SCOPUS 정보 검색 플랫폼

Journal of the American Chemical Society

Volumn 125, Issue 13, 2003, Pages 3793-3798

Chiral hetero Diels-Alder products by enantioselective and diastereoselective zirconium catalysis. Scope, limitation, mechanism, and application to the concise synthesis of (+)-prelactone C and (+)-9-deoxygoniopypyrone

(4) Yamashita, Yasuhiro a Saito, Susumu a Ishitani, Haruro a Kobayashi, Shu a

a UNIVERSITY OF TOKYO (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHIRAL COMPOUNDS; ENANTIOSELECTIVITY;

ADDITION REACTIONS; CATALYSIS; CATALYST SELECTIVITY; DERIVATIVES; ZIRCONIUM;

STEREOCHEMISTRY;

3,3' DIIODOBINAPHTHOL; 9 DEOXYGONIOPYPYRONE; ALCOHOL; ALKADIENE; LACTONE DERIVATIVE; NAPHTHOL DERIVATIVE; PRELACTONE C; PYRAN DERIVATIVE; PYRONE DERIVATIVE; UNCLASSIFIED DRUG; ZIRCONIUM DERIVATIVE; ZIRCONIUM TERT BUTOXIDE;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHIRALITY; CYCLOADDITION; ENANTIOSELECTIVITY; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SYNTHESIS;

ALDEHYDES; ALKENES; CATALYSIS; LACTONES; PYRANS; STEREOISOMERISM; ZIRCONIUM;

EID: 0037414319 PISSN: 00027863 EISSN: None Source Type: Journal
DOI: 10.1021/ja028186k Document Type: Article

Times cited : (152)

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80
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- A similar intermediate which suggested the stepwise mechanism was also isolated in the reaction of benzaldehyde with 1h.

81
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- 2O (20 mol %), the aldol reaction of benzaldehyde with(Z)-2-benzyloxy-1-phenoxy-1-trimethylsiloxyethene proceeded in toluene′BuOMe at -20 °C to afford the corresponding syn-aldol adduct in high yield with high stereoselectivity (quantitative yield, syn/anti = > 30/1, 97% ee (syn)).

* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.