Enantioselective Allylation of Aldehydes with (Dialkoxyallyl)chromium(III) Complexes

Journal of Organic Chemistry

Volumn 62, Issue 8, 1997, Pages 2322-2323

  Sugimoto, Kazuyuki ^a   Aoyagi, Sakae ^a   Kibayashi, Chihiro ^a  

^a TOKYO UNIVERSITY OF PHARMACY AND LIFE SCIENCES   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001567540     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo970069y     Document Type: Article

References (16)

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3. For recent reviews on the use of organochromium compounds in carbon-carbon bond-forming reactions, see: (a) Cintas, P. Synthesis 1992, 248. (b) Saccomamo, N. A. In Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon Press: Oxford, 1991; Vol. 2, pp 173-209. (c) Hodgson, D. M. J. Organomet. Chem. 1994, 476, 1.
4. For recent reviews on the use of organochromium compounds in carbon-carbon bond-forming reactions, see: (a) Cintas, P. Synthesis 1992, 248. (b) Saccomamo, N. A. In Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon Press: Oxford, 1991; Vol. 2, pp 173-209. (c) Hodgson, D. M. J. Organomet. Chem. 1994, 476, 1.
5. For recent reviews on the use of organochromium compounds in carbon-carbon bond-forming reactions, see: (a) Cintas, P. Synthesis 1992, 248. (b) Saccomamo, N. A. In Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon Press: Oxford, 1991; Vol. 2, pp 173-209. (c) Hodgson, D. M. J. Organomet. Chem. 1994, 476, 1.
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8. For asymmetric allylation by other metals, see: Yanagisawa, A.; Nakashima, H.; Ishiba, A.; Yamamoto, H. J. Am. Chem. Soc. 1996, 118, 4723 and references cited therein.
9. O'Brien, P. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCieverty, J. A., Eds.; Pergamon Press: Oxford, 1987; Vol. 3, p 737.
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11. Adams, R. W.; Bishop, E.; Martin, R. L.; Winter, G. Aust. J. Chem. 1966, 19, 207. Also see: Horvath, B.; Horvath, E. G. Z. Anorg. Allg. Chem. 1979, 457, 51.
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16. 4, and concentrated. The crude product was purified by column chromatography on silica gel to give the homoallylic alcohol with the chemical and optical yields reported in Tables 1 and 2.