Quinoxaline-bridged porphyrinoids

Journal of the American Chemical Society

Volumn 124, Issue 45, 2002, Pages 13474-13479

  Sessler, Jonathan L ^a   Maeda, Hiromitsu ^a,b,c   Mizuno, Toshihisa ^a   Lynch, Vincent M ^a   Furuta, Hiroyuki ^b,c  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

^b KYOTO UNIVERSITY   (Japan)

^c KYUSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

MACROCYCLES;

CONDENSATION; SALTS; SUBSTITUTION REACTIONS; X RAY ANALYSIS;

DERIVATIVES;

ANION; FLUORIDE; MACROCYCLIC COMPOUND; PHOSPHATE; PORPHYRIN DERIVATIVE; PYRROLE; QUINOXALINE DERIVATIVE; TETRABUTYLAMMONIUM;

ARTICLE; BINDING AFFINITY; MASS SPECTROMETRY; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; X RAY ANALYSIS; X RAY DIFFRACTION;

ANIONS; ANTHRACENES; CRYSTALLOGRAPHY, X-RAY; MODELS, MOLECULAR; PORPHYRINS; QUINOXALINES;

EID: 0037073214     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0273750     Document Type: Article

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33. 3 are bound by Schiff-base-N (C-H···N, 3.271 Å) and the neighboring macrocycle-derived pyrrolyl-NH atoms (Cl···H-N, 3.706 Å.
34. 5a but remains an area of current interest and study.
35. The binding constants for 3b-c and dihydrogenphosphate proved too low to measure accurately. So, in this report, only 3a was used for quantitative analyses involving this anion. The low affinities seen for 3b and 3c are consistent with the known electron-donating (and anion affinity reducing) ability of alkoxy groups. See: ref 7b.
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46. 6b,c
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