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Volumn 22, Issue 1, 2003, Pages 129-135

(Pentamethylcyclopentadienyl)lanthanide(II) alkyl and silyl complexes: Synthesis, structures, and catalysis in polymerization of ethylene and styrene

Author keywords

[No Author keywords available]

Indexed keywords

BLOCK-COPOLYMERIZATION; INTERCHAIN INTERCATION; INTERMOLECULAR INTERACTION; MIGRATORY ADDITION; NEUTRAL STABILIZATION LIGAND; PENTAMETHYCYCLOPENTADIENYL LANTHANIDE;

EID: 0037421457     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020742w     Document Type: Article
Times cited : (75)

References (58)
  • 10
    • 4243915177 scopus 로고    scopus 로고
    • a thematic issue on lanthanide chemistry
    • Recent reviews on organolanthanide chemistry: (a) Chem. Rev. 2002, 102, 6 (a thematic issue on lanthanide chemistry).
    • (2002) Chem. Rev. , vol.102 , pp. 6
  • 11
    • 0013466373 scopus 로고    scopus 로고
    • Noyori, R., Imamoto, T., Eds.; Thieme: Stuttgart, Germany; Chapter 2.12
    • (b) Hou, Z.; Wakatsuki, Y. In Science of Synthesis; Noyori, R., Imamoto, T., Eds.; Thieme: Stuttgart, Germany, 2002; Vol. 2, Chapter 2.12.
    • (2002) Science of Synthesis , vol.2
    • Hou, Z.1    Wakatsuki, Y.2
  • 13
    • 0000969532 scopus 로고
    • Abel, E. W., Stone, F. G. A., Wilkinson, G., Lappert, M. F., Eds.; Pergamon: Oxford, U.K.
    • (d) Edelmann, F. T. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Lappert, M. F., Eds.; Pergamon: Oxford, U.K., 1995; Vol. 4, p 11.
    • (1995) Comprehensive Organometallic Chemistry II , vol.4 , pp. 11
    • Edelmann, F.T.1
  • 25
    • 0034600349 scopus 로고    scopus 로고
    • For structurally characterized cyclopentadienyl-free lanthanide-(II) alkyl and aryl complexes, see: (a) Heckmann, G.; Niemeyer, M. J. Am. Chem. Soc. 2000, 122, 4227.
    • (2000) J. Am. Chem. Soc. , vol.122 , pp. 4227
    • Heckmann, G.1    Niemeyer, M.2
  • 40
    • 0013525469 scopus 로고    scopus 로고
    • note
    • The synthesis and structure of the Sm(II) alkyl complex (1a) has been briefly described in a previous communication.
  • 41
    • 0013464568 scopus 로고    scopus 로고
    • note
    • 5 ring in 1a was treated as a fixed Cp model (C-C = 1.420 Å), because of the poor quality of the crystal. This restraint was released in the present work.
  • 44
    • 0013528734 scopus 로고    scopus 로고
    • note
    • 3", as described below.
  • 45
    • 0013502463 scopus 로고    scopus 로고
    • note
    • 2 with KH to give a Ln-H species was not observed in THF at room temperature.
  • 46
    • 0013530318 scopus 로고    scopus 로고
    • note
    • 3".
  • 51
    • 33847797506 scopus 로고
    • 2+ = -1.55 V. (a) Morss, L. R. Chem. Rev. 1976, 76, 827.
    • (1976) Chem. Rev. , vol.76 , pp. 827
    • Morss, L.R.1
  • 54
    • 0013528898 scopus 로고    scopus 로고
    • note
    • 3 group in the polymer products by NMR were not successful, possibly owing to the high molecular weight of the polymers.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.