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2O, pD 6, 295 K), a second species (ca. 30% of the major one) was observed at higher frequency that sharpened but did not shift position significantly at pD 9. It may tentatively be assigned to the diastereoisomer of that depicted in the X-ray structure, with a A helicity and a (λλλλ) configuration for the NCCN macrocyclic chelate rings (cf. Figure 1).
-
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44
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0033597628
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1H NMR analysis of the ring protons in a twisted square antiprismatic geometry that follow a different shift sequence, see: Aime, S.; Barge, A.; Bruce, J. I.; Botta, M.; Howard, J. A. K.; Moloney, J. M.; Parker, D.; de Sousa, A. S.; Woods, M. J. Am. Chem. Soc. 1999, 121, 5672. Woods, M.; Aime, S.; Botta, M.; Howard, J. A. K.; Moloney, J. M.; Navet, M.; Parker, D.; Port, M.; Rousseaux, O. J. Am. Chem. Soc. 2000, 122, 9781.
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1H NMR analysis of the ring protons in a twisted square antiprismatic geometry that follow a different shift sequence, see: Aime, S.; Barge, A.; Bruce, J. I.; Botta, M.; Howard, J. A. K.; Moloney, J. M.; Parker, D.; de Sousa, A. S.; Woods, M. J. Am. Chem. Soc. 1999, 121, 5672. Woods, M.; Aime, S.; Botta, M.; Howard, J. A. K.; Moloney, J. M.; Navet, M.; Parker, D.; Port, M.; Rousseaux, O. J. Am. Chem. Soc. 2000, 122, 9781.
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