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Volumn 41, Issue 26, 2002, Pages 6973-6985

Electronic spectra and structures of d2 molybdenum-oxo complexes. Effects of structural distortions on orbital energies, two-electron terms, and the mixing of singlet and triplet states

Author keywords

[No Author keywords available]

Indexed keywords

LIGAND; METAL COMPLEX; MOLYBDENUM COMPLEX; PHOSPHINE DERIVATIVE;

EID: 0037203103     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic020565r     Document Type: Article
Times cited : (22)

References (96)
  • 2
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    • Hille, R. Chem. Rev. 1996, 96, 2757-2816.
    • (1996) Chem. Rev. , vol.96 , pp. 2757-2816
    • Hille, R.1
  • 60
    • 0012124332 scopus 로고    scopus 로고
    • Full details are available in the Supporting Information
    • Full details are available in the Supporting Information.
  • 64
    • 0012119266 scopus 로고    scopus 로고
    • Unpublished results
    • (a) Da Re, R. E. Unpublished results.
    • Da Re, R.E.1
  • 68
    • 0012192581 scopus 로고    scopus 로고
    • note
    • xy (as for IIa) in this section.
  • 70
    • 0012119472 scopus 로고    scopus 로고
    • note
    • 2.
  • 74
    • 0012158434 scopus 로고    scopus 로고
    • note
    • + ions fall within the 1.657-1.696 Å range for six-coordinate Mo(IV) monooxo complexes (19 entries in the Cambridge Structural Database, version 5.21 (April 2001)).
  • 75
    • 0012157663 scopus 로고    scopus 로고
    • note
    • + (Table 2) is uncertain, being tied to the unknown adequacy of the model for the disordered carbon-atom positions.
  • 77
  • 82
    • 0012124335 scopus 로고    scopus 로고
    • note
    • 2O.
  • 83
    • 0012155873 scopus 로고    scopus 로고
    • note
    • + ion. A detailed analysis of these features, the interpretation of which is not germane to the subject of this paper, is provided in the Supporting Information.
  • 86
    • 0012118796 scopus 로고    scopus 로고
    • note
    • yz) = 0.1155-(eσ(dmpe)) + 2.347(-eπ(dmpe)).
  • 87
    • 0012118797 scopus 로고    scopus 로고
    • note
    • 3)).
  • 88
    • 0012157665 scopus 로고    scopus 로고
    • note
    • yz orbitals remain degenerate.
  • 92
    • 0012124336 scopus 로고    scopus 로고
    • Unpublished results
    • Da Re, R. E. Unpublished results.
    • Da Re, R.E.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.