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40
-
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0013525469
-
-
note
-
The synthesis and structure of the Sm(II) alkyl complex (1a) has been briefly described in a previous communication.
-
-
-
-
41
-
-
0013464568
-
-
note
-
5 ring in 1a was treated as a fixed Cp model (C-C = 1.420 Å), because of the poor quality of the crystal. This restraint was released in the present work.
-
-
-
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42
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33845280818
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44
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0013528734
-
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note
-
3", as described below.
-
-
-
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45
-
-
0013502463
-
-
note
-
2 with KH to give a Ln-H species was not observed in THF at room temperature.
-
-
-
-
46
-
-
0013530318
-
-
note
-
3".
-
-
-
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47
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84984026733
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33845376846
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2 bond in lanthanide(III) metallocene complexes toward ethylene was known. Jeske, G.; Lauke, H.; Mauermann, H.; Swepston, P. N.; Schumann, H.; Marks, T. J. J. Am. Chem. Soc. 1985, 107, 8091.
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54
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0013528898
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note
-
3 group in the polymer products by NMR were not successful, possibly owing to the high molecular weight of the polymers.
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55
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37049104831
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