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Volumn 124, Issue 43, 2002, Pages 12697-12705

Structural, luminescence, and NMR studies of the reversible binding of acetate, lactate, citrate, and selected amino acids to chiral diaqua ytterbium, gadolinium, and europium complexes

Author keywords

[No Author keywords available]

Indexed keywords

AMINES; CHELATION; COMPLEXATION; CRYSTAL STRUCTURE; LUMINESCENCE; NITROGEN COMPOUNDS; NUCLEAR MAGNETIC RESONANCE; POLARIZATION; POSITIVE IONS; PROTEINS;

EID: 0037202136     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja020836x     Document Type: Article
Times cited : (244)

References (57)
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    • 2O, pD 6, 295 K), a second species (ca. 30% of the major one) was observed at higher frequency that sharpened but did not shift position significantly at pD 9. It may tentatively be assigned to the diastereoisomer of that depicted in the X-ray structure, with a A helicity and a (λλλλ) configuration for the NCCN macrocyclic chelate rings (cf. Figure 1).
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