Measuring ozonation rate constants in gas-liquid reactors under the kinetic-diffusional transition regime

Chemical Engineering Communications

Volumn 143, Issue , 1996, Pages 195-204

  Andreozzi, R ^a   Caprio, V ^b   Insola, A ^a   Tufano, V ^c  

^a CNR   (Italy)

^b UNIVERSITY OF NAPLES FEDERICO II   (Italy)

^c UNIVERSITY OF BASILICATA   (Italy)

Author keywords

Ozonation; Rate constant; Transition Regime

Indexed keywords

GAS-LIQUID; OZONATION; RATE CONSTANTS; REACTORS;

ABSORPTION; DIFFUSION; GASES; LIQUIDS; MASS TRANSFER; MATHEMATICAL MODELS; ORGANIC ACIDS; OZONE; PHASE TRANSITIONS; PHENOLS; REACTION KINETICS; SUBSTRATES;

GAS LIQUID REACTORS; OZONATION; RATE CONSTANT;

CHEMICAL REACTORS;

EID: 0029657149     PISSN: 00986445     EISSN: None     Source Type: Journal    
DOI: 10.1080/00986449608936441     Document Type: Article

References (9)

1. Andreozzi, R., Caprio, V., D'Amore, M. G., Insola, A., and Tufano, V., Analysis of Complex Reaction Networks in Gas-Liquid Systems: The Ozonation of 2-Hydioxypyridine in Aqueous Solutions, Ind. Eng. Chem. Res., 30, 2098-2104 (1991).
2. Caprio, V., D'Amore, M. G., and Insola, A., The Kinetics of Ozonation of Maleic Acid in Aqueous Solution, Oxid. Commun., 10, 105-113 (1987).
3. Danckwerts P. V., Gas-Liquid Reactions, McGraw-Hill, New York (1970).
4. Hoignè, J., and Bader, H., Rate Constants of Reactions of Ozone with Organic and Inorganic Compounds in Water - I Non-Dissociating Organic Compounds, Water Res., 17, 173-183 (1983a).
5. Hoignè, J., and Bader, H., Rate Constants of Reactions of Ozone with Organic and Inorganic Compounds in Water - II Dissociating Organic Compounds, Water Res., 17, 185-194 (1983b).
6. Li K. Y., Kuo, C. H., and Weeks J. L. Jr., A Kinetic Study of Ozone- Phenol Reaction in Aqueous Solutions, AIChE J. 25, 583-591 (1979).
7. Tufano, V., Andreozzi, R., Caprio, V., D'Amore, M. G., and Insola, A., Kinetic Analysis of Complex Gas-Liquid Reactions: Transport Limitations in the Slow-Fast Transition Regime. Chem. Eng. Sci., 47, 2239-2244 (1992).
8. Tufano, V., Unsteady Reaction Regimes in Gas-Liquid Stirred Reactors, ACH-Models in Chemistry, 131, 9-23 (1994).
9. Tufano, V., Andreozzi, R., Caprio, V., D'Amore, M. G., and Insola, A., Optimal Operating Conditions for Lab-Scale Ozonation Reactors. Ozone Sci. Eng., 16, 181-195 (1994).