstein, Adv. Organomet. Chem., 1981, 19, 213. For intramolecular reactions, see: W. Lin, S. R. Wilson and G. S. Girolami, Organometallics, 1994, 13, 2309.
6. For intermoleeular reactions, see: H. Yamashita, M. Tanaka and K. Honda, J. Am. Chem. Soc., 1995, 117, 8873, some examples of catalytic redistribution of functionalized alkylsilanes (e.g. halosilanes) are also known; M. D. Curtis and P. S. Epstein, Adv. Organomet. Chem., 1981, 19, 213. For intramolecular reactions, see: W. Lin, S. R. Wilson and G. S. Girolami, Organometallics, 1994, 13, 2309.
7. M. Akita, T. Oku, R. Hua and Y. Moro-oka, J. Chem. Soc., Chem. Commun., 1993, 1670.
8. The MeCN adduct 11 was prepared from 5a following the published synthetic procedure for 1: N. M. Doherty, J. A. K. Howard, S. A. R. Knox, N. J. Terril and M. I. Yates, J. Chem. Soc., Chem. Commun., 1989, 638.
9. 2 faster than does 11, the reaction mixture may become complicated: R. Hua, M. Akita and Y. Moro-oka, unpublished results.