Exchange properties of the three-dimensional coordination compound 1,3,5-tris(4-ethynylbenzonitrile)benzene · AgO3SCF3

Journal of the American Chemical Society

Volumn 118, Issue 29, 1996, Pages 6946-6953

  Gardner, Geoffrey B ^a   Kiang, Y H ^a   Lee, Stephen ^a   Asgaonkar, Anil ^a   Venkataraman, D ^b  

^a UNIVERSITY OF MICHIGAN   (United States)

^b UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

1,3,5 TRIS(4 ETHYNYLBENZONITRILE)BENZENE SILVER TRIFLATE; BENZYL ALCOHOL; COORDINATION COMPOUND; TOLUENE; UNCLASSIFIED DRUG; UNDECANOIC ACID;

ABSORPTION; ADSORPTION; ARTICLE; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE;

EID: 0029899243     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja960595r     Document Type: Article

References (30)

1. Hoskins, B. F.; Robson, R. J. Am. Chem. Soc. 1990, 112, 1546-1554.
2. Wang, X.; Simard, M.; Wuest, J. D. J. Am. Chem. Soc. 1994, 116, 12119-12120.
3. Fujita, M.; Kwon, Y. J.; Washizu, S.; Ogura, K. J. Am. Chem. Soc. 1994, 116, 1151-1152.
4. Gardner, G. B.; Venkataraman, D.; Moore, J. S.; Lee, S. Nature 1995, 374, 792-795.
5. Venkataraman, D.; Gardner, G.; Lee, S.; Moore, J. S. J. Am. Chem. Soc. 1995, 117, 11600-11601.
6. Yaghi, O. M.; Li G.; Li, H. Nature 1995, 378, 703-706.
7. Yaghi, O. M.; Li, H. J. Am. Chem. Soc. 1996, 188, 295-296.
8. Simard, M.; Su, D.; Wuest, J. D. J. Am. Chem. Soc. 1991, 113, 4696-4698.
9. Kaszynski, P.; Friedli, A. C.; Michl, J. J. Am. Chem. Soc. 1992, 114, 601-620.
10. Venkataraman, D.; Lee, S.; Zhang, J.; Moore, J. S. Nature 1994, 371, 591-593.
11. Endo, K.; Sawaki, T.; Koyanagi, M.; Kobayashi, K.; Masuda, H.; Aoyama, Y. J. Am. Chem. Soc. 1995, 117, 8341-8352.
12. Abrahams, B. F.; Hoskins, B. F.; Michail, D. M.; Robson, R. Nature 1994, 369, 727-729.
13. Subramanian, S.; Zaworotko, M. J. Coord. Chem. Rev. 1994, 137, 357-401.
14. Inclusion Compounds; Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Eds.; Academic Press: London, 1984; Vol. 1-2.
15. Ermer, O.; Lindenberg, L. Helv. Chim. Acta 1991, 74, 825-877.
16. Etter, M. C. Acc. Chem. Res. 1990, 23, 120-126.
17. Fan, E. K.; Yang, J.; Geib, S. J.; Hopkins, M. D.; Hamilton, A. D. J. Chem. Soc., Chem. Commun. 1995, 1251-1252.
18. Ung, A. T.; Gizachew, D.; Bishop, R.; Scudder, M. L.; Dance, I. G. J. Am. Chem. Soc. 1995, 117, 8745-8756.
19. Lee, F.; Gabe, E.; Tse, J. S.; Ripmeester, J. A. J. Am. Chem. Soc. 1988, 110, 6014-6019.
20. 4 forms an interlocking structure for which no inclusion compounds have yet been obtained.
21. 2O. See: Cartaud, P.; Cointot, A.; Renaud, A. J. Chem. Soc., Faraday Trans. 1 1981, 77, 1561.
22. Schwer, H.; Keller, E.; Krämer, V. Z. Kristallogr. 1993, 204, 203-213.
23. 2 Chemical Simulations Software Package; Molecular Simulation Inc.; Burlington, MA, 1994.
24. Wells, A. F. Structural Inorganic Chemistry; Oxford University Press: New York, 1993; pp Chapter 3.
25. Carlucci, L.; Ciani, G.; Proserpio, D. M.; Sironi, A. J. Am. Chem. Soc. 1995, 117, 4562-4569.
26. Desiraju, G. R.; Gavezzotti, A. Acta Crystallogr. 1989, B45, 473-482.
27. Examples of optical microscopy of the host crystal both before and after exchange are included in the supplementary materials.
28. Spek, A. L. J. Appl. Crystallogr. 1988, 21, 578-579.
29. Measurement by this technique was complicated by the difficulty of "drying" the sample so the slowly evaporating included benzene would remain with the sample while benzene on the exterior of the channels would be excluded from the initial weight. It was decided that a lower bound could be obtained by measuring the sample after the powder itself appeared dry.
30. 3: C, 57.46; H, 2.44; N, 5.63; Ag, 15.2. Found: C, 56.16; H, 2.44; N, 5.63; Ag, 14.5.