An unusual course of thioglycoside activation with bromine: Synthesis and crystal structure of 4-O-acetyl-2-bromo-2,3,6-trideoxy-3-C-methyl-3-trifluroacetamido-α-L- altropyranosyl bromide

Carbohydrate Research

Volumn 338, Issue 10, 2003, Pages 1121-1125

  Dulin, Mildred L ^a   Noecker, Lincoln A ^a   Kassel, W Scott ^a   Giuliano, Robert M ^a  

^a VILLANOVA UNIVERSITY   (United States)

Author keywords

Bromine activation of thioglycosides; Bromodihydrooxazine; Cororubicin

Indexed keywords

BROMINE; CRYSTAL STRUCTURE; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

BICYCLIC PRODUCTS;

CARBOHYDRATES;

2 TRIFLUOROMETHYL (4 O ACETYL 2 BROMO 2,3,6 TRIDEOXY 3 C METHYL ALPHA ALTROHEPYRANO)[3,2,1 D,E] 2 OXAZINE; 4 O ACETYL 2 BROMO 2,3,6 TRIDEOXY 3 C METHYL 3 TRIFLUOROACETAMIDO ALPHA ALTROPYRANOSYLBROMIDE; 4 O ACETYL 2,3,6 TRIDEOXY 3 C METHYL 3 TRIFLUOROACETAMIDO 1 THIO ALPHA,BETA HEXOPYRANOSIDE; BROMINE DERIVATIVE; DISACCHARIDE; OXAZINE DERIVATIVE; PYRANOSIDE; SILICATE; UNCLASSIFIED DRUG;

ARTICLE; CARBOHYDRATE ANALYSIS; CARBOHYDRATE SYNTHESIS; CHEMICAL REACTION; CRYSTAL STRUCTURE; PRIORITY JOURNAL; REACTION ANALYSIS; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 0037403332     PISSN: 00086215     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0008-6215(03)00066-1     Document Type: Article

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