Superacid catalyzed hydroxyalkylation of aromatics with ethyl trifluoropyruvate: A new synthetic route to Mosher's acid analogs

Synlett

Volumn , Issue 4, 2003, Pages 527-531

  Prakash, G K Surya ^a   Yan, Ping ^a   Török, Béla ^a   Olah, George A ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

Author keywords

Friedel Crafts hydroxyalkylation; Gallium triflate; Mosher's acid; Trifluoromethanesulfonic acid; trifluoromethyl alcohol

Indexed keywords

ACETIC ACID DERIVATIVE; ALPHA HYDROXY ALPHA TRIFLUOROMETHYL PHENYL ACETIC ACID ETHYL ESTER; AROMATIC COMPOUND; BENZENE DERIVATIVE; GALLIUM TRIFLUOROMETHANESULFONATE; PYRUVIC ACID DERIVATIVE; TRIFLUOROMETHANESULFONIC ACID; TRIFLUOROPYRUVIC ACID ETHYL ESTER; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL MODIFICATION; CHEMICAL REACTION; CHEMICAL STRUCTURE; FRIEDEL CRAFTS REACTION; SYNTHESIS;

EID: 0037232079     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2003-37517     Document Type: Article

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31. 3): δ 168.5, 137.6, 137.5, 131.2, 126.8, 123.0 (q, J = 284.8 Hz), 80.3 (q, J= 30.2 Hz), 61.7, 21.6, 21.5, 19.4, 12.6.