NMR, relaxometric, and structural studies of the hydration and exchange dynamics of cationic lanthanide complexes of macrocyclic tetraamide ligands

Journal of the American Chemical Society

Volumn 121, Issue 24, 1999, Pages 5762-5771

  Aime, Silvio ^a   Barge, Alessandro ^a   Bruce, James I ^b   Botta, Mauro ^a   Howard, Judith A K ^b   Moloney, Janet M ^b   Parker, David ^b   De Sousa, Alvaro S ^b   Woods, Mark ^b  

^a UNIVERSITY OF TURIN   (Italy)

^b DURHAM UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

LANTHANIDE; MACROCYCLIC COMPOUND; MIANSERIN;

ARTICLE; COMPLEX FORMATION; CRYSTAL STRUCTURE; HYDRATION; HYDROGEN BOND; LIGAND BINDING; MOLECULAR DYNAMICS; NUCLEAR MAGNETIC RESONANCE;

EID: 0033597628     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja990225d     Document Type: Article

References (40)

1. (a) Aime, S.; Botta, M.; Fasano, M.; Terreno, M. Chem. Soc. Rev. 1998, 27, 19.
2. (b) Peters, J. A.; Huskens, J.; Raber, D. J. Prog. NMR Spectrosc. 1996, 28, 283.
3. (c) Lauffer, R. B. Chem. Rev. 1987, 87, 901.
4. (a) Meiboom, S. J. Chem. Phys. 1961, 34, 375.
5. (b) Frey, U.; Merbach, A. E.; Powell, D. H. In Dynamics of Solutions and Fluid Mixtures by NMR; Delpuech, J.-J., Ed.; John Wiley & Sons Ltd.; Chichester, 1995; pp 263-307.
6. Cossy, C.; Helm, A. E.; Merbach, A. E. Inorg. Chem. 1988, 27, 1973.
7. (a) Gonzalez, G.; Powell, H. D.; Tissières, V.; Merbach, A. E. J. Phys. Chem. 1994, 98, 53.
8. (b) Aime, S.; Botta, M.; Fasano, M.; Paoletti, S.; Anelli, P. L.; Uggeri, F.; Virtuani, M. Inorg. Chem. 1994, 33, 4707.
9. (a) Spirlet, M. R.; Rebizant, J.; Loncin, M. F.; Desreux, J. F. Inorg. Chem. 1984, 23, 4278.
10. (b) Harrison, A.; Walker, C. A.; Pereira, K. A.; Parker, D.; Royle, L.; Pulukkody, K.; Norman, T. J. Magn. Reson. Imaging 1993, 11, 761.
11. (c) Parker, D. In Comprehensive Supramolecular Chemistry; Atwood, J. L., Davies J. E. D., MacNicol, D. D., Vögtle, F., Reinhoudt, D. N., Eds.; Pergamon: Oxford, 1996; Vol. 10, pp 487-536.
12. (a) Amin, S.; Morrow, J. R.; Lake, C. H.; Churchill, M. R. Angew. Chem., Int. Ed. Engl. 1994, 33, 773.
13. (b) Parker, D.; Williams, J. A. G. J. Chem. Soc., Perkin Trans. 2 1995, 1305.
14. (c) Dickins, R. S.; Howard, J. A. K.; Lehmann, C. W., Moloney, J. M.; Parker, D.; Peacock, R. D. Angew. Chem., Int. Ed. Engl. 1997, 521.
15. Dickins, R. S.; Parker, D.; de Sousa, A. S.; Williams, J. A. G. Chem. Commun. 1996, 697. Beeby, A.; Clarkson, I. M.; Dickins, R. S.; Faulkner, S.; Parker, D.; Royle, L.; de Sousa, A. S.; Williams, J. A. G. J. Chem. Soc., Perkin Trans. 2 1999, 493.
16. Dickins, R. S.; Parker, D.; de Sousa, A. S.; Williams, J. A. G. Chem. Commun. 1996, 697. Beeby, A.; Clarkson, I. M.; Dickins, R. S.; Faulkner, S.; Parker, D.; Royle, L.; de Sousa, A. S.; Williams, J. A. G. J. Chem. Soc., Perkin Trans. 2 1999, 493.
17. Aime, S.; Barge, S.; Botta, S.; Parker, D.; de Sousa, A. S. J. Am. Chem. Soc. 1997, 119, 4767.
18. Aime, S.; Barge, A.; Botta, M.; Parker, D.; de Sousa, A. S. Angew. Chem., Int. Ed. Engl. 1998, 37, 2673.
19. DOTAM = 1,4,7,10-tetrakis[carbamoylmethyl]-1,4,7,10-tetraazacyclododecane, 2; DTMA = 1,4,7,10-tetrakis[(N-methylcarbarnoyl)methyl]-1,4,7,10-tetraazacydododecane, 3; DOTTA = 1,4,7,10-tetrakis[(N,N-dimethylcarbamoyl)methyl]-1,4,7,10-tetraazacyclododecane, 4.
20. Kataky, R.; Matthes, K. E.; Nicholson, P. E.; Parker, D.; Buschmann, H. J. J. Chem. Soc., Perkin Trans. 2 1990, 1425.
21. Alderighi, L.; Bianchi, A.; Calabi, L.; Dapporto, P.; Giorgi, C.; Losi, P.; Pateari, L.; Paoli, P.; Rossi, P.; Valtancoli, B.; Virtuani, M. Eur. J. Inorg. Chem. 1998, 1581.
22. (a) Dubost, J. P.; Leger, M.; Langlois, M.-H.; Meyer, D.; Schaefer, M. C. R. Acad. Sci., Paris, Ser. 2 1991, 312, 349.
23. (b) Parker, D.; Pulukkody, K.; Smith, F. C.; Batsanov, A. S.; Howard, J. A. K. J. Chem. Soc., Dalton Trans. 1994, 689.
24. (c) Aime, S.; Barge, A.; Botta, M.; Fasano, M.; Ayala, J. D.; Bombieri, G. Inorg. Chim. Acta 1996, 246, 423.
25. Aime, S.; Batsanov, A. S.; Botta, M.; Dickins, R. S.; Faulkner, S.; Foster, C. E.; Harrison, A.; Howard, J. A. K.; Moloney, J. M.; Norman, T. J.; Parker, D.; Royle, L.; Williams, J. A. G. J. Chem. Soc., Dalton Trans. 1997, 3623.
26. Aime, S.; Botta, M.; Parker, D.; Senanayake, K.; Williams, J. A. G.; Batsanov, A. S.; Howard, J. A. K. Inorg. Chem. 1994, 33, 4696.
27. Maumela, H., Hancock, R. D.; Carlton, C.; Reibenspies, J. H.; Wainwright, K. P. J. Am. Chem. Soc. 1995, 117, 6698.
28. Amin, S., Voss, D. A.; Horrocks, W. de W.; Lake, C. H.; Churchill, M. R.; Morrow, J. R. Inorg. Chem. 1995, 34, 3294.
29. Dickens, R. S.; Howard, J. A. K.; Maupin, C. L.; Moloney, J. M.; Parker, D.; Peacock, R. D.; Riehl, J. P.; Siligardi, G. New. J. Chem. 1998, 891.
30. Aime, S.; Botta, M.; Fasano, M.; Harques, M. P. M.; Geraldes, C. F. G. C.; Pubanz, D.; Merbach, A. E. Inorg. Chem. 1997, 36, 2059.
31. Aime, S.; Botta, M.; Ermondi, G. Inorg. Chem. 1992, 31, 4291.
32. Howard, J. A. K.; Kenwright, A. K.; Moloney, J. M.; Parker, D.; Port, M.; Navet, M.; Rousseau, O.; Woods, M. Chem. Commun. 1998, 1381.
33. Spirlet, M.; Rebizant, J.; Desreux, J. F.; Loncin, M.-F. Inorg. Chem. 1984, 23, 359.
34. Hoeft, S.; Roth, K. Chem. Ber. 1993, 126, 869.
35. Frey, U.; Merbach, A. E.; Powell, D. H. In Dynamics of Solutions and Fluid Mixtures by NMR; Delpuech, J.-J., Ed.; John Wiley & Sons Ltd.: Chichester, 1995; pp 263-307.
36. 4 symmetry.
37. Bányai, I.; Glaser, J.; Read, M. C.; Sandström, M. Inorg. Chem. 1995, 34, 2423.
38. Bruker Analytical X-Ray Instruments (1998) SHELX96: suite of programs for data reduction, solution, and refinement of crystal structures.
39. Bernasconi, C. F. Relaxation Kinetics; Academic Press: New York, 1976; p 51.
40. Hertz, H. G.; Versmold, H.; Yoon, C. Ber. Bunsen-Ges. Phys. Chem. 1983, 87, 577.