Electrophilic aromatic substitution reactions of a metallabenzene: Nitration and halogenation of the osmabenzene [Os{C(SMe)CHCHCHCH}I(CO)(PPH3)2]

Angewandte Chemie - International Edition

Volumn 39, Issue 4, 2000, Pages 750-752

  Rickard, Clifton E F ^a   Roper, Warren R ^a   Woodgate, Scott D ^a   Wright, L James ^a  

^a UNIVERSITY OF AUCKLAND   (New Zealand)

Author keywords

Aromaticity; Electrophilic aromatic substitutions; Metallacycles; Osmium

Indexed keywords

AROMATIC COMPOUND; BENZENE DERIVATIVE; METAL COMPLEX; OSMIUM DERIVATIVE;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CRYSTAL STRUCTURE; HALOGENATION; NITRATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHYSICAL CHEMISTRY; X RAY CRYSTALLOGRAPHY;

EID: 0034681525     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(20000218)39:4<750::AID-ANIE750>3.0.CO;2-Q     Document Type: Article

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17. 2) = 1.061. Programs used: SHELXS-97 (structure solution) and SHELXL-97 (structure refinement). Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Center as supplementary publication nos. CCDC-133773 (2) and CCDC-133774 (3). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK deposit@ccdc.cam.ac.uk.
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