Iridium-catalyzed Mizoroki-Heck-Type reaction of organosilicon reagents

Angewandte Chemie - International Edition

Volumn 42, Issue 1, 2003, Pages 89-92

  Koike, Tooru ^a   Du, Xiaoli ^a   Sanada, Tomoyuki ^a   Danda, Yasuaki ^a   Mori, Atsunori ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Alkoxysilanes; C C coupling; Homogeneous catalysis; Iridium; Silicon

Indexed keywords

CATALYSTS; CHEMICAL BONDS; COMPLEXATION; IRIDIUM; RHODIUM; SUBSTRATES;

REAGENTS;

ORGANOMETALLICS;

ALKADIENE; CARBONYL DERIVATIVE; CYCLOOCTA 1,5 DIENE; IRIDIUM COMPLEX; ORGANOSILICON DERIVATIVE; REAGENT; RHODIUM; SILANE DERIVATIVE; SILICON; SOLVENT; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL BINDING; CHEMICAL REACTION; COMPLEX FORMATION; MIZOROKI HECK TYPE REACTION; REACTION ANALYSIS;

EID: 0037414921     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200390061     Document Type: Article

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35. 2] (3 mol%) afforded the Mizoroki-Heck-type product(46%), in which 36% of 2a was converted into 9.
36. 2 (0.6 mmol), 2a (0.3 mmol), and 3b (0.6 mmol) in THF (3 mL) at 70 °C for 24 h) afforded 27% of the Mizoroki-Heck-type product 3a and 3% of 4b with 75% recovery of 3b.