A new asymmetric tridentate carbazole ligand: Its preparation and application to Nozaki-Hiyama allylation

Synlett

Volumn , Issue 4, 2003, Pages 570-572

  Suzuki, Takahiro ^a   Kinoshita, Akihiro ^a   Kawada, Hatsuo ^a   Nakada, Masahisa ^a  

^a WASEDA UNIVERSITY   (Japan)

Author keywords

Allylations; Asymmetric catalysis; Carbazole; Chromium; Nozaki Hiyama reaction; Tridentate ligand

Indexed keywords

ALLYLATION; ARTICLE; ASYMMETRIC CATALYSIS; ASYMMETRIC SYNTHESIS; ENANTIOSELECTIVITY; LIGAND BINDING; NOZAKI HIYAMA ALLYLATION; PRODUCT RECOVERY; PRODUCTIVITY; REACTION OPTIMIZATION;

EID: 0037239928     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2003-37535     Document Type: Article

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24. 4, and evaporated. The residue was purified by flash chromatography (hexane/ethyl acetate = 10:1) to afford the known compound, -1-phenyl-3-buten-1-ol (64.7 mg, 71% ee, 96%): ee was determined by HPLC (254 nm); Daicel Chiral Cell OD-H 0.46 cm φ × 25 cm; hexane/iso-propanol = 19:1; flow rate=0.3 mL/min); retention time: 26.4 min for (R)-1-phenyl-3-buten-1-ol, 28.7 min for (S)-1-phenyl-3-buten-1-ol.
25. 3
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