Controlled photochemical release of nitric oxide from O2-naphthylmethyl- and O2-naphthylallyl-substituted diazeniumdiolates

Journal of the American Chemical Society

Volumn 124, Issue 43, 2002, Pages 12640-12641

  Bushan, K Mani ^a   Xu, Hua ^a   Ruane, Patrick H ^a   D'Sa, Raechelle A ^a   Pavlos, Christopher M ^a   Smith, Joseph A ^a   Celius, Tevye C ^a   Toscano, John P ^a  

^a JOHNS HOPKINS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANION; NAPHTHYL GROUP; NITRIC OXIDE;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL STRUCTURE; PHOTOCHEMISTRY; PHOTOLYSIS; PHOTOSENSITIVITY; REACTION ANALYSIS;

EID: 0037202221     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja027957h     Document Type: Article

References (22)

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3. For a recent review of NO-donor chemistry, see: Wang, P. G.; Xian, M.; Tang, X.; Wu, X.; Wen, Z.; Cai, T.; Janczuk, A. J. Chem. Rev. 2002, 102, 1091-1134.
4. Srinivasan, A.; Kebede, N.; Saavedra, J. E.; Nikolaitchik, A. V.; Brady, D. A.; Yourd, E. Y.; Davies, K. M.; Keefer, L. K.; Toscano, J. P. J. Am. Chem. Soc. 2001, 123, 5465-5472.
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6. A full characterization of the photochemistry of diazeniumdiolates 1 will soon be reported: D'Sa, R. A.; Ruane, P. H.; Kumar, N. A.; Relyea, H. A.; Toscano, J. P. Manuscript in preparation.
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21. 4
22. -1) that tails out to A = 0 at approximately 400 nm. It is soluble up to 20 μM in 95% aqueous acetonitrile and is stable at room temperature in pH 2, 7, and 11 solutions for at least 24 h. We are currently developing derivatives of 6 with enhanced water solubility; these results will be reported in due course.