Voltammetry of electroactive oil droplets: Electrochemically-induced ion insertion, expulsion and reaction processes at microdroplets of N,N,N′,N′-tetraalkyl-para-phenylenediamines (TRPD, R = n-butyl, n-hexyl, n-heptyl and n-nonyl)

Journal of Physical Chemistry B

Volumn 106, Issue 37, 2002, Pages 9619-9632

  Wadhawan, Jay D ^a   Evans, Russell G ^a   Banks, Craig E ^a   Wilkins, Shelley J ^a   France, Robert R ^a   Oldham, Neil J ^a   Fairbanks, Antony J ^a   Wood, Bill ^b   Walton, David J ^b   Schröder, Uwe ^c   Compton, Richard G ^a  

^a UNIVERSITY OF OXFORD   (United Kingdom)

^b Institute for Clean Growth and Future Mobility   (United Kingdom)

^c UNIVERSITY OF GREIFSWALD   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLIC VOLTAMMETRY; ELECTRODES; ELECTROLYTES; OXIDATION; REDOX REACTIONS; SOLUTIONS;

MICRODROPLETS;

ELECTROCHEMISTRY;

EID: 0037136777     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp020679o     Document Type: Article

References (54)

1. See, for example: Welton, T. Chem. Rev. 1999, 99, 2071.
2. Earle, M.J.; Seddon, K.R. Pure Appl. Chem. 2000, 72, 1391.
3. See for example Every, H.; Bishop, A.G.; Forsythe, M.; MacFarlane, Electrochim. Acta 2000, 45, 1279.
4. McEwen, A.B.; Ngo, H.L.; LeCompte, K.; Goldman, J.L. J. Electrochem. Soc. 1999, 146, 1687.
5. Gajar, S.A.; Geis, M.W. J. Electrochem. Soc. 1992, 139, 2833.
6. Goldman, J.L.; McEwen, A.B. Electrochem. Solid State Lett. 1999, 2, 501.
7. Bonhôte, P.; Dias, A.P.; Papageorgiou, N.; Kalyanasundaram, M.; Grätzel, M. Inorg. Chem. 1996, 35, 1168.
8. Marken, F.; Webster, R.D.; Bull, S.D.; Davies, S.G., J. Electroanal. Chem. 1997, 437, 209.
9. Marken, F.; Compton, R.G.; Goeting, C.H.; Foord, J.S.; Bull, S.D.; Davies, S.G. Electroanalysis 1998, 10, 821.
10. Marken, F.; Blythe, A.N.; Compton, R.G.; Bull, S.D.; Davies, S.G. Chem. Commun. 1999, 1823.
11. Marken, F.; Blythe, A.N.; Wadhawan, J.D.; Compton, R.G.; Bull, S.D.; Aplin, R.T.; Davies, S.G. J. Solid. State Electrochem. 2001, 5, 17.
12. (a) Fulian, Q.; Ball, J.C.; Marken, F.; Compton, R.G.; Fisher, A.C. Electroanalysis 2000, 12, 1012.
13. (b) Ball, J.C.; Marken, F.; Fulian, Q.; Wadhawan, J.D.; Blythe, A.N.; Schröder, U.; Compton, R.G.; Bull, S.D.; Davies, S.G. Electroanalysis 2000, 12, 1017.
14. Wadhawan, J.D.; Compton, R.G.; Marken, F.; Bull, S.D.; Davies, S.G. J. Solid State Electrochem. 2001, 5, 301.
15. Marken, F.; Compton, R.G.; Goeting, C.H.; Foord, J.S.; Bull, S.D.; Davies, S.G. J. Solid State Electrochem. 2001, 5, 88.
16. Schröder, U.; Compton, R.G.; Marken, F.; Bull, S.D.; Davies, S.G.; Gilmour, S. J. Phys. Chem. B 2001, 105, 1344.
17. Marken, F.; Hayman, C.M.; Bulman Page, P.C. Electroanalysis 2002, 14, 172.
18. Schröder, U.; Wadhawan, J.D.; Evans, R.G.; Compton, R.G.; Wood, B.; Walton, D.J.; France, R.R.; Marken, F.; Bulman Page, P.C.; Hayman, C.M. J. Phys. Chem. B, in press.
19. Scholz, F.; Meyer, B. In Electroanal. Chem.; Bard, A.J., Rubinstein, I., Eds.; Vol. 20; Marcel Dekker: New York, 1998.
20. Monk, P.M.S.; Mortimer, R.J.; Rosseinsky, D.R. Electrochromism: Fundamentals and Applications; Weinheim-VCH: New York, 1995.
21. Rosslee, C.A.; Abbott, N.L. Anal. Chem. 2001, 73, 4808.
22. Mälkiä, A.; Liljeroth, P.; Kontturi, A.-K.; Kontturi, K. J. Phys. Chem. B, 2001, 105, 10 884.
23. Lawrence, N.S.; Davis, J.; Jiang, L.; Jones, T.G.J.; Davies, S.N.; Compton, R.G. Electroanalysis 2000, 12, 1453.
24. Lawrence, N.S.; Davis, J.; Jiang, L.; Jones, T.G.J.; Davies, S.N.; Compton, R.G. Analyst 2000, 125, 661.
25. Lawrence, N.S.; Davis, J.; Marken F.; Jiang, L.; Jones, T.G.J.; Davies, S.N.; Compton, R.G. Sens. Acts. B 2000, 69, 189.
26. Lawrence, N.S.; Davis, J.; Jiang, L.; Jones, T.G.J.; Davies, S. N.; Compton, R.G. Electroanalysis 2001, 13, 432.
27. White, P.C.; Lawrence, N.S.; Davis, J.; Compton, R.G. Anal. Chim. Acta 2001, 447, 1.
28. Lawrence, N.S.; Thompson, M.; Davis, J.; Jiang, L.; Jones, T.G. J.; Compton, R.G. Mikrochim. Acta 2001, 137, 105.
29. Lawrence, N.S.; Wadhawan, J.D.; Compton, R.G., Foundations of Physical Chemistry: Worked Examples; Oxford University Press: Oxford, 1999; pp 140-2.
30. Ball, J.C., D.Phil. Thesis, University of Oxford, 2000.
31. See for example, Lee, H.J.; Fermin, D.J.; Corn, R.M.; Girault, H.H. Electrochem. Commun. 1999, 1, 190.
32. Lawrence, N.S.; Thompson, M.; Davis, J.; Jiang, L.; Jones, T.G. J.; Compton, R.G. Chem. Commun. 2002, 1028.
33. Marken, F.; Compton, R.G. Electrochim. Acta 1997, 43, 2157.
34. Scholz, F.; Kormorsky-Lovrić, Š.; Lovrić, M. Electrochem. Commun. 2000, 2, 112.
35. Kormorsky-Lovrić, Š.; Lovrić, M.; Scholz, F. J. Electroanal. Chem. 2001, 508, 129.
36. Gulaboski, R.; Mirčeski, V.; Scholz, F. Electrochem. Commun. 2002, 4, 277.
37. Gergely, A.; Inzelt, G. Electrochem. Commun. 2001, 3, 753.
38. Donten, M.; Stojek, Z.; Scholz, F. Electrochem. Commun. 2002, 4, 324.
39. Wadhawan, J.D.; Marken, F.; Compton, R.G. Pure Appl. Chem. 2001, 73, 1947.
40. -3
41. This is contrary to what was reported earlier (ref 11). This is probably due to an instrument artifact-see for example ref 15; the data reported in Figure 8c were recorded using an analogue instrument.
42. See for example Hammereich, O.; Parker, V.D. Adv. Phys. Org. Chem. 1984, 20, 55.
43. Nickel, U.; Borchardt, M.; Bapat, M.R.; Jaenicke, W. Ber. Bunsenges. Phys. Chem. 1979, 83, 8773.
44. Nickel, U.; Jaenicke, W. Ber. Bunsenges. Phys. Chem. 1982, 86, 695.
45. See for example http://dcwww.epfl.ch/cgi-bin/LE/DB/InterrDB.pl This is a very good compendium of Gibbs energies for ion transfer across liquid|liquid interfaces complied from a variety of literature sources by Hubert Girault, Ecole Polytechnique Fédérale de Lausanne.
46. See for example Greenwood, N.N.; Earnshaw, A. Chemistry of the Elements; Pergamon Press: Oxford; 1984.
47. Savéant, J.-M. J. Phys. Chem. B, 2001, 105, 8995.
48. (a) Krienke, H.; Barthel, J. Exp. Thermodyn. 2000, 5, 751.
49. (b) Dupont, J.; Consorti, C.S.; Spencer, J. J. Braz. Chem. Soc. 2000, 11, 337.
50. Wadhawan, J.D.; Marken, F.; Compton, R.G., unpublished results, University of Oxford, 2000.
51. Terui, N.; Nakatani, K.; Kitamura, N. J. Electroanal. Chem. 2000, 494, 41.
52. Marcus, Y. Pure Appl. Chem. 1983, 55, 977.
53. Workentin, M.S.; Parker, V.D.; Morkin, T.L.; Wayner, D.D. M. J. Phys. Chem. A 1998, 102, 6503.
54. Magnus, P.; Lacour, J.; Weber, W. J. Am. Chem. Soc. 1993, 115, 9347.