Functionalization of carbon nanotubes with polystyrene

Macromolecules

Volumn 35, Issue 25, 2002, Pages 9466-9471

  Hill, Darron E ^a   Lin, Yi ^a   Rao, Apparao M ^b   Allard, Lawrence F ^c   Sun, Ya Ping ^a  

^a AMRL   (United States)

^b CLEMSON UNIVERSITY   (United States)

^c OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON NANOTUBES; CARBOXYLIC ACIDS; COPOLYMERS; ESTERIFICATION; ORGANIC SOLVENTS; SOLUBILITY;

FUNCTIONALIZATION; WET-CASTING METHOD;

POLYSTYRENES;

EID: 0037016087     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma020855r     Document Type: Article

References (36)

1. (a) Ajayan, P. M. Chem. Rev. 1999, 99, 1787.
2. (b) Ajayan, P. M.; Zhou, O. Z. Top. Appl. Phys. 2001, 80, 391.
3. (a) Ajayan P. M.; Stephan, O.; Colliex, C.; Trauth, D. Science 1994, 265, 1212.
4. (b) Ajayan, P. M.; Schadler, L. S.; Giannaris, C.; Rubio, A. Adv. Mater. 2000, 12, 750.
5. Ago, H.; Petritsch, K.; Shaffer, M. S. P.; Windle, A. H.; Friend, R. H. Adv. Mater. 1999, 11, 1281.
6. (a) Curran, S. A.; Ajayan, P. M.; Blau, W. J.; Carroll, D. L.; Coleman, J. N.; Dalton, A. B.; Davey, A. P.; Drury, A.; McCarthy, B.; Maier, S.; Strevens, A. Adv. Mater. 1998, 10, 1091.
7. (b) Coleman, J. N.; Curran, S.; Dalton, A. B. Davey, A. P.; McCarthy, B.; Blau, W.; Barklie, R. C. Synth. Met. 1999, 102, 1174.
8. Gao, M.; Huang, S. M.; Dai, L. M.; Wallace, G.; Gao, R. P.; Wang, Z. L. Angew. Chem., Int. Ed. 2000 39 3664.
9. Star, A.; Stoddard, J. F.; Steuerman, D.; Diehl, M.; Boukai, A.; Wong E. W.; Yang, X.; Chung, S. W.; Choi, H.; Heath, J. R. Angew. Chem., Int. Ed. 2001, 40, 1721.
10. Cochet, M.; Maser, W. K.; Benito, A. M.; Callejas, M. A.; Martinez, M. T.; Benoit, J. M.; Schreiber, J.; Chauvet, O. Chem. Commun. 2001, 1451.
11. (a) Qian, D.; Dickey, E. C.; Andrews, R.; Rantell, T. Appl. Phys. Lett. 2000, 76, 2868.
12. (b) Qian, D.; Dickey, E. C. J. Microsc. 2001, 204, 39,
13. (c) Grimes, C. A.; Dickey, E. C.; Mungle, C.; Ong, K. G; Qian, D. J. Appl. Phys. 90, 4134.
14. Safadi, B.; Andrews, R.; Grulke, E. A. J. Appl. Polym. Sci. 2002, 84, 2660.
15. Liao, K.; Li, S. Appl. Phys. Lett. 2001, 79, 4225.
16. Watts, P. C. P.; Hsu, W. K.; Chen, G. Z.; Fray, D. J.; Kroto, H. W.; Walton, D. R. M. J. Mater. Chem. 2001, 11, 2482.
17. Tang, B. Z.; Xu, H. Macromolecules 1999, 32, 2569.
18. O'Connell, M. J.; Boul, P.; Ericson, L. M.; Huffman, C.; Wang, Y. H.; Haroz, E.; Kuper, C.; Tour, J.; Ausman, K. D.; Smalley, R. E. Chem. Phys. Lett. 2001, 342, 265.
19. Hamon, M. A.; Hu, H.; Bhowmik, P.; Niyogi, S.; Zhao, B.; Itkis, M. E.; Haddon, R. C. Chem. Phys. Lett. 2001, 347, 8.
20. Sun, Y.-P.; Fu, K.; Lin, Y.; Huang, W. Acc. Chem. Res., submitted.
21. Chen, J.; Hamon, M. A.; Hu, H.; Chen, Y.; Rao, A. M.; Eklund, P. C.; Haddon, R. C. Science 1998, 282, 98.
22. Chen, J.; Rao, A. M.; Lyuksyutov, S.; Itkis, M. E.; Hamon, M. A.; Hu, H.; Cohn, R. W.; Eklund, P. C.; Colbert, D. T.; Smalley, R. E.; Haddon, R. C. J. Phys. Chem. B 2001, 105, 2525.
23. (a) Niyogi, S.; Hu, H.; Hamon, M. A.; Bhowmik, P.; Zhao, B.; Rozenzhak, S. M.; Chen, J.; Itkis, M. E.; Meier, M. S.; Haddon, R. C. J. Am. Chem. Soc. 2001, 123, 733.
24. (b) Zhao, B.; Hu, H.; Niyogi, S.; itkis, M. E.; Hamon, M. A.; Bhowmik, P.; Meier, M. S.; Haddon, R. C. J. Am. Chem. Soc. 2001, 123, 11673.
25. (a) Sun, Y.-P.; Huang, W.; Lin, Y.; Fu, K.; Kitaygorodskiy, A.; Riddle, L. A.; Yu, Y. J.; Carroll, D. L. Chem. Mater. 2001, 13, 2864.
26. (b) Fu, K.; Huang, W.; Lin, Y.; Riddle, L. A.; Carroll, D. L.; Sun, Y.-P. Nano Lett. 2001, 1, 439.
27. (a) Riggs, J. E.; Guo Z.; Carroll, D. L.; Sun, Y.-P. J. Am. Chem. Soc. 2000, 122, 5879.
28. (b) Riggs, J. E.; Walker, D. B.; Carroll, D. L.; Sun, Y.-P. J. Phys. Chem. B 2000, 104, 7071.
29. (c) Czerw, R.; Guo, Z. X.; Ajayan, P. M.; Sun, Y.-P.; Carroll, D. L. Nano Lett. 2001, 1, 423.
30. (a) Lin, Y.; Rao, A. M.; Sadanadan, B.; Kenik, E. A.; Sun, Y. -P. J. Phys. Chem. B 2002, 106, 1294.
31. (b) Huang, W.; Lin, Y.; Taylor, S.; Gaillard, J.; Rao, A. M.; Sun, Y.-P. Nano Lett. 2002, 2, 231.
32. Liu, J.; Rinzler, A. G.; Dai, H.; Hafner, J. H.; Bradley, R. K.; Boul, P. J.; Lu, A.; Lverson, T.; Shelimov, K.; Huffman, C. B.; Rodriguez-Macias, F.; Shon, Y.-S.; Lee, T. R.; Colbert, D. T.; Smalley, R. E. Science 1998, 280, 1253.
33. 24 though the effect in this work is the same as that of a classical hydrolysis reaction.
34. Lamparth, I.; Hirsch, A. J. Chem. Soc., Chem. Commun. 1994, 1727.
35. According to these results, the estimated degree of functionalization is on the order of 10 -15 PSV chains per 1000 nanotube carbons for both SWNTs and MWNTs.
36. The solid species recovered from centrifuging were partially soluble in chlorobenzene. The solution thus obtained was added to the parent solution.