Asymmetric IrI-catalysed allylic alkylation of monosubstituted allylic acetates with phosphorus amidites as ligands

European Journal of Organic Chemistry

Volumn , Issue 6, 2003, Pages 1097-1103

  Bartels, Björn ^a   García Yebra, Cristina ^a   Helmchen, Günter ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

Allylic substitution; Asymmetric catalysis; Chirality; Iridium; P ligands

Indexed keywords

ACETIC ACID DERIVATIVE; AMINE; IRIDIUM; LIGAND; PHOSPHORUS DERIVATIVE;

ALKYLATION; ARTICLE; ASYMMETRIC CATALYSIS; CHIRALITY; ENANTIOMER; ENANTIOSELECTIVITY; GAS CHROMATOGRAPHY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY;

EID: 0037353622     PISSN: 1434193X     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejoc.200390162     Document Type: Article

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52. 3) for 3b with 86% ee (R).
53. 2) for 3c with 85% ee (R).
54. 3) for 3a with 93% ee (R).
55. 3) for 3d with 66% ee (R).
56. 3) for 3e with 70% ee (R).
57. This apparatus was invented in the senior author's group in the 1980s, cf. G. Wegner, PhD Dissertation, Universität Würzburg, Würzburg, Germany, 1987. In the meantime, it has become widely known in the chemical community by oral communication.