A unique copper(II)-hydroxide complex derived from copper(II)-superoxide

Chemistry Letters

Volumn , Issue 9, 1996, Pages 813-814

  Harata, Manabu ^a   Jitsukawa, Koichiro ^a   Masuda, Hideki ^a   Einaga, Hisahiko ^a  

^a NAGOYA INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0030376444     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1996.813     Document Type: Article

References (9)

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2. L. L. Ingraham, D. L. Meyer, "Biochemistry of Dioxygen," In "Biochemistry of Elements," ed by E. Frieden, Plenum Press, New York (1985), Vol. 4.
3. "Bioinorganic Chemistry of Copper," ed by K. D. Karlin and Z. Tyeklar, Chapman & Hall, New York (1993).
4. M. Harata, K. Jitsukawa, H. Masuda, and H. Einaga, J. Am. Chem. Soc., 116, 10817 (1994).
5. -1, 2 < 2θ < 120 °. Intensity data collected at room temperature on a Rigaku AFC-5R four-circle diffractometer; structure solved and refined using teXsan program system, absorption correction was applied by DIFABS. 4984 Unique reflections of which 3253 [I > 3σ(I)] were observed. The structure was solved by the heavy-atom method and refined anisotropically. Hydrogen atoms were included in the calculation, but they were not refined except for the hydroxyl hydrogen atom. Final R and Rw values were 0.068 and 0,061, respectively.
6. M. Harata, K. Jitsukawa, H. Masuda, and H. Einaga, Chem. Lett. , 1995, 61.
7. -3, 3 < 2θ < 55 °. Intensity data collected at room temperature on an Enraf - Nonius CAD4 - EXPRESS four - circle diffractometer ; structure solved and refined using SDP-MoIEN program system, absorption correction was applied by DIFABS. 8143 Unique reflections of which 353 1 [I > 3σ(1)] were observed. The structure was solved by the heavy-atom method and refined anisotropically. Hydrogen atoms were included in the calculation, but they were not refined except for the hydroxyl hydrogen atom. Final R and Rw values were 0.065 and 0.078, respectively.
8. I. I. Mathews, S. P. S. Rao, and M. Nethaji, Polyhedron, 11, 1397 (1992).
9. A. Messerschmidt, "Blue Copper Oxidases," In "Advances in Inorganic Chemistry," ed by G. Sykes, Academic Press, New York (1993), Vol. 40.