Redox cycling of segmented copper helicates [17]

Journal of the American Chemical Society

Volumn 120, Issue 38, 1998, Pages 9973-9974

  El Ghayouy, A ^a   Harriman, A ^a   De Cian, A ^a   Fischer, J ^a   Ziessel, R ^a  

^a UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER DERIVATIVE;

CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL STRUCTURE; CYCLIC POTENTIOMETRY; LETTER; OXIDATION REDUCTION REACTION; PROTON NUCLEAR MAGNETIC RESONANCE; X RAY CRYSTALLOGRAPHY;

EID: 0032581955     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja981284e     Document Type: Letter

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14. 2) is 0.0004, and the amount of charge transferred (1-2a2) is unity.
15. -1}.
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17. For example, the binuclear coppcr(I) helicate described in ref 17 undergoes rapid dissociation on one-electron oxidation. The rate of dissociation is too fast to be measured by stopped-flow techniques.
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