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Volumn , Issue 17, 1999, Pages 1699-1700

Stereodifferentiation and base-pair selectivity in the binding of Δ and Λ cationic lanthanide complexes to [(CG)6]2, [(AT)6]2 and CT-DNA

Author keywords

[No Author keywords available]

Indexed keywords

CATION; LANTHANIDE;

EID: 0033533557     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a904257a     Document Type: Article
Times cited : (32)

References (15)
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    • 1b complexes of Eu, Tb and Yb possess the Δ configuration. The Yb complex possesses a reduced helicity about the metal centre (ca. 29 vs. 40° for Eu/Tb), associated with its twisted square-anti-prismatic solution structure. VT-Proton NMR studies have confirmed that > 97% of one isomeric species exists in solution in each case: for a related example, see A. S. Batsanov, A. Beeby, J. I. Brace, J. A. K. Howard, A. M. Kenwright and D. Parker, Chem. Commun., 1999, 1011.
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    • 2 may exist as an alternating structure termed 'wrinkled D': A. Rich, A. Nordheim and A. H.-J. Wang, Annu. Rev. Biochem., 1984, 53, 791; S. Arnott, R. Chandreasekaran, D. W. L. Hukins, P. J. C. Smith and L. Watts, J. Mol. Biol, 1974, 88, 523; R. Chandrasekaran and S. Arnott, in Landolt-Bornstein New Series VII/1b, ed. W. Saenger, Springer-Verlag, New York, 1989, pp. 31-70.
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    • 2 may exist as an alternating structure termed 'wrinkled D': A. Rich, A. Nordheim and A. H.-J. Wang, Annu. Rev. Biochem., 1984, 53, 791; S. Arnott, R. Chandreasekaran, D. W. L. Hukins, P. J. C. Smith and L. Watts, J. Mol. Biol, 1974, 88, 523; R. Chandrasekaran and S. Arnott, in Landolt-Bornstein New Series VII/1b, ed. W. Saenger, Springer-Verlag, New York, 1989, pp. 31-70.
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