Polymer Electrolyte Fuel Cells

Advances in Electrochemical Science and Engineering

Volumn 5, Issue , 2008, Pages 195-301

  Gottesfeld, Shimshon ^a   Zawodzinski, Tom A ^a  

^a LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC);

POLYMER ELECTROLYTE FUEL CELLS;

POLYELECTROLYTES;

EID: 84912116739     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9783527616794.ch4     Document Type: Chapter

References (131)

1. S. Gottesfeld, I. D. Raistrick, S. Srinivasan, J. Electrochem. Soc. 134, 1455 (1987).
2. W. K. Paik, T. E. Springer, S. Srinivasan, J. Electrochem. Soc. 136, 644 (1989).
3. A. Parthasarathy, C. R. Martin, S. Srinivasan, J. Electrochem. Soc. 138, 916 (1991).
4. A. Parthasarathy, B. Dave, S. Srinivasan, A. J. Appleby, C. R. Martin, J. Electrochem. Soc. 139, 1634 (1992).
5. A. Parthasarathy, S. Srinivasan, A. J. Appleby, C. R. Martin, J. Electrochem. Soc. 139, 2856 (1992).
6. A. Parthasarathy, S. Srinivasan, A. J. Appleby, C. R. Martin, J. Electrochem. Soc. 139, 2530 (1992).
7. F. Uribe, M. S. Wilson, T. E. Springer, S. Gottesfeld, Proc. Workshop on Structural Effects in Electrocatalysis and Oxygen Electrochemistry, Electrochemical Soc. Proc. Vol. 92-11, pp. 494-509 (1992).
8. Z. Ogumi, Z. Takehara, S. Yoshizawa, J. Electrochem. Soc. 131, 769 (1984)
9. Z. Ogumi, T. Kuroe, S. Yoshizawa, J. Electrochem. Soc. 132, 2601 (1985).
10. F. A. Uribe, T. E. Springer, S. Gottesfeld, J. Electrochem. Soc. 139, 765 (1992).
11. K. L. Hsueh, H. H. Chang, D. T. Chin, S. Srinivasan, Electrochim Acta 30, 1137 (1985)
12. M. A. Enayatullah, T. D. De Vilbiss, J. O'M Bockris, J. Electrochem. Soc. 136, 3369 (1989).
13. A. K. Shukla, P. Stevens, A. Hamnett, J. B. Goodenough, J. Appl. Electrochem. 19, 383 (1989)
14. Data of PEFC testing at Los Alamos National Laboratory (1986-1987).
15. S. Mukerjee, S. Srinivasan, J. Electroanal. Chem. 357, 201 (1993)
16. see also S. Mukerjee, S. Srinivasan, M. P. Soriaga, J. McBreen, J. Phys. Chem. 99. 4577 (1995).
17. M. T. Paffett, J. G. Beery, S. Gottesfeld, J. Electrochem. Soc. 135, 1431 (1988).
18. M. S. Wilson, S. Gottesfeld, J. Appl. Electrochem. 22 1 (1992).
19. I. D. Raistrick, Internal Report, Los Alamos National Loboratory, (1985).
20. N. E. Vanderborgh, J. Guante, R. E. Dean, R. D. Sutton, Abastracts of the Fuel Cell Seminar in Long-Beach, CA. Oct. 1988, Courtesy Associates, Inc., Washington, DC, p. 52.
21. S. Gottesfeld, J. Pafford, J. Electrochem. Soc. 135, 2651 (1988)
22. S. Gottesfeld, US Patent 4 910 099 (March 20, 1990).
23. W. Vogel, J. Lundquist, P. Ross, P. Stonehart, Electrochim. Acta 20, 79 (1975)
24. H. Igarashi, T. Fujino, M. Watanabe, J. Electroanal. Chem., 391, 119 (1995)
25. D. Thirumalai, T. A. Zawodzinski, T. E. Springer, S. Gottesfeld, Abstr. Electrochem. Soc. Meeting, Montreal (May 1997)
26. H. A. Gasteiger, N. M. Markovic, P. N. Ross, J. Phys. Chem. 99, 8290 (1995)
27. H. A. Gasteiger, N. M. Markovic, P. N. Ross, J. Phys. Chem. 99, 16757 (1995).
28. See, for example, P. J. Berlowitz, C. H. F. Peden, D. W. Goodman, J. Phys. Chem. 92, 5213 (1988).
29. M. T. Paffett, Los Alamos National Laboratory, Internal Report.
30. M. S. Wilson, T. E. Springer, T. A. Zawodzinski, S. Gottesfeld Proc. 28th Intersociety Energy Conversion Engineering Conf. 1993, Atlanta, Georgia, Vol. 1, pp. 1203-1208.
31. V. M. Schmidt, R. Ianniello, H. -F. Oetjen, H. Reger, U. Stimming, F. Trila p. 1.
32. M. Iwase, S. Kawatsu in: Proton Conducting Membrane Fuel Cells I, S. Gottesfeld, G. Halpert, A. Landgrebe (Eds), the Electrochemical Society, Pennington, NJ, Oct (1995), p. 12.
33. R. D. Sutton, Report at the Fuel Cell Seminar in Tucson, AZ (1992).
34. B. Z. Nikolic, H. Huang, D. Gervasio, A. Lin, C. Fierro, R. R. Adzic, E. B. Yeager J. Electroanal Chem. 295, 415 (1990).
35. A. LaConti, G. Smarz, F. Sribnik, New Membrane - Catalyst for Solid Polymer Electrolyte Systems, Final Report to Los Alamos National Laboratory from United Technologies, Hamilton, Standard, (1985).
36. C. M. Seymour et al. Abstracts of the Fuel Cell Seminar in Tucson, AZ, Courtesy Associates Inc., Washington, DC (1992), p. 446.
37. Abstracts of the PNGV Workshop on Fuel Processing for Proton Exchange Membrane (PEM) Fuel Cells, Dearborn, MI, October 1995, US DOE, Office of Transportation Technology.
38. Niedrach, US Patent 3, 297, 484 (1967).
39. R. J. Lawrence, US Patent 4 272 353 (June, 1981).
40. H. Takenaka, E. Torikai, Kokai Tokyo Koho (Japanese Patent) 55, 38943 (1980).
41. P. S. Fedkiw, W.-H Her, J. Electrochem. Soc. 136, 899 (1989).
42. P. Aldebert, F. Novel-Cattin, M. Pineri, R. Durand, Solid State Ionics 35, 3 (1989).
43. I. D. Raistrick, in: Diaphragms, Separators, and Ion Exchange Membranes, J. W. Van Zee, R. E. White, K. Kinoshita, H. S. Burney, (eds.). The Electrochemical Society Softbound Proc. Series, Pennington, NJ (1986), PV 86-13, p. 172.
44. S. Srinivasan, E. A. Ticianelli, C. R. Derouin, A. Redondo, J. Power Sources 22, 359 (1988).
45. E. A. Ticianelli, C. R. Derouin, A. Redondo, S. Srinivasan, J. Electrochem. Soc. 135, 2209 (1988).
46. E. A. Ticianelli, C. R. Derouin, S. Srinivasan, J. Electroanal. Chem. 251, 275 (1988).
47. S. Mukerjee, S. Srinivasan, A. J. Appleby, Electrochim. Acta, 38, 1661 (1993).
48. D. Rocco de Senna, E. A. Ticianelli, E. R. Gonzalez, Abstracts of the Fuel Cell Seminar in Phoenix, AZ, Courtesy Associates Inc., Washington, DC (1990), p. 391.
49. E. J. Taylor, E. B. Anderson, N. R. K. Vilambi, J. Electrochem. Soc. 139, L45 (1992).
50. M. S. Wilson, S. Gottesfeld, J. Electrochem. Soc. 139, L28 (1992).
51. M. S. Wilson, J. A. Valerio, S. Gottesfeld, Electrochim. Acta 40, 355 (1995).
52. M. S. Wilson, US Patents. 5 211 984 and 5 234 777 (1993).
53. Abstracts of the US Department of Energy Hydrogen Program Review Meeting in Coral Gables, FL, April 1995.
54. J. F. McElroy, Abstracts of the Fuel Cell Seminar in Phoenix, AZ, Courtesy Associates, Inc., Washington, DC (1990), p. 282.
55. M. S. Wilson, F. Garzon, K. E. Sickafus, S. Gottesfeld, J. Electrochem. Soc. 140, 2872 (1993).
56. M. Reddy, J. A. Marinsky, J. Phys. Chem. 22, 3884 (1970).
57. J.-P. Randin, J. Electrochem. Soc. 129, 1215 (1982).
58. A. B. LaConti, A. R. Fragala, J. R. Boyack, in: Electrode Materials and Processes for Energy Conversion and Storage, J. D. E. McIntyre, S. Srinivasan, F. G. Will (eds.), The Electrochemical Society Softbound Proc., Pennington, NJ (1977) PV 77-6, p. 354.
59. G. G. Scherer, T. Mamose, K. Tomiie, J. Electrochem. Soc. 135, 3071 (1988).
60. T. Kyu in: Materials Science of Synthetic Membranes, D. R. Lloyd (ed.), ACS Symp. Ser. No. 269 (1985), p. 365.
61. R. S. Yeo, H. L. Yeager, Modern Aspects of Electrochem. 16, 437 (1985).
62. S. C. Yeo, A. Eisenberg, J. Appl. Polym. Sci. 21, 875 (1977).
63. K. A. Mauritz, C. E. Rogers, Macromolecules 18, 423 (1985).
64. H. L. Yeager, A. Steck, J. Electrochem. Soc. 128, 1880 (1981).
65. D. Wu, DuPont Central Research, private communication.
66. W. Grot, G. E. Munn, P. N. Walmsley, Abstracts of the ECS Meeting in Houston, TX, May, 1972.
67. T. A. Zawodzinski, Jr., C. Derouin, S. Radzinski, R. J. Sherman, T. Springer, S. Gottesfeld, J. Electrochem Soc. 140, 1041 (1993).
68. T. A. Zawodzinski, Jr., C. Lopez, R. Jestel, J. Valerio, S. Gottesfeld, J. Electrochem Soc. 140,. 1981 (1993).
69. G. A. Eisman in: Diaphragms, Separators and Ion Exchange Membranes, J. W. Van Zee, R. E. White, K. Kinoshita, H. S. Burney (eds.), The Electrochemical Society Softbound Proc. Ser., Pennington, NJ (1986), PV 86-13, pp. 156-171.
70. M. Escoubes, M. Pineri in: Structure and Properties of Ionomers, M. Pineri, A. Eisenberg (eds.), Reidel, Dordrecht (1987), p. 341.
71. P. C. Rieke, N. E. Vanderborgh, J. Membr. Sci. 32 313 (1987).
72. K. K. Pushpa, D. Nandan, R. M. Iyer, J. Chem. Soc. Faraday Trans. 84, 2047 (1988).
73. T. A. Zawodzinski, M. Neeman, L. Sillerud, S. Gottesfeld, J. Phys. Chem. 95, 6040 (1991).
74. M. Heaney, Ph.D. Thesis, University of Colorado, Boulder (1993).
75. P. Schroeder, Z. Phys. Chem. 45, 75 (1903).
76. T. A. Zawodzinski, M. Shoichet, T. McCarthy, S. Gottesfeld, J. Appl. Electrochem. 23, 86 (1993).
77. T. A. Zawodzinski, Jr., S. Gottesfeld, Extended Abstr. of Electrochemical Society Meeting Canada, Fall 1992.
78. T. A. Zawodzinski, Jr., T. Springer, F. Uribe, S. Gottesfeld, Solid State Ionics 60, 199 (1993).
79. N. Sivashinsky, G. B. Tanny, J. Appl. Polym. Sci. 26. 2625 (1981).
80. N. G. Boyle, V. J. MacBrierty, D. C. Douglass, Macromolecules 16, 75 (1983).
81. R. C. T. Slade, A. Hardwick, P. G. Dickens, Solid State Ionics 9/10, 1093 (1983).
82. F. Valino, M. Pineri, A. J. Dainoux, J. Polym. Sci. 20, 481 (1982).
83. M. Falk, Can. J. Chem. 58. 1495 (1980).
84. R. S. Chen, J. P. Jayakody, S. G. Greenbaum, Y. S. Pak, G. Xu, M. G. McLin, J. J. Fontanella, Solid State Ionics (1993).
85. Y. S. Pak, G. Xu, J. Electrochem. Soc. 140, 1237 (1993).
86. M. Varbrugge, R. Hill, J. Electrochem. Soc. 137, 3770 (1990).
87. M. Verbrugge, E. W. Schneider, R. S. Conell, R. Hill, J. Electrochem. Soc. 139, 3421 (1992).
88. J. J. Fontanella, M. G. McLin, M. C. Wintersgill, J. P. Calame, S. G. Greenbaum, Solid State Ionics 66, 1 (1993).
89. J. J. Fontanella, M. G. McLin, M. C. Wintersgill, J. Polym. Sci. B: Polym. Phys. in press.
90. B. D. Cahan, J. S. Wainwright, J. Electrochem. Soc. 140, L185 (1993).
91. J. Crank, The Mathematics of Diffusion, 2nd edn, Clarendon, Oxford, (1975), Chapter 9.
92. M. Verbrugge, R. Hill, J. Phys. Chem. 92, 6778 (1988).
93. M. Verbrugge, J. Electrochem. Soc. 136, 417 (1989).
94. R. Hill, M. Verbrugge, J. Electrochem. Soc. 137, 886 and 893 (1990).
95. R. C. T. Slade, A. Hardwick, P. G. Dickens, Solid State Ionics (1990).
96. T. E. Springer, T. A. Zawodzinski, S. Gottesfeld, J. Electrochem. Soc. 138, 2334 (1991).
97. H. R. Zelsmann, M. Pineri, M. Thomas, M. Escoubes, J. Appl. Polym. Sci. 41, 1673 (1990).
98. K.-D. Kreuer, T. Dippel, W. Meyer, J. Maier, Mater. Res. Soc. Symp. Proc. 293, 273 (1993).
99. B. Breslau, I. Miller, Ind. Chem. Eng. Fundam. 10, 554 (1971).
100. F. Helferrich, Ion Exchange, McGraw-Hill, New York, (1962).
101. D. Bernardi, M. Verbrugge, J. Electrochem. Soc. 139, 2477 (1992).
102. T. Okada, S. K. Ratjke, H. Nache-Olsen, J. Membr. Sci., 66, 179 (1992).
103. R. Mosdale, P. Stevens, F. Novel-Cattin, B. Loppinet, G. Gebel, P. Adelbert, M. Pineri, Proc. Eur. Space Power Conf., p. 479 (1991).
104. K. D. Kreuer, T. Dippel, J. Maier in: Proton Conducting Mambrane Fuel Cells I, S. Gottesfeld, G. Halpert, A. Landgrebe (eds.), The Electrochemical Society, Pennington, NJ (1995) 241.
105. T. Fuller, J. Newman, J. Electrochem. Soc. 139, 1332 (1992).
106. T. A. Zawodzinski, J. Davey, J. Valerio, S. Gottesfeld, Electrochim. Acta 40 297 (1995).
107. A. Sen, K. E. Leach, R. D. Varijan, Abstracts of the Spring 1995 Meeting of the MRS, San Francisco, CA, (1995).
108. A. Steck, H. L. Yeager, Anal. Chem. 51, 869 (1979).
109. T. E. Springer, M. S. Wilson, S. Gottesfeld, J. Electrochem. Soc. 140, 3513 (1993).
110. R. F. Savinell, S. D. Fritts, J. Power Sources 22, 423 (1988).
111. D. Bernardi, J. Electrochem. Soc. 137, 3334 (1990).
112. D. M. Bernardi, M. W. Verbrugge, AIChe J. 37, 1151 (1991).
113. T. F. Fuller, J. Newman in: Proc. Symposium on Fuel Cells, R. E. White, A. J. Appleby (eds.), Electrochem. Soc. Proc. 89-14, 25 (1989).
114. D. Bernardi, M. Verbrugge, J. Electrochem. Soc. 139, 2477 (1992).
115. T. F. Fuller, J. Newman, J. Electrochem. Soc. 140, 1218 (1993).
116. T. V. Nguyen, R. E. White, J. Electrochem. Soc. 140, 2178 (1993).
117. T. E. Springer, T. A. Zawodzinski, M. S. Wilson, S. Gottesfeld in: Proton Conducting Membrane Fuel Cells I, S. Gottesfeld, G. Halpert, A. Landgrebe (eds.) The Electrochemical Society, Pennington, NJ (1995), p. 137; also, J. Electrochem. Soc., 143, 587 (1996).
118. J. L. Fales et al. in: Diaphragms, Separators, and Ion Exchange Membranes, J. W. Van Zee, R. E. White, K. Kinoshita, H. S. Burney (eds.) The Electrochemical Society Softbound Proc. Series, Pennington, NJ (1986), PV 86-13, p. 179.
119. E. A. Ticianelli, C. R. Derouin, A. Redondo, S. Srinivasan, J. Electrochem. Soc. 135, 2209 (1988)
120. for more uses of the same approach see also E. A. Ticianelli, C. R. Derouin, S. Srinivasan, J. Electroanal. Chem. 251, 275 (1988)
121. S. Srinivasan, D. J. Manko, H. Koch, M. A. Enayatullah, A. J. Appleby, J. Power Sources 29, 367 (1990).
122. R. B. Bird, W. E. Stewart, E. N. Lightfoot, Transport Phenomena, Wiley, New York (1960), p. 570.
123. K. B. Prater, J. Power Sources 37, 181 (1992).
124. S. Surampudi, S. R. Narayanan, E. Vamos, H. Frank, G. Halpert, A. LaConti, J. Kosek, G. K. Surya Prakash, G. A. Olah, J. Power Sources 47, 377 (1994).
125. J. A. Kosek, C. C. Cropley, G. Wilson, A. B. LaConti, S. Narayan, E. Vamos S. Surampudi, H. Frank in: Proc. 28th Intersociety Energy Conversion Engineering Conference (DECEC), Atlanta, GA (1993), Vol. 1, p. 1209.
126. R. F. Savinell, E. Yeager, D. Tryk, U. Landau, J. S. Wainright, D. Weng, K. Lux, M. Litt, C. Rogers, J. Electrochem. Soc. 141. L46 (1994).
127. X. Ren, Mahlon S. Wilson, S. Gottesfeld in: Proton Conducting Membrane Fuel Cells I, S. Gottesfeld, G. Halpert, A. Landgrebe (eds.), The Electrochemical Society, Pennington, NJ 1995, p. 252.
128. X. Ren, T. A. Zawodzinski, F. Uribe, H. Dai, S. Gottesfeld in: Proton Conducting Membrane Fuel Cells I, S. Gottesfeld, G. Halpert, A. Landgrebe (eds.), The Electrochemical Society, Pennington, NJ (1995), p. 284.
129. H. Grüne, G. Luft, K. Mund, M. Waidhas, Program and Abstracts, Fuel Cell Seminar, San Diego, CA, Nov. 28 - Dec. 1, 1994, p. 474.
130. M. Watanabe, M. H. Uchida, S. Motoo, J. Electroanal. Chem. 229, 395 (1987).
131. M. Watanabe, M. H. Uchida, Y. Seki, M. Emori, P. Stonehart, J. Electrochem. Soc. 143, 3847 (1996).