Coordination of allenyl/propargyl group to samarium(III): The first crystal structures of η3-allenyl and η1-propargyl lanthanide complexes

Journal of Organometallic Chemistry

Volumn 613, Issue 1, 2000, Pages 26-32

  Ihara, Eiji ^a   Tanaka, Motomi ^a   Yasuda, Hajime ^a   Kanehisa, Nobuko ^b   Maruo, Tatsuya ^b   Kai, Yasushi ^b  

^a HIROSHIMA UNIVERSITY   (Japan)

^b OSAKA UNIVERSITY   (Japan)

Author keywords

Crystal structure; Samarium; 1 propargyl; 3 allenyl; 5 cyclopentadienyl

Indexed keywords

EID: 0003110463     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(00)00479-4     Document Type: Article

References (14)

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10. Because of the poor quality of the X-ray analysis data of 2a and 2b, we report only the ORTEP drawings for these complexes (Figs. 1 and 2) in this paper. The full data for 2a and 2b have been deposited with CCDC.
11. NMR spectra of solutions of single crystals of these complexes indicated that these complexes existed as equilibrium mixtures.
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