Effect of ion pairing on the mechanism and rate of electron transfer. Electrochemical aspects

Journal of Physical Chemistry B

Volumn 105, Issue 37, 2001, Pages 8995-9001

  Savéant, Jean Michel ^a  

^a UNIVERSITÉ PARIS DIDEROT   (France)

Author keywords

[No Author keywords available]

Indexed keywords

QUANTUM CHEMISTRY;

CHEMICAL BONDS; DISSOCIATION; OXIDATION; REDUCTION; THERMODYNAMICS;

ELECTROCHEMISTRY;

EID: 0035922535     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp011374x     Document Type: Article

References (54)

1. Swarc, M. Ions and Ion pairs in Organic Reactions; Wiley-Interscience: New York, 1972, 1974; Vols. 1 and 2.
2. Peover, M.E.; Davies, J.D. J. Electroanal. Chem. 1963, 6, 46.
3. Fujinaga, T.; Izutsu, K.; Nomura, T. J. Electroanal. Chem. 1971, 29, 333.
4. (a) Kalinovski, M.K. Chem. Phys. Lett. 1970, 7, 55.
5. (b) Kalinovski, M.K. Chem. Phys. Lett. 1971, 8, 378.
6. (c) Lasia, A.; Kalinovski, M.K. J. Electroanal. Chem. 1972, 36, 511.
7. (d) Kalinovski, M.K.; Tenderende-Guminska, J. Electroanal. Chem. 1974, 55, 227.
8. (e) Kapturkiewicz. J. Phys. Chem. 1978, 82, 1141.
9. Holleck, L.; Levine, S. J. Electroanal. Chem. 1973, 43, 175.
10. Krygovski, T.M.; Lipsztajn, Y.; Galus, Z. J. Electroanal. Chem. 1973, 42, 261.
11. (a) Ryan, M.D.; Evans, D.H. J. Electrochem. Soc. 1974, 121, 881.
12. (b) Ryan, M.D.; Evans, D.H. J. Electroanal. Chem. 1976, 67, 333.
13. (c) Evans, D.H. J. Phys. Chem. B 1998, 102, 9928.
14. (d) Evans, D.H.; Lehmann, M.W. Acta Chem. Scand. 1999, 53, 765.
15. Hazelrigg, M.J.; Bard, A.J. J. Electrochem. Soc. 1975, 122, 211.
16. (a) Chauhan, B.G.; Fawcett, W.R.; Lasia, A. J. Phys. Chem. 1977, 81, 1476.
17. (b) Fawcett, W.R.; Lasia, A. J. Phys. Chem. 1978, 82, 1114.
18. (c) Fawcett, W.R.; Lasia, A. Can. J. Chem. 1981, 59, 3256.
19. (d) Andreu, R.; Calvente, J.J.; Fawcett, W.R.; Molero, M. J. Phys. Chem. B 1997, 101, 2884.
20. (a) Andrieux, C.P.; Savéant, J.-M. Savéant, J. Electroanal. Chem. 1974, 57, 27.
21. (b) Andrieux, C.P.; Robert, M.; Savéant, J.-M. J. Am. Chem. Soc. 1995, 117, 9340.
22. Hapiot, P.; Konovalov, V.; Savéant, J.-M. J. Am. Chem. Soc. 1995, 117, 1428.
23. Garst, J.F.; Ungvary, F. Mechanism of Grignard Reagent Formation. In Grignard Reagents: New Developments; Ricbey, H.G., Ed.; Wiley: Chichester, U.K., 2000; pp 185-275.
24. (a) Dickinson, E.; Williams, M.R.; Hendrickson, M.R.; Masui, H.; Murray, R.W. J. Am. Chem. Soc. 1999, 121, 613.
25. (b) Williams, M.R.; Masui, H.; Murray, R.W. J. Phys. Chem. B 2000, 104, 10699.
26. Marcus, R.A. J. Phys. Chem. B 1998, 102, 10071.
27. (a) Marcus, R.A. J. Chem. Phys. 1956, 24, 966.
28. (b) Marcus, R.A. J. Chem. Phys. 1956, 24, 979.
29. (c) Marcus, R.A. J. Chem. Phys. 1956, 24, 4966.
30. (d) Hush, N.S. J. Chem. Phys. 1958, 28, 962.
31. (e) Marcus, R.A. J. Chem. Phys. 1965, 43, 679.
32. (f) Marcus, R.A. In Special Topics in Electrochemistry; Rock, P.A., Ed.; Elsevier: New York, 1977; pp 161-179.
33. 16c.
34. (b) Bard, A.J.; Faulkner, L.R. Electrochemical Methods. Fundamentals and Applications. Wiley: New York, 2001; p 331.
35. (c) Bard, A.J.; Fanlkner, L.R. Electrochemical Methods. Fundamentals and Applications. Wiley: New York, 2001; pp 168-176.
36. (a) Savéant, J.-M.; Tessier, D. J. Electroanal. Chem. 1975, 65, 57.
37. (b) Sayéant, J.-M.; Tessier, D. J. Phys. Chem. 1977, 81, 2192.
38. Antonello, S.; Musumeci, M.; Wayner, D.D.M.; Maran, F. J. Am. Chem. Soc. 1997, 119, 9541.
39. Workentin, M.S.; Donkers, R.L. J. Am. Chem. Soc. 1998, 120, 2664.
40. (a) Savéant, J.-M. Single Electron Transfer and Nucleophilic Substitution In Advances in Physical Organic Chemistry; Bethel, D., Ed.; Academic Press: New York, 1990; Vol. 26, pp 1-130.
41. (b) Savéant, J.-M. Dissociative Electron Transfer. In Advances in Electron Transfer Chemistry; Mariano, P.S., Ed.; JAI Press: New York, 1994; Vol. 4, pp 53-116.
42. Nadjo, L.; Savéant, J.-M. J. Electroanal. Chem. 1973, 48, 113.
43. Andrieux, C.P.; Sayéant, J.-M. In Electrochemical Reactions in Investigation of Rates and Mechanisms of Reactions, Techniques of Chemistry; Bernasconi, C.F., Ed.; Wiley: New York, 1986; Vol. VI/4E, Part 2, pp 305-390.
44. 26b.
45. (b) Debye, P. Trans. Electrochem. Soc. 1942, 82, 265.
46. Savéant, J.-M.; Vianello, E. Electrochim. Acta 1963, 8, 905.
47. Savéant, J.-M. Electron Transfer, Bond Breaking and Bond Formation. In Advances in Physical Organic Chemistry; Tidwell, T.T., Ed.; Academic Press: New York, 2000; Vol. 35, pp 117-192.
48. Savéant, J.-M. J. Am. Chem. Soc. 1987, 109, 6788.
49. (b) Savéant, J.-M. J. Am. Chem. Soc. 1992, 114, 10595.
50. (a) Becke, A.D.J. Chem. Phys. 1993, 98, 5648.
51. (b) Hariharan, P.C.; Pople, J.A. Chem. Phys. Lett. 1972, 16, 217.
52. Frisch, M.J.; Trucks, G.W.; Schlegel, H.B.; Scuseria, G.E.; Robb, M.A.; Cheeseman, J.R.; Zakrzewski, V.G.; Montgomery, J.A., Jr.; Stratmann, R.E.; Burant, J.C.; Dapprich, S.; Millam, J.M.; Daniels, A.D.; Kudin, K.N,; Strain, M.C.; Farkas, O.; Tomasi, J.; Barone, V.; Cossi, M.; Cammi, R.; Mennucci, B.; Pomelli, C.; Adamo, C.; Clifford, S.; Ochterski, J.; Petersson, G.A.; Ayala, P.Y.; Cui, Q.; Morokuma, K.; Malick, D.K.; Rabuck, A.D.; Raghavachari, K.; Foresman, J.B.; Cioslowski, J.; Ortiz, J.V.; Stefanov, B.B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Gomperts, R.; Martin, R.L.; Fox, D.J.; Keith, T.; Al-Laham, M.A.; Peng, C.Y.; Nanayakkara, A.; Gonzalez, C.; Challacombe, M.; Gill, P.M.W.; Johnson, B.G.; Chen, W.; Wong, M.W.; Andres, J.L.; Head-Gordon, M.; Replogle, E.S.; Pople, J.A. Gaussian 98, revision A.1; Gaussian, Inc.: Pittsburgh, PA, 1998.
53. (a) Cossi, M.; Barone, V.; Cammi, R.; Tomasi, J. Chem. Phys. Lett. 1996, 255, 327.
54. (b) For a general review about solvation methods, see: Cramer, J. Truhlar, D.G. Chem. Rev. 1999, 99, 2161.