Nonlinear effects and auto-induction in the asymmetric aldol condensation of synthetic equivalents of acetoacetic esters

Tetrahedron Asymmetry

Volumn 13, Issue 18, 2002, Pages 1949-1952

  Villano, Rosaria ^a   De Rosa, Margherita ^a   Salerno, Concetta ^a   Soriente, Annunziata ^a   Scettri, Arrigo ^a  

^a UNIVERSITY OF SALERNO   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

ACETOACETIC ACID DERIVATIVE; ALCOHOL DERIVATIVE; ALKADIENE; ESTER DERIVATIVE; TITANIUM DERIVATIVE;

ARTICLE; ASYMMETRIC CATALYSIS; CATALYST; CHEMICAL REACTION; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; NONLINEAR SYSTEM; POLYMERIZATION; PRIORITY JOURNAL;

EID: 0037145006     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(02)00539-6     Document Type: Article

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25. 8c (90% yield, 24% e.e.).
26. It is noteworthy that in the experiments performed with silyloxydienes 1 and 2 in the presence of Ti(IV)/(R)-BINOL (100% e.e.) complex, the corresponding aldols (R)-4 and (R)-5 were respectively obtained in 93% yield (>99% e.e.) and 81% yield (96% e.e.).