Esterification by immobilized lipase in solvent-free media: Kinetic and thermodynamic arguments

Biotechnology and Bioengineering

Volumn 78, Issue 3, 2002, Pages 313-320

  Sandoval, G ^a   Condoret, J S ^b   Monsan, P ^a   Marty, A ^a  

^a UMR792 INGÉNIERIE DES SYSTÈMES BIOLOGIQUES ET DES PROCÉDÉS   (France)

^b LABORATOIRE DE GÉNIE CHIMIQUE   (France)

Author keywords

Esterification; Immobilized enzyme; Lipase; Solvent free medium; Water activity

Indexed keywords

CATALYSIS; ESTERIFICATION; ETHANOL; OLEIC ACID; ORGANIC SOLVENTS; SUBSTRATES; THERMODYNAMICS;

MOLAR RATIO;

ENZYME IMMOBILIZATION;

ALCOHOL; HEXANE; OLEIC ACID; ORGANIC SOLVENT; SOLVENT; TRIACYLGLYCEROL LIPASE;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CONCENTRATION (PARAMETERS); ENZYME IMMOBILIZATION; ENZYME KINETICS; ENZYME STABILITY; ENZYME SUBSTRATE; ESTERIFICATION; MASS; RECYCLING; THERMODYNAMICS; VOLUMETRY; WATER CONTENT;

ENZYMES, IMMOBILIZED; ESTERIFICATION; ETHANOL; HEXANES; KINETICS; LIPASE; OLEIC ACID; SOLVENTS; THERMODYNAMICS; WATER;

SANDFLY FEVER SICILIAN VIRUS;

EID: 0037023905     PISSN: 00063592     EISSN: None     Source Type: Journal    
DOI: 10.1002/bit.10224     Document Type: Article

References (27)

1. Enzymology in non-conventional media
2. Optimization of lipase-catalyzed synthesis of (z)-3-hexen-1-yl acetate by direct esterification in hexane and a solvent-free medium
3. Biocatalysis in organic media
4. Kinetic study of esterification by immobilized lipase in n-hexane
5. Water activity control: A way to improve the efficiency of continuous lipase esterification
6. Prediction of water adsorption curves for heterogeneous biocatalysis in organic and supercritical solvents
7. Enzymatic synthesis with mainly undissolved substrates at very high concentrations
8. Kinetics of enzymatic solid-to-solid peptide synthesis: Intersubstrate compound, substrate ratio, and mixing effects
9. Production of glycerides from glycerol and fatty acid immobilized lipases in non-aqueous media
10. The nature of fatty acid modifies equilibrium position in the esterification catalyzed by lipase
11. Optimization of lipase-catalyzed synthesis of citronellyl acetate in solvent-free medium
12. Enzymatic ester synthesis with continuous measurement of water activity
13. Engineering biocatalytic systems in organic media with low water content
14. Production of medium-chain glycerides by immobilized lipase in a solvent-free system
15. Rules for optimization of biocatalysis in organic solvents
16. 2
17. Continuous reaction-separation process for enzymatic esterification in supercritical carbon dioxide
18. In search of practical esterification
19. Thermodynamic activity based enzyme kinetics: An efficient tool for prediction of enzyme kinetics in non-aqueous media
20. Esterification and interesterification activities of lipases from Rhizopus niveus and Mucor miehei in three different types of organic media: Comparative study
21. Do organic-solvents affect the catalytic properties of lipase? Intrinsic kinetic-parameters of lipases in ester hydrolysis and formation in various organic solvents
22. Enzyme-catalyzed processes in organic solvents
23. The effect of water on enzyme action in organic media