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Volumn 107, Issue 15, 2003, Pages 3351-3366

Kinetics of proton transport in water

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRIC CONDUCTIVITY; HYDRODYNAMICS; PLATINUM; PROTONS; REACTION KINETICS; WATER;

EID: 0037451934     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp020857d     Document Type: Article
Times cited : (251)

References (63)
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    • Gottesfeld, S.1    Zawodzinski, T.A.2
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    • Such a conjecture is justified if the proton distribution is delocalized within the pore. The precise proton distribution is not known. Mean field theory [Eikerling, M.; Kornyshev, A. A.; Kuznetsov, A. M.; Ulstrup, J.; Walbran, S. J. Phys. Chem. B 2001,105, 3646] suggests a smooth radial distribution with a finite proton population in the centre of the pore, where the protons would move almost as in the bulk. Simulation results [Spohr, E.; Commer, P.; Kornyshev, A. A. J. Phys. Chem. B 2002, 106, 10560] are less unambiguous and show strong pinning of protons to pointlike immobile counter charges on the walls of the pore. Proton localization is much weaker for distributed and fluctuating negative charges in the models of real side chains.
    • (2001) J. Phys. Chem. B , vol.105 , pp. 3646
    • Eikerling, M.1    Kornyshev, A.A.2    Kuznetsov, A.M.3    Ulstrup, J.4    Walbran, S.5
  • 17
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    • Such a conjecture is justified if the proton distribution is delocalized within the pore. The precise proton distribution is not known. Mean field theory [Eikerling, M.; Kornyshev, A. A.; Kuznetsov, A. M.; Ulstrup, J.; Walbran, S. J. Phys. Chem. B 2001,105, 3646] suggests a smooth radial distribution with a finite proton population in the centre of the pore, where the protons would move almost as in the bulk. Simulation results [Spohr, E.; Commer, P.; Kornyshev, A. A. J. Phys. Chem. B 2002, 106, 10560] are less unambiguous and show strong pinning of protons to pointlike immobile counter charges on the walls of the pore. Proton localization is much weaker for distributed and fluctuating negative charges in the models of real side chains.
    • (2002) J. Phys. Chem. B , vol.106 , pp. 10560
    • Spohr, E.1    Commer, P.2    Kornyshev, A.A.3
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    • Special Issue on Bioinorganic Enzymology
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    • Colomban, P.1
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    • Colomban, P., Ed.; Cambridge University Press: Cambridge
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.