Paracetamol oxidation from aqueous solutions by means of ozonation and H2O2/UV system

Water Research

Volumn 37, Issue 5, 2003, Pages 993-1004

  Andreozzi, Roberto ^a   Caprio, Vincenzo ^a   Marotta, Raffaele ^a   Vogna, Davide ^a  

^a UNIVERSITY OF NAPLES FEDERICO II   (Italy)

Author keywords

Advanced oxidation process; Drug; Hydrogen peroxide UV photolysis; Ozonation; Paracetamol

Indexed keywords

CARBON DIOXIDE; OXIDATION; OZONIZATION; PHOTOLYSIS; SUBSTRATES;

PARACETAMOL;

WATER ANALYSIS;

AROMATIC COMPOUND; CARBON; CARBON DIOXIDE; HYDROGEN PEROXIDE; PARACETAMOL;

AQUEOUS SOLUTION; KINETICS; OZONATION; PHOTOLYSIS; WASTEWATER TREATMENT;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; GAS CHROMATOGRAPHY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; KINETICS; MASS SPECTROMETRY; MINERALIZATION; NONHUMAN; OXIDATION; OZONATION; PHOTOLYSIS; PRIORITY JOURNAL; ULTRAVIOLET RADIATION;

EID: 0037351034     PISSN: 00431354     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0043-1354(02)00460-8     Document Type: Article

References (35)

1. Paxeus N. Organic pollutants in the effluents of large wastewater treatment plants in Sweden. Water Res. 30(5):1996;1115-1122.
2. Janssens I., Tanghe T., Verstraete W. Micropollutants. a bottleneck in sustainable wastewater treatment Water Sci Technol. 35(10):1997;13-26.
3. Fromme H., Otto T., Pilz K. Polycyclic musk fragrances in different environmental compartments in Berlin (Germany). Water Res. 35(1):2001;121-128.
4. Rodgers G., Jobling S., Morris S., Kelly C., Kirby S., Janbakhsh A., Harries J.E., Waldock M.J., Sumpter J.P., Tyler C.R. Long-term temporal changes in the estrogenic compostion of treated sewage effluents and its biological effects on fish. Environ Sci Technol. 34:2000;1521-1528.
5. Holm J.H., Rugge K., Bjerg P.L., Christensen T.H. Occurrence and distribution of pharmaceutical organic compounds in the groundwater downgradient of a landfill (Griendsted, Denmark). Environ Sci Technol. 29(5):1995;1415-1420.
6. Ternes T.A. Occurrence of drugs in German sewage treatment plants and rivers. Water Res. 32:1998;3245-3260.
7. Daughton C.G., Ternes T.A. Pharmaceuticals and personal care products in the environment. agents of subtle change? Environ Health Perspectives. 107(6):1999;907-938.
8. Hirsch R., Ternes T., Haberer K., Kratz K.L. Occurrence of antibiotics in the aquatic environment. Sci Total Environ. 225:1999;109-118.
9. Buser H.R., Poiger T., Muller M.D. Occurrence and environmental behavior of the chiral pharmaceutical drug Ibuprofen in surface waters and in wastewater. Environ Science & Technology. 33:1999;2529-2535.
10. Jorgensen S.E., Halling-Sorensen B. Drugs in the environment. Chemosphere. 40:2000;691-699.
11. Buser HR, Poiger T, Muller MD Occurrence and fate of the pharmaceutical drug diclofenac in surface waters: rapid photodegradation in a lake. Environ Sci Technol 1998a;32(22): 3449-56.
12. Buser HR, Muller MD, Norbert T. Occurrence of the pharmaceutical drug clofibric acid and the herbicide mecoprop in various Swiss lakes and in the North Sea. Environ Sci Technol 1998b;32: 188-92.
13. Zuccato E., Calamari D., Natangelo M., Fanelli R. Presence of therapeutic drugs in the environment. Lancet. 355:2000;1789-1790.
14. Halling-Sorensen B., Nielsen S.N., Lanzky P.F., Ingerslev F., Lutzhorft H.C., Jorgensen S.E. Occurrence, fate and effects of pharmaceutical substances in the environment- a review. Chemosphere. 36:1998;357-393.
15. Burton K. An invader worse than a "B" movie. Endang. Species Bull 2000; XXV(5): 11-2.
16. Andreozzi R, Caprio V, Insola A, Marotta R. The oxidation of metol (N-methyl-p-aminophenol) in aqueous solution by UV/H2O2 photolysis. Water Res 2000a;34(2): 463-72.
17. Andreozzi R, Lo Casale MS, Marotta R, Pinto G, Pollio A. N-methyl-p-aminophenol (metol) ozonation in aqueous solution: kinetics, mechanism and toxicological characterization of ozonized samples. Water Res 2000b;34(18): 4419-29.
18. Lunar L., Sicilia D., Rubio S., Perez-Bendito D., Nickel U. Degradation of photographic developers by Fenton's reagent. condition optimization and kinetic for metol oxidation Water Res. 34:2000;1791-1802.
19. Nicole I., De Laat J., Doré M., Duguet J.P., Bonnel C. Use of UV radiation in water treatment. measurement of photonic flux by hydrogen peroxide actinometry Water Res. 24(2):1990;157-168.
20. Treadwell FP, Hall J. Analytical chemistry, vol. II (8th ed.) New York: John Wiley, 1935.
21. Andreozzi R, Insola A, Caprio V, D'Amore MG. Quinoline ozonation in aqueous solutions. Water Res 1992a;26(5): 639-44.
22. Bailey P S. Ozonation in organic chemistry, Vol. II. New York: Academic Press, 1982.
23. 2 systems Water Res. 31(6):1997;1383-1397.
24. Scheck C.K., Frimmel F.H. Degradation of phenol and salicylic acid by ultraviolet radiation/hydrogen peroxide/oxygen. Water Res. 29(10;):1995;2346-2352.
25. Andreozzi R, Insola A, Caprio V, D'Amore MG. Kinetics and mechanism of malonic acid ozonation in aqueous solution. Oxid Commun 1992b;15(2): 76-84.
26. Andreozzi R., Caprio V., Insola A., Tufano V. Measuring ozonation rate constants in gas-liquid reaction under the kinetic-diffusional transition regime. Chem Eng Commun. 143:1996;195-197.
27. Andreozzi R., Marotta R. Ozonation of p-chlorophenol. J Hazard Mater. B69:1999;303-317.
28. Reklaitis G.V., Ravindran A., Regsdell K.M. Engineering optimization. 1983;Wiley, New York.
29. Dastmalchi S., Rashidi M.R., Rassi M. Simultaneous determination of the pKa and octanol/water partition coefficient of acetaminophen. J. Sch. Pharm., Med. Sci. 4(3):1995;7-14.
30. 2 - quantum yields, tracer and fractionation effects. J Am Chem Soc. 74:1952;5999-6002.
31. -·) in aqueous solution. J Phys Chem Ref. Data. 17(2):1988;513-886.
32. - radicals in aqueous solution. J Phys Chem Ref Data. 14(4):1985;1041-1100.
33. Baxendale J.H., Wilson J.A. Photolysis of hydrogen peroxide at high light intensities. Trans Faraday Soc. 53:1957;344-356.
34. Volman D.H., Chen J.C. The photochemical decomposition of hydrogen peroxide in aqueous solutios of allyl alcohol at 2537 A. J Am Chem Soc. 81:1959;4141-4144.
35. 15N-aided inventory of nitrogenous breakdown products. J Org Chem. 67:2002;6143-6151.