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85085719204
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3 ̌(CH) bands cancel; these data are included in Table 1.
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75
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85085718623
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note
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2 in this region under our experimental conditions.
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80
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33645935844
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note
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38 In the present study low-frequency vibrational features sensitive to methylidyne deuteration are not observed, but it is possible that the methylidyne rocking mode, like λ(W≡C-H), is very weak in the Raman spectra.
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84
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0005456636
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0342284220
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McDowell, R. S.; Radziemski, L. J.; Flicker, H.; Galbraith, H. W.; Kennedy, R. C.; Nereson, N. G.; Krohn, B. J.; Aldridge, J. P.; King, J. D.; Fox, K. J. Chem. Phys. 1978, 69, 1513-1521.
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-1 feature than does Cl-W≡C bending in that calculated H/D shifts are much smaller. The calculated shifts (Table 2) for the Cl-W≡C bend (which could alternatively be described as the methylidyne rocking mode of footnote 37) are so large as to confirm that this mode has not been experimentally located.
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99
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33645936156
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note
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Because ffr is neglected, the PED is completely described by the single quantity plotted in Figure 7. That is, %R plus 5r in each of the stretching modes is equal to 100, and the sum of %R (and also of %r) over the two stretching modes is equal to 100. The PED for the A bending mode is 100% X because no other e-symmetry modes are considered.
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101
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0030550703
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One striking feature of these data is that M≡N bond distances are approximately 0.05 A shorter than M≡O bond distances for a given force constant. This systematic effect violates the basic assumption of a row-row bond-distance/force-constant correlation.
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103
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33845278743
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85085719580
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64
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110
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0001584926
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A brief review of some of these studies is provided in: McKean, D. C. Croat. Chem. Acta 1988, 67, 447-461.
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121
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85085718387
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note
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CH)].
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