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note
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The X-ray structure refers to the racemic isomer but there is no reason to suppose that the meso form does not exist in solution.
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0344194281
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note
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This assertion is based on the results of the ESMS studies where it is seen that the 2:2 complex makes only a minor contribution to the overall composition of the system.
-
-
-
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65
-
-
0345056477
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note
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2.
-
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66
-
-
0345488210
-
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note
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1. At early stages of the titration, the experimental conditions are such that the 1:2 complex is favoured but, as the concentration of copper approaches that of L, the equilibrium moves firmly in favour of the 1:1 complex since there will be little free ligand present in solution.
-
-
-
-
67
-
-
0345488211
-
-
note
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This process was followed in the presence of a modest excess of copper in order to prevent ejection of metal ions from the metallo-helicate. The only other cationic species present in solution are the 1:1 and 2:2 complexes. Equilibration between these latter species should be insensitive to the presence of excess copper(I), provided a constant ionic strength is maintained.
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68
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0344194282
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note
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2.
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69
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0000129451
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M. Meyer, A. M. Albrecht-Gary, C. O. Dietrich-Buchecher and J. P. Sauvage, Inorg. Chem., 1999, 38, 2279.
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(1999)
Inorg. Chem.
, vol.38
, pp. 2279
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Meyer, M.1
Albrecht-Gary, A.M.2
Dietrich-Buchecher, C.O.3
Sauvage, J.P.4
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