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Volumn 9, Issue 2, 2003, Pages 415-424

Structural studies of N,N′-di(ortho-fluorophenyl)formamidine group 1 metallation

Author keywords

Alkali metals; Amidinates; Coordination modes; Inclusion compounds; N ligands

Indexed keywords

CHELATION; CRYSTALLINE MATERIALS; DIMERS; FLUORINE; POSITIVE IONS; POTASSIUM; SODIUM; SPECTROSCOPIC ANALYSIS; X RAY ANALYSIS;

EID: 0037455361     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200390043     Document Type: Article
Times cited : (29)

References (116)
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    • note
    • 2-hybridised, so that the nitrogen donor orbitals are directed parallel to one another. Unlike many sterically encumbered amidinates, the backbone proton of formamidinates predisposes them to bridging because they can access this idealised structure. However, this does not prohibit chelation (donor orbitals non-parallel) or other more elaborate binding modes.
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    • From a survey of the Cambridge Crystallographic Structural Database (CCSD)
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.