Chemistry of a binuclear cadmium(II) hydroxide complex: Formation from water, CO2 reactivity, and comparison to a zinc analog

Inorganic Chemistry

Volumn 41, Issue 25, 2002, Pages 6790-6801

  Allred, Russell A ^a   McAlexander, Lenore H ^b   Arif, Atta M ^c   Berreau, Lisa M ^a  

^a UTAH STATE UNIVERSITY   (United States)

^b IDAHO STATE UNIVERSITY   (United States)

^c UNIVERSITY OF UTAH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CADMIUM DERIVATIVE; CARBON DIOXIDE; CARBONIC ACID DERIVATIVE; HYDROXIDE; LIGAND; METAL COMPLEX; WATER; ZINC DERIVATIVE;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; COMPLEX FORMATION; CRYSTAL STRUCTURE; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0037121869     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0258072     Document Type: Article

References (62)

1. (a) Rominger, F.; Thewalt, U. Z. Naturforsch., B 1996, 51, 1716-1724.
2. (b) Müller, S.; Thewalt, U. Collect. Czech. Chem. Commun. 1997, 62, 257-264.
3. (c) Weidenbruch, M.; Herrndorf, M.; Schäfer, A.; Pohl, S.; Saak, W. J. Organomet. Chem. 1989, 361, 139-145.
4. (d) Duhme, A.-K.; Strasdeit, H. Eur. J. Inorg. Chem. 1998, 657-662.
5. (e) Konno, T.; Kageyama, Y.; Okamoto, K. Bull. Chem. Soc. Jpn. 1994, 67, 1957-1960.
6. (f) Forniés, J.; Gómez, J.; Lalinde, E.: Moreno, M. T. Inorg. Chem. 2001, 40, 5415-5419.
7. (a) Ito, H.; Ito, T. Acta Crystallogr., Sect. C 1985, 41, 1598-1602.
8. (b) Pariya, C.; Puranik, V. G.; Chaudhuri, N. R. Chem. Commun. 1997, 1307-1308.
9. (a) Phosphotriesterase: Benning, M. M.; Shim, H.; Raushel, F. M.; Holden, H. M. Biochemistry 2001, 40, 2712-2722.
10. (b) Metallo-β-lactamase: Concha, N. O.: Rasmussen, B. A.; Bush, K.; Herzberg, O. Protein Sci. 1997, 6, 2671-2676.
11. (a) Cullen, J. T.; Lane, T. W.; Morel, F. M. M.; Sherrell, R. M. Nature 1999, 402, 165-167.
12. (b) Lane, T. W.; Morel, F. M. M. Proc. Natl. Acad. Sci. U.S.A. 2000, 97, 4627-4631.
13. (c) Strasdeit, H. Angew. Chem., Int. Ed. 2001, 40, 707-709.
14. Saito, M. A.; Lane, T. W.; Morel, F. M. M. Abstracts of Papers, 223rd National Meeting of the American Chemical Society, Orlando, FL, Spring 2002; American Chemical Society: Washington, DC, 2002; INOR 35.
15. (a) Hammes, B. S.; Young, V. G., Jr.; Borovik, A. S. Angew. Chem., Int. Ed. 1999, 38, 666-669.
16. (b) MacBeth, C. E.; Golombek, A. P.; Young, V. G., Jr.; Yang, C.; Kuczera, K.; Hendrich, M. P.; Borovik, A. S. Science 2000, 289, 938-941.
17. (c) Shirin, Z.; Hammes, B. S.; Young, V. G., Jr.; Borovik, A. S. J. Am. Chem. Soc. 2000, 122, 1836-1837.
18. (d) MacBeth, C. E.; Hammes, B. S.; Young, V. G., Jr.; Borovik, A. S. Inorg. Chem. 2001, 40, 4733-4741.
19. (e) Gupta, R.; MacBeth, C. E.; Young, V. G., Jr.; Borovik, A. S. J. Am. Chem. Soc. 2002, 124, 1136-1137.
20. Harata, M.; Jitsukawa, K.; Masuda, H.; Einaga, H. Chem. Lett. 1996, 813-814.
21. Berreau, L. M.; Allred, R. A.; Makowska-Grzyska, M. M.; Arif, A. M. Chem. Commun. 2000, 1423-1424.
22. Allred, R. A.; Arif, A. M.; Berreau, L. M. J. Chem. Soc., Dalton Trans. 2002, 300-301.
23. Armarego, W. L. F.; Perrin, D. D. Purification of Laboratory Chemicals, 4th Ed.; Butterworth-Heinemann: Boston, MA, 1996.
24. Wolsey, W. C. J. Chem. Educ. 1973, 50, A335-A337.
25. Garner, D. K.; Allred, R. A.; Arif, A. M.; Berreau, L. M. Inorg. Chem. 2002, 41, 3533-3541.
26. Otwinowski, Z.; Minor, W. Methods Enzymol. 1997, 276, 307-326.
27. Coetzee, J. F.; Cunningham, G. P. J. Am. Chem. Soc. 1965, 87, 2529-2534.
28. Geary, W. J. Coord. Chem. Rev. 1971, 7, 81-122.
29. Feltham, R. D.; Hayter, R. G. J. Chem. Soc. 1964, 4587-4591.
30. 3CN ligands: (a) Adams, H.; Bastida, R.; Fenton, D. E.; Macias, A.; Spey, S. E.; Valencia, L. Inorg. Chem. 1999, 2, 513-515. (b) Adams, H.; Bastida, R.; Fenton, D. E.; Macias, A.; Spey, S. E.; Valencia, L. J. Chem. Soc., Dalton Trans. 1999, 4131-4137. (c) Li, S.-L.; Zhang, Z.-Z.; Mak, T. C. W. Inorg. Chim. Acta 1998, 268, 177-187. (d) Adams, H.; Bailey, N. A.; Fenton, D. E.; Ford, I. G.; Kitchen, S. J.; Williams, M. G.; Tasker, P. A.; Leong, A. J.; Lindoy, L. F. J. Chem. Soc., Dalton Trans. 1991, 1665-1674. (e) Bebout, D. C.; Stokes, S. W.; Butcher, R. J. Inorg. Chem. 1999, 38, 1126-1133. (f) Brooker, S.; Bertel, N.; Stalke, D.; Noltemeyer, M.; Roesky, H. W.; Sheldrick, G. M.; Edelmann, F. T. Organometallics 1992, 11, 192-195. (g) Barnett, S. A.; Blake, A. J.; Champness, N. R.; Nicolson, J. E. B.; Wilson, C. J. Chem. Soc., Dalton Trans. 2001, 567-573. (h) Kitazawa, T.; Kikuyama, T.; Ugajin, H.; Takahashi, M.; Takeda, M. J. Coord. Chem. 1996, 37, 17-22.
31. 3CN ligands: (a) Adams, H.; Bastida, R.; Fenton, D. E.; Macias, A.; Spey, S. E.; Valencia, L. Inorg. Chem. 1999, 2, 513-515. (b) Adams, H.; Bastida, R.; Fenton, D. E.; Macias, A.; Spey, S. E.; Valencia, L. J. Chem. Soc., Dalton Trans. 1999, 4131-4137. (c) Li, S.-L.; Zhang, Z.-Z.; Mak, T. C. W. Inorg. Chim. Acta 1998, 268, 177-187. (d) Adams, H.; Bailey, N. A.; Fenton, D. E.; Ford, I. G.; Kitchen, S. J.; Williams, M. G.; Tasker, P. A.; Leong, A. J.; Lindoy, L. F. J. Chem. Soc., Dalton Trans. 1991, 1665-1674. (e) Bebout, D. C.; Stokes, S. W.; Butcher, R. J. Inorg. Chem. 1999, 38, 1126-1133. (f) Brooker, S.; Bertel, N.; Stalke, D.; Noltemeyer, M.; Roesky, H. W.; Sheldrick, G. M.; Edelmann, F. T. Organometallics 1992, 11, 192-195. (g) Barnett, S. A.; Blake, A. J.; Champness, N. R.; Nicolson, J. E. B.; Wilson, C. J. Chem. Soc., Dalton Trans. 2001, 567-573. (h) Kitazawa, T.; Kikuyama, T.; Ugajin, H.; Takahashi, M.; Takeda, M. J. Coord. Chem. 1996, 37, 17-22.
32. 3CN ligands: (a) Adams, H.; Bastida, R.; Fenton, D. E.; Macias, A.; Spey, S. E.; Valencia, L. Inorg. Chem. 1999, 2, 513-515. (b) Adams, H.; Bastida, R.; Fenton, D. E.; Macias, A.; Spey, S. E.; Valencia, L. J. Chem. Soc., Dalton Trans. 1999, 4131-4137. (c) Li, S.-L.; Zhang, Z.-Z.; Mak, T. C. W. Inorg. Chim. Acta 1998, 268, 177-187. (d) Adams, H.; Bailey, N. A.; Fenton, D. E.; Ford, I. G.; Kitchen, S. J.; Williams, M. G.; Tasker, P. A.; Leong, A. J.; Lindoy, L. F. J. Chem. Soc., Dalton Trans. 1991, 1665-1674. (e) Bebout, D. C.; Stokes, S. W.; Butcher, R. J. Inorg. Chem. 1999, 38, 1126-1133. (f) Brooker, S.; Bertel, N.; Stalke, D.; Noltemeyer, M.; Roesky, H. W.; Sheldrick, G. M.; Edelmann, F. T. Organometallics 1992, 11, 192-195. (g) Barnett, S. A.; Blake, A. J.; Champness, N. R.; Nicolson, J. E. B.; Wilson, C. J. Chem. Soc., Dalton Trans. 2001, 567-573. (h) Kitazawa, T.; Kikuyama, T.; Ugajin, H.; Takahashi, M.; Takeda, M. J. Coord. Chem. 1996, 37, 17-22.
33. 3CN ligands: (a) Adams, H.; Bastida, R.; Fenton, D. E.; Macias, A.; Spey, S. E.; Valencia, L. Inorg. Chem. 1999, 2, 513-515. (b) Adams, H.; Bastida, R.; Fenton, D. E.; Macias, A.; Spey, S. E.; Valencia, L. J. Chem. Soc., Dalton Trans. 1999, 4131-4137. (c) Li, S.-L.; Zhang, Z.-Z.; Mak, T. C. W. Inorg. Chim. Acta 1998, 268, 177-187. (d) Adams, H.; Bailey, N. A.; Fenton, D. E.; Ford, I. G.; Kitchen, S. J.; Williams, M. G.; Tasker, P. A.; Leong, A. J.; Lindoy, L. F. J. Chem. Soc., Dalton Trans. 1991, 1665-1674. (e) Bebout, D. C.; Stokes, S. W.; Butcher, R. J. Inorg. Chem. 1999, 38, 1126-1133. (f) Brooker, S.; Bertel, N.; Stalke, D.; Noltemeyer, M.; Roesky, H. W.; Sheldrick, G. M.; Edelmann, F. T. Organometallics 1992, 11, 192-195. (g) Barnett, S. A.; Blake, A. J.; Champness, N. R.; Nicolson, J. E. B.; Wilson, C. J. Chem. Soc., Dalton Trans. 2001, 567-573. (h) Kitazawa, T.; Kikuyama, T.; Ugajin, H.; Takahashi, M.; Takeda, M. J. Coord. Chem. 1996, 37, 17-22.
34. 3CN ligands: (a) Adams, H.; Bastida, R.; Fenton, D. E.; Macias, A.; Spey, S. E.; Valencia, L. Inorg. Chem. 1999, 2, 513-515. (b) Adams, H.; Bastida, R.; Fenton, D. E.; Macias, A.; Spey, S. E.; Valencia, L. J. Chem. Soc., Dalton Trans. 1999, 4131-4137. (c) Li, S.-L.; Zhang, Z.-Z.; Mak, T. C. W. Inorg. Chim. Acta 1998, 268, 177-187. (d) Adams, H.; Bailey, N. A.; Fenton, D. E.; Ford, I. G.; Kitchen, S. J.; Williams, M. G.; Tasker, P. A.; Leong, A. J.; Lindoy, L. F. J. Chem. Soc., Dalton Trans. 1991, 1665-1674. (e) Bebout, D. C.; Stokes, S. W.; Butcher, R. J. Inorg. Chem. 1999, 38, 1126-1133. (f) Brooker, S.; Bertel, N.; Stalke, D.; Noltemeyer, M.; Roesky, H. W.; Sheldrick, G. M.; Edelmann, F. T. Organometallics 1992, 11, 192-195. (g) Barnett, S. A.; Blake, A. J.; Champness, N. R.; Nicolson, J. E. B.; Wilson, C. J. Chem. Soc., Dalton Trans. 2001, 567-573. (h) Kitazawa, T.; Kikuyama, T.; Ugajin, H.; Takahashi, M.; Takeda, M. J. Coord. Chem. 1996, 37, 17-22.
35. 3CN ligands: (a) Adams, H.; Bastida, R.; Fenton, D. E.; Macias, A.; Spey, S. E.; Valencia, L. Inorg. Chem. 1999, 2, 513-515. (b) Adams, H.; Bastida, R.; Fenton, D. E.; Macias, A.; Spey, S. E.; Valencia, L. J. Chem. Soc., Dalton Trans. 1999, 4131-4137. (c) Li, S.-L.; Zhang, Z.-Z.; Mak, T. C. W. Inorg. Chim. Acta 1998, 268, 177-187. (d) Adams, H.; Bailey, N. A.; Fenton, D. E.; Ford, I. G.; Kitchen, S. J.; Williams, M. G.; Tasker, P. A.; Leong, A. J.; Lindoy, L. F. J. Chem. Soc., Dalton Trans. 1991, 1665-1674. (e) Bebout, D. C.; Stokes, S. W.; Butcher, R. J. Inorg. Chem. 1999, 38, 1126-1133. (f) Brooker, S.; Bertel, N.; Stalke, D.; Noltemeyer, M.; Roesky, H. W.; Sheldrick, G. M.; Edelmann, F. T. Organometallics 1992, 11, 192-195. (g) Barnett, S. A.; Blake, A. J.; Champness, N. R.; Nicolson, J. E. B.; Wilson, C. J. Chem. Soc., Dalton Trans. 2001, 567-573. (h) Kitazawa, T.; Kikuyama, T.; Ugajin, H.; Takahashi, M.; Takeda, M. J. Coord. Chem. 1996, 37, 17-22.
36. 3CN ligands: (a) Adams, H.; Bastida, R.; Fenton, D. E.; Macias, A.; Spey, S. E.; Valencia, L. Inorg. Chem. 1999, 2, 513-515. (b) Adams, H.; Bastida, R.; Fenton, D. E.; Macias, A.; Spey, S. E.; Valencia, L. J. Chem. Soc., Dalton Trans. 1999, 4131-4137. (c) Li, S.-L.; Zhang, Z.-Z.; Mak, T. C. W. Inorg. Chim. Acta 1998, 268, 177-187. (d) Adams, H.; Bailey, N. A.; Fenton, D. E.; Ford, I. G.; Kitchen, S. J.; Williams, M. G.; Tasker, P. A.; Leong, A. J.; Lindoy, L. F. J. Chem. Soc., Dalton Trans. 1991, 1665-1674. (e) Bebout, D. C.; Stokes, S. W.; Butcher, R. J. Inorg. Chem. 1999, 38, 1126-1133. (f) Brooker, S.; Bertel, N.; Stalke, D.; Noltemeyer, M.; Roesky, H. W.; Sheldrick, G. M.; Edelmann, F. T. Organometallics 1992, 11, 192-195. (g) Barnett, S. A.; Blake, A. J.; Champness, N. R.; Nicolson, J. E. B.; Wilson, C. J. Chem. Soc., Dalton Trans. 2001, 567-573. (h) Kitazawa, T.; Kikuyama, T.; Ugajin, H.; Takahashi, M.; Takeda, M. J. Coord. Chem. 1996, 37, 17-22.
37. 3CN ligands: (a) Adams, H.; Bastida, R.; Fenton, D. E.; Macias, A.; Spey, S. E.; Valencia, L. Inorg. Chem. 1999, 2, 513-515. (b) Adams, H.; Bastida, R.; Fenton, D. E.; Macias, A.; Spey, S. E.; Valencia, L. J. Chem. Soc., Dalton Trans. 1999, 4131-4137. (c) Li, S.-L.; Zhang, Z.-Z.; Mak, T. C. W. Inorg. Chim. Acta 1998, 268, 177-187. (d) Adams, H.; Bailey, N. A.; Fenton, D. E.; Ford, I. G.; Kitchen, S. J.; Williams, M. G.; Tasker, P. A.; Leong, A. J.; Lindoy, L. F. J. Chem. Soc., Dalton Trans. 1991, 1665-1674. (e) Bebout, D. C.; Stokes, S. W.; Butcher, R. J. Inorg. Chem. 1999, 38, 1126-1133. (f) Brooker, S.; Bertel, N.; Stalke, D.; Noltemeyer, M.; Roesky, H. W.; Sheldrick, G. M.; Edelmann, F. T. Organometallics 1992, 11, 192-195. (g) Barnett, S. A.; Blake, A. J.; Champness, N. R.; Nicolson, J. E. B.; Wilson, C. J. Chem. Soc., Dalton Trans. 2001, 567-573. (h) Kitazawa, T.; Kikuyama, T.; Ugajin, H.; Takahashi, M.; Takeda, M. J. Coord. Chem. 1996, 37, 17-22.
38. A search of the Cambridge Crystallographic Database (CSD version 5.23, April 2002) revealed 7 examples wherein a cadmium coordination environment contained both a water ligand and nitrogen and sulfur donors: (a) Burshtein, I. F.; Volodina, G. F.; Gerbeleu, N. V.; Bologa, O. A.; Filippova, I. G.; Malinovskii, T. I. Koord. Khim. 1985, 11, 692-695. (b) Rodesiler, P. F.; Charles, N. G.; Griffith, E. A. H.; Amma, E. L. Acta Crystallogr., Sect. C 1987, 43, 1058-1061. (c) Pickardt, J.; Gong, G.-T. Z. Naturforsch., B 1993, 48, 23-26. (d) Griffith, E. A. H.; Amma, E. L. Chem. Commun. 1979, 1013-1014. (e) Baggio, S.; Baggio, R.; Garland, M. T. Acta Crystallogr., Sect. C 1998, 54, 1099-1102. (f) Yang, G.; Zhu, H.-G.; Liang, B.-H.: Chen. X.-M. J. Chem. Soc., Dalton Trans. 2001, 580-585. (g) Casas, J. S.; Castellano, E. E.; Garcia-Tasende, M, S.; Sanchez, A.; Sordo, J.; Zukerman-Schpector, J. Z. Anorg. Allg. Chem. 1997, 623, 825-831.
39. A search of the Cambridge Crystallographic Database (CSD version 5.23, April 2002) revealed 7 examples wherein a cadmium coordination environment contained both a water ligand and nitrogen and sulfur donors: (a) Burshtein, I. F.; Volodina, G. F.; Gerbeleu, N. V.; Bologa, O. A.; Filippova, I. G.; Malinovskii, T. I. Koord. Khim. 1985, 11, 692-695. (b) Rodesiler, P. F.; Charles, N. G.; Griffith, E. A. H.; Amma, E. L. Acta Crystallogr., Sect. C 1987, 43, 1058-1061. (c) Pickardt, J.; Gong, G.-T. Z. Naturforsch., B 1993, 48, 23-26. (d) Griffith, E. A. H.; Amma, E. L. Chem. Commun. 1979, 1013-1014. (e) Baggio, S.; Baggio, R.; Garland, M. T. Acta Crystallogr., Sect. C 1998, 54, 1099-1102. (f) Yang, G.; Zhu, H.-G.; Liang, B.-H.: Chen. X.-M. J. Chem. Soc., Dalton Trans. 2001, 580-585. (g) Casas, J. S.; Castellano, E. E.; Garcia-Tasende, M, S.; Sanchez, A.; Sordo, J.; Zukerman-Schpector, J. Z. Anorg. Allg. Chem. 1997, 623, 825-831.
40. A search of the Cambridge Crystallographic Database (CSD version 5.23, April 2002) revealed 7 examples wherein a cadmium coordination environment contained both a water ligand and nitrogen and sulfur donors: (a) Burshtein, I. F.; Volodina, G. F.; Gerbeleu, N. V.; Bologa, O. A.; Filippova, I. G.; Malinovskii, T. I. Koord. Khim. 1985, 11, 692-695. (b) Rodesiler, P. F.; Charles, N. G.; Griffith, E. A. H.; Amma, E. L. Acta Crystallogr., Sect. C 1987, 43, 1058-1061. (c) Pickardt, J.; Gong, G.-T. Z. Naturforsch., B 1993, 48, 23-26. (d) Griffith, E. A. H.; Amma, E. L. Chem. Commun. 1979, 1013-1014. (e) Baggio, S.; Baggio, R.; Garland, M. T. Acta Crystallogr., Sect. C 1998, 54, 1099-1102. (f) Yang, G.; Zhu, H.-G.; Liang, B.-H.: Chen. X.-M. J. Chem. Soc., Dalton Trans. 2001, 580-585. (g) Casas, J. S.; Castellano, E. E.; Garcia-Tasende, M, S.; Sanchez, A.; Sordo, J.; Zukerman-Schpector, J. Z. Anorg. Allg. Chem. 1997, 623, 825-831.
41. A search of the Cambridge Crystallographic Database (CSD version 5.23, April 2002) revealed 7 examples wherein a cadmium coordination environment contained both a water ligand and nitrogen and sulfur donors: (a) Burshtein, I. F.; Volodina, G. F.; Gerbeleu, N. V.; Bologa, O. A.; Filippova, I. G.; Malinovskii, T. I. Koord. Khim. 1985, 11, 692-695. (b) Rodesiler, P. F.; Charles, N. G.; Griffith, E. A. H.; Amma, E. L. Acta Crystallogr., Sect. C 1987, 43, 1058-1061. (c) Pickardt, J.; Gong, G.-T. Z. Naturforsch., B 1993, 48, 23-26. (d) Griffith, E. A. H.; Amma, E. L. Chem. Commun. 1979, 1013-1014. (e) Baggio, S.; Baggio, R.; Garland, M. T. Acta Crystallogr., Sect. C 1998, 54, 1099-1102. (f) Yang, G.; Zhu, H.-G.; Liang, B.-H.: Chen. X.-M. J. Chem. Soc., Dalton Trans. 2001, 580-585. (g) Casas, J. S.; Castellano, E. E.; Garcia-Tasende, M, S.; Sanchez, A.; Sordo, J.; Zukerman-Schpector, J. Z. Anorg. Allg. Chem. 1997, 623, 825-831.
42. A search of the Cambridge Crystallographic Database (CSD version 5.23, April 2002) revealed 7 examples wherein a cadmium coordination environment contained both a water ligand and nitrogen and sulfur donors: (a) Burshtein, I. F.; Volodina, G. F.; Gerbeleu, N. V.; Bologa, O. A.; Filippova, I. G.; Malinovskii, T. I. Koord. Khim. 1985, 11, 692-695. (b) Rodesiler, P. F.; Charles, N. G.; Griffith, E. A. H.; Amma, E. L. Acta Crystallogr., Sect. C 1987, 43, 1058-1061. (c) Pickardt, J.; Gong, G.-T. Z. Naturforsch., B 1993, 48, 23-26. (d) Griffith, E. A. H.; Amma, E. L. Chem. Commun. 1979, 1013-1014. (e) Baggio, S.; Baggio, R.; Garland, M. T. Acta Crystallogr., Sect. C 1998, 54, 1099-1102. (f) Yang, G.; Zhu, H.-G.; Liang, B.-H.: Chen. X.-M. J. Chem. Soc., Dalton Trans. 2001, 580-585. (g) Casas, J. S.; Castellano, E. E.; Garcia-Tasende, M, S.; Sanchez, A.; Sordo, J.; Zukerman-Schpector, J. Z. Anorg. Allg. Chem. 1997, 623, 825-831.
43. A search of the Cambridge Crystallographic Database (CSD version 5.23, April 2002) revealed 7 examples wherein a cadmium coordination environment contained both a water ligand and nitrogen and sulfur donors: (a) Burshtein, I. F.; Volodina, G. F.; Gerbeleu, N. V.; Bologa, O. A.; Filippova, I. G.; Malinovskii, T. I. Koord. Khim. 1985, 11, 692-695. (b) Rodesiler, P. F.; Charles, N. G.; Griffith, E. A. H.; Amma, E. L. Acta Crystallogr., Sect. C 1987, 43, 1058-1061. (c) Pickardt, J.; Gong, G.-T. Z. Naturforsch., B 1993, 48, 23-26. (d) Griffith, E. A. H.; Amma, E. L. Chem. Commun. 1979, 1013-1014. (e) Baggio, S.; Baggio, R.; Garland, M. T. Acta Crystallogr., Sect. C 1998, 54, 1099-1102. (f) Yang, G.; Zhu, H.-G.; Liang, B.-H.: Chen. X.-M. J. Chem. Soc., Dalton Trans. 2001, 580-585. (g) Casas, J. S.; Castellano, E. E.; Garcia-Tasende, M, S.; Sanchez, A.; Sordo, J.; Zukerman-Schpector, J. Z. Anorg. Allg. Chem. 1997, 623, 825-831.
44. A search of the Cambridge Crystallographic Database (CSD version 5.23, April 2002) revealed 7 examples wherein a cadmium coordination environment contained both a water ligand and nitrogen and sulfur donors: (a) Burshtein, I. F.; Volodina, G. F.; Gerbeleu, N. V.; Bologa, O. A.; Filippova, I. G.; Malinovskii, T. I. Koord. Khim. 1985, 11, 692-695. (b) Rodesiler, P. F.; Charles, N. G.; Griffith, E. A. H.; Amma, E. L. Acta Crystallogr., Sect. C 1987, 43, 1058-1061. (c) Pickardt, J.; Gong, G.-T. Z. Naturforsch., B 1993, 48, 23-26. (d) Griffith, E. A. H.; Amma, E. L. Chem. Commun. 1979, 1013-1014. (e) Baggio, S.; Baggio, R.; Garland, M. T. Acta Crystallogr., Sect. C 1998, 54, 1099-1102. (f) Yang, G.; Zhu, H.-G.; Liang, B.-H.: Chen. X.-M. J. Chem. Soc., Dalton Trans. 2001, 580-585. (g) Casas, J. S.; Castellano, E. E.; Garcia-Tasende, M, S.; Sanchez, A.; Sordo, J.; Zukerman-Schpector, J. Z. Anorg. Allg. Chem. 1997, 623, 825-831.
45. Jeffrey, G. A. An Introduction to Hydrogen Bonding; Oxford University Press: New York, 1997.
46. (a) Allerhand, A.; Schleyer, P. V. R. J. Am. Chem. Soc. 1963, 85, 1233-1237.
47. (b) Steiner, T. Acta Crystallogr., Sect. B 1998, 54, 456-463.
48. Nishio, M.; Umezawa, Y.; Hirota, M.; Takeuchi, Y. Tetrahedron 1995, 51, 8665-8701.
49. Looney, A.; Han, R.; McNeill, K.; Parkin, G. J. Am. Chem. Soc. 1993, 115, 4690-4697.
50. Kleywegt, G. J.; Wiesmeijer, W. G. R.; Van Driel, G. J.; Driessen, W. L.; Reedijk, J.; Noordik, J. H. J. Chem. Soc., Dalton Trans. 1985, 2177-2184.
51. A seven-coordinate pentagonal bipyramidal geometry has been observed in other cadmium complexes: Turner, R. W.; Charles, N. G.; Amma, E. L. Cryst. Struct. Commun. 1982, 11, 241-245.
52. The two thioether sulfur atoms bound to Cd(2) in the X-ray crystal structure of 1 exhibit disorder. Each was split into two fragments and refined. This refinement led to a 0.68:0.32 ratio in occupancy over two positions for each thioether sulfur atom. The Cd(2)-S(3/4) distances given in the text are for the position each sulfur atom occupies 68% of the time in the X-ray structure. The Cd(2)-S(3/4) distances for the minor occupancy S(3a)/S(4a) positions are Cd(2)-S(3a) 2.649(6) Å and Cd(2)-S(4a) 2.718(10) Å. There are also two independent binuclear cations in the asymmetric unit of 1. The average Cd-S distances for the two cations are similar (see Table 2).
53. Dietrich, J.; Heinemann, F. W.; Schrodt, A.; Schindler, S. Inorg. Chim. Acta 1999, 288, 206-209.
54. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th Ed.; Wiley & Sons: New York, 1997.
55. Kitajima, N.; Hikichi, S.; Tanaka, M.; Moro-oka, Y. J. Am. Chem. Soc. 1993, 115, 5496-5508 and also references therein.
56. (a) Armitage, I. M.; Boulanger, Y. NMR Newly Accessible Nucl. 1983, 2, 337-365.
57. (b) Summers, M. F. Coord. Chem. Rev. 1988, 86, 43-134.
58. (c) Reger, D. L.; Mason, S. S.; Rheingold, A. L.; Ostrander, R. L. Inorg. Chem. 1993, 32, 5216-5222.
59. Lippard, S. J.; Berg, J. M. Principles of Bioinorganic Chemistry; University Science Books: Mill Valley, CA, 1994.
60. Holloway, C. E.; Melnik, M. Main Group Met. Chem. 1995, 18, 451-585.
61. (a) Grapperhaus, C. A.; Tuntulani, T.; Reibenspies, J. H.; Darensbourg, M. Y. Inorg. Chem. 1998, 37, 4052-4058.
62. (b) Brand, U.; Rombach, M.; Vahrenkamp, H. Chem. Commun. 1998, 2717-2718.