Diverse catalytic activity of the cationic actinide complex [(Et2N)3U][BPh4] in the dimerization and hydrosilylation of terminal alkynes. Characterization of the first f-element alkyne π-complex [(Et2N)2U(CCtBu)(η2-HCC tBu)][BPh4]

Journal of Organometallic Chemistry

Volumn 604, Issue 1, 2000, Pages 83-98

  Dash, Aswini K ^a   Wang, Jia Xi ^a   Berthet, Jean Claude ^b   Ephritikhine, Michel ^b   Eisen, Moris S ^a  

^a TECHNION ISRAEL INSTITUTE OF TECHNOLOGY   (Israel)

^b CNRS   (France)

Author keywords

Alkyne complexes; Catalysis; Dimerization of alkynes; Hydrosilylation; Organoactinide; Complexes

Indexed keywords

EID: 0002410738     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(00)00207-2     Document Type: Article

References (145)

1. For general organolanthanide reviews, see: (a) R. Anwander, W.A. Herrman, Top. Curr. Chem. 179 (1996) 1. (b) F.T. Edelmann, Top. Curr. Chem. 179 (1996) 247. (c) H. Schumann, J.A. Meese-Marktscheffel, L. Esser, Chem. Rev. 95 (1995) 865 and references therein. (d) C.J. Schaverien, Adv. Organomet. Chem. 36 (1994) 283 and references therein. (e)W.J. Evans, Adv. Organomet. Chem. 24 (1985) 131 and references therein. (f) H.B. Kagan, J.L. Namy, in: K.A. Gschneider, L. Eyring (Eds.), Handbook on the Physics and Chemistry of Rare Earths, Elsevier, Amsterdam, 1984 (Chapter 50). (g) T.J. Marks, R.D. Ernst, in: G. Wilkinson, F.G.A. Stone, E.W. Abel (Eds.), Comprehensive Organometallic Chemistry, Pergamon Press, Oxford, UK, 1982 (Chapter 21) and references therein. (h) H. Schumann, in: T.J. Marks, I. Fragala (Eds.), Fundamental and Technological Aspects of Organo-f-Element Chemistry, Reidel, Dordrecht, Holland, 1985 (Chapter 1).
2. For general organolanthanide reviews, see: (a) R. Anwander, W.A. Herrman, Top. Curr. Chem. 179 (1996) 1. (b) F.T. Edelmann, Top. Curr. Chem. 179 (1996) 247. (c) H. Schumann, J.A. Meese-Marktscheffel, L. Esser, Chem. Rev. 95 (1995) 865 and references therein. (d) C.J. Schaverien, Adv. Organomet. Chem. 36 (1994) 283 and references therein. (e)W.J. Evans, Adv. Organomet. Chem. 24 (1985) 131 and references therein. (f) H.B. Kagan, J.L. Namy, in: K.A. Gschneider, L. Eyring (Eds.), Handbook on the Physics and Chemistry of Rare Earths, Elsevier, Amsterdam, 1984 (Chapter 50). (g) T.J. Marks, R.D. Ernst, in: G. Wilkinson, F.G.A. Stone, E.W. Abel (Eds.), Comprehensive Organometallic Chemistry, Pergamon Press, Oxford, UK, 1982 (Chapter 21) and references therein. (h) H. Schumann, in: T.J. Marks, I. Fragala (Eds.), Fundamental and Technological Aspects of Organo-f-Element Chemistry, Reidel, Dordrecht, Holland, 1985 (Chapter 1).
3. For general organolanthanide reviews, see: (a) R. Anwander, W.A. Herrman, Top. Curr. Chem. 179 (1996) 1. (b) F.T. Edelmann, Top. Curr. Chem. 179 (1996) 247. (c) H. Schumann, J.A. Meese-Marktscheffel, L. Esser, Chem. Rev. 95 (1995) 865 and references therein. (d) C.J. Schaverien, Adv. Organomet. Chem. 36 (1994) 283 and references therein. (e)W.J. Evans, Adv. Organomet. Chem. 24 (1985) 131 and references therein. (f) H.B. Kagan, J.L. Namy, in: K.A. Gschneider, L. Eyring (Eds.), Handbook on the Physics and Chemistry of Rare Earths, Elsevier, Amsterdam, 1984 (Chapter 50). (g) T.J. Marks, R.D. Ernst, in: G. Wilkinson, F.G.A. Stone, E.W. Abel (Eds.), Comprehensive Organometallic Chemistry, Pergamon Press, Oxford, UK, 1982 (Chapter 21) and references therein. (h) H. Schumann, in: T.J. Marks, I. Fragala (Eds.), Fundamental and Technological Aspects of Organo-f-Element Chemistry, Reidel, Dordrecht, Holland, 1985 (Chapter 1).
4. For general organolanthanide reviews, see: (a) R. Anwander, W.A. Herrman, Top. Curr. Chem. 179 (1996) 1. (b) F.T. Edelmann, Top. Curr. Chem. 179 (1996) 247. (c) H. Schumann, J.A. Meese-Marktscheffel, L. Esser, Chem. Rev. 95 (1995) 865 and references therein. (d) C.J. Schaverien, Adv. Organomet. Chem. 36 (1994) 283 and references therein. (e)W.J. Evans, Adv. Organomet. Chem. 24 (1985) 131 and references therein. (f) H.B. Kagan, J.L. Namy, in: K.A. Gschneider, L. Eyring (Eds.), Handbook on the Physics and Chemistry of Rare Earths, Elsevier, Amsterdam, 1984 (Chapter 50). (g) T.J. Marks, R.D. Ernst, in: G. Wilkinson, F.G.A. Stone, E.W. Abel (Eds.), Comprehensive Organometallic Chemistry, Pergamon Press, Oxford, UK, 1982 (Chapter 21) and references therein. (h) H. Schumann, in: T.J. Marks, I. Fragala (Eds.), Fundamental and Technological Aspects of Organo-f-Element Chemistry, Reidel, Dordrecht, Holland, 1985 (Chapter 1).
5. For general organolanthanide reviews, see: (a) R. Anwander, W.A. Herrman, Top. Curr. Chem. 179 (1996) 1. (b) F.T. Edelmann, Top. Curr. Chem. 179 (1996) 247. (c) H. Schumann, J.A. Meese-Marktscheffel, L. Esser, Chem. Rev. 95 (1995) 865 and references therein. (d) C.J. Schaverien, Adv. Organomet. Chem. 36 (1994) 283 and references therein. (e)W.J. Evans, Adv. Organomet. Chem. 24 (1985) 131 and references therein. (f) H.B. Kagan, J.L. Namy, in: K.A. Gschneider, L. Eyring (Eds.), Handbook on the Physics and Chemistry of Rare Earths, Elsevier, Amsterdam, 1984 (Chapter 50). (g) T.J. Marks, R.D. Ernst, in: G. Wilkinson, F.G.A. Stone, E.W. Abel (Eds.), Comprehensive Organometallic Chemistry, Pergamon Press, Oxford, UK, 1982 (Chapter 21) and references therein. (h) H. Schumann, in: T.J. Marks, I. Fragala (Eds.), Fundamental and Technological Aspects of Organo-f-Element Chemistry, Reidel, Dordrecht, Holland, 1985 (Chapter 1).
6. For general organolanthanide reviews, see: (a) R. Anwander, W.A. Herrman, Top. Curr. Chem. 179 (1996) 1. (b) F.T. Edelmann, Top. Curr. Chem. 179 (1996) 247. (c) H. Schumann, J.A. Meese-Marktscheffel, L. Esser, Chem. Rev. 95 (1995) 865 and references therein. (d) C.J. Schaverien, Adv. Organomet. Chem. 36 (1994) 283 and references therein. (e)W.J. Evans, Adv. Organomet. Chem. 24 (1985) 131 and references therein. (f) H.B. Kagan, J.L. Namy, in: K.A. Gschneider, L. Eyring (Eds.), Handbook on the Physics and Chemistry of Rare Earths, Elsevier, Amsterdam, 1984 (Chapter 50). (g) T.J. Marks, R.D. Ernst, in: G. Wilkinson, F.G.A. Stone, E.W. Abel (Eds.), Comprehensive Organometallic Chemistry, Pergamon Press, Oxford, UK, 1982 (Chapter 21) and references therein. (h) H. Schumann, in: T.J. Marks, I. Fragala (Eds.), Fundamental and Technological Aspects of Organo-f-Element Chemistry, Reidel, Dordrecht, Holland, 1985 (Chapter 1).
7. For general organolanthanide reviews, see: (a) R. Anwander, W.A. Herrman, Top. Curr. Chem. 179 (1996) 1. (b) F.T. Edelmann, Top. Curr. Chem. 179 (1996) 247. (c) H. Schumann, J.A. Meese-Marktscheffel, L. Esser, Chem. Rev. 95 (1995) 865 and references therein. (d) C.J. Schaverien, Adv. Organomet. Chem. 36 (1994) 283 and references therein. (e)W.J. Evans, Adv. Organomet. Chem. 24 (1985) 131 and references therein. (f) H.B. Kagan, J.L. Namy, in: K.A. Gschneider, L. Eyring (Eds.), Handbook on the Physics and Chemistry of Rare Earths, Elsevier, Amsterdam, 1984 (Chapter 50). (g) T.J. Marks, R.D. Ernst, in: G. Wilkinson, F.G.A. Stone, E.W. Abel (Eds.), Comprehensive Organometallic Chemistry, Pergamon Press, Oxford, UK, 1982 (Chapter 21) and references therein. (h) H. Schumann, in: T.J. Marks, I. Fragala (Eds.), Fundamental and Technological Aspects of Organo-f-Element Chemistry, Reidel, Dordrecht, Holland, 1985 (Chapter 1).
8. For general organolanthanide reviews, see: (a) R. Anwander, W.A. Herrman, Top. Curr. Chem. 179 (1996) 1. (b) F.T. Edelmann, Top. Curr. Chem. 179 (1996) 247. (c) H. Schumann, J.A. Meese-Marktscheffel, L. Esser, Chem. Rev. 95 (1995) 865 and references therein. (d) C.J. Schaverien, Adv. Organomet. Chem. 36 (1994) 283 and references therein. (e)W.J. Evans, Adv. Organomet. Chem. 24 (1985) 131 and references therein. (f) H.B. Kagan, J.L. Namy, in: K.A. Gschneider, L. Eyring (Eds.), Handbook on the Physics and Chemistry of Rare Earths, Elsevier, Amsterdam, 1984 (Chapter 50). (g) T.J. Marks, R.D. Ernst, in: G. Wilkinson, F.G.A. Stone, E.W. Abel (Eds.), Comprehensive Organometallic Chemistry, Pergamon Press, Oxford, UK, 1982 (Chapter 21) and references therein. (h) H. Schumann, in: T.J. Marks, I. Fragala (Eds.), Fundamental and Technological Aspects of Organo-f-Element Chemistry, Reidel, Dordrecht, Holland, 1985 (Chapter 1).
9. For general organoactininide reviews, see: (a) F.T. Edelmann, Y.K. Gun'ko, Coord. Chem. Rev. 165 (1997) 163. (b) M. Ephritikhine, New. J. Chem. 16 (1992) 451 (c) F.T. Edelmann, in: E.W. Abel, F.G.A. Stone, G. Wilkinson (Eds.), Comprehensive Organometallic Chemistry II, Pergmon Press, Oxford, UK, 1995 (Chapter 2).
10. For general organoactininide reviews, see: (a) F.T. Edelmann, Y.K. Gun'ko, Coord. Chem. Rev. 165 (1997) 163. (b) M. Ephritikhine, New. J. Chem. 16 (1992) 451 (c) F.T. Edelmann, in: E.W. Abel, F.G.A. Stone, G. Wilkinson (Eds.), Comprehensive Organometallic Chemistry II, Pergmon Press, Oxford, UK, 1995 (Chapter 2).
11. For general organoactininide reviews, see: (a) F.T. Edelmann, Y.K. Gun'ko, Coord. Chem. Rev. 165 (1997) 163. (b) M. Ephritikhine, New. J. Chem. 16 (1992) 451 (c) F.T. Edelmann, in: E.W. Abel, F.G.A. Stone, G. Wilkinson (Eds.), Comprehensive Organometallic Chemistry II, Pergmon Press, Oxford, UK, 1995 (Chapter 2).
12. For examples of catalytic activity of organolanthanides in a variety of alkene and alkyne transformations including hydrogenation see: (a) P.W. Roesky, U. Denninger, C.L. Stern, T.J. Marks, Organometallics 16 (1997) 4486. (b) P.W. Roesky, C.L. Stern, T.J. Marks, Organometallics 16 (1997) 4705. (c) C.M. Haar C.L. Stern, T.J. Marks, Organometallics 15 (1996) 1765. (d) G.A. Molander, J. Winterfeld, J. Organomet. Chem. 524 (1996) 275. (e) M.A. Giardello, V.P. Conticello, L. Brard, M.R. Gagné, T.J. Marks, J. Am. Chem. Soc. 116 (1994) 10241. (f) G.A. Molander, J.O. Hoberg, J. Am. Chem. Soc. 114 (1992) 3123. (g) G. Jeske, H. Lauke, H. Mauermann, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8111. (h) W.J. Evans, I. Bloom, W.E. Hunter, J.L. Atwood, J. Am. Chem. Soc. 105 (1983) 1401.
13. For examples of catalytic activity of organolanthanides in a variety of alkene and alkyne transformations including hydrogenation see: (a) P.W. Roesky, U. Denninger, C.L. Stern, T.J. Marks, Organometallics 16 (1997) 4486. (b) P.W. Roesky, C.L. Stern, T.J. Marks, Organometallics 16 (1997) 4705. (c) C.M. Haar C.L. Stern, T.J. Marks, Organometallics 15 (1996) 1765. (d) G.A. Molander, J. Winterfeld, J. Organomet. Chem. 524 (1996) 275. (e) M.A. Giardello, V.P. Conticello, L. Brard, M.R. Gagné, T.J. Marks, J. Am. Chem. Soc. 116 (1994) 10241. (f) G.A. Molander, J.O. Hoberg, J. Am. Chem. Soc. 114 (1992) 3123. (g) G. Jeske, H. Lauke, H. Mauermann, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8111. (h) W.J. Evans, I. Bloom, W.E. Hunter, J.L. Atwood, J. Am. Chem. Soc. 105 (1983) 1401.
14. For examples of catalytic activity of organolanthanides in a variety of alkene and alkyne transformations including hydrogenation see: (a) P.W. Roesky, U. Denninger, C.L. Stern, T.J. Marks, Organometallics 16 (1997) 4486. (b) P.W. Roesky, C.L. Stern, T.J. Marks, Organometallics 16 (1997) 4705. (c) C.M. Haar C.L. Stern, T.J. Marks, Organometallics 15 (1996) 1765. (d) G.A. Molander, J. Winterfeld, J. Organomet. Chem. 524 (1996) 275. (e) M.A. Giardello, V.P. Conticello, L. Brard, M.R. Gagné, T.J. Marks, J. Am. Chem. Soc. 116 (1994) 10241. (f) G.A. Molander, J.O. Hoberg, J. Am. Chem. Soc. 114 (1992) 3123. (g) G. Jeske, H. Lauke, H. Mauermann, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8111. (h) W.J. Evans, I. Bloom, W.E. Hunter, J.L. Atwood, J. Am. Chem. Soc. 105 (1983) 1401.
15. For examples of catalytic activity of organolanthanides in a variety of alkene and alkyne transformations including hydrogenation see: (a) P.W. Roesky, U. Denninger, C.L. Stern, T.J. Marks, Organometallics 16 (1997) 4486. (b) P.W. Roesky, C.L. Stern, T.J. Marks, Organometallics 16 (1997) 4705. (c) C.M. Haar C.L. Stern, T.J. Marks, Organometallics 15 (1996) 1765. (d) G.A. Molander, J. Winterfeld, J. Organomet. Chem. 524 (1996) 275. (e) M.A. Giardello, V.P. Conticello, L. Brard, M.R. Gagné, T.J. Marks, J. Am. Chem. Soc. 116 (1994) 10241. (f) G.A. Molander, J.O. Hoberg, J. Am. Chem. Soc. 114 (1992) 3123. (g) G. Jeske, H. Lauke, H. Mauermann, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8111. (h) W.J. Evans, I. Bloom, W.E. Hunter, J.L. Atwood, J. Am. Chem. Soc. 105 (1983) 1401.
16. For examples of catalytic activity of organolanthanides in a variety of alkene and alkyne transformations including hydrogenation see: (a) P.W. Roesky, U. Denninger, C.L. Stern, T.J. Marks, Organometallics 16 (1997) 4486. (b) P.W. Roesky, C.L. Stern, T.J. Marks, Organometallics 16 (1997) 4705. (c) C.M. Haar C.L. Stern, T.J. Marks, Organometallics 15 (1996) 1765. (d) G.A. Molander, J. Winterfeld, J. Organomet. Chem. 524 (1996) 275. (e) M.A. Giardello, V.P. Conticello, L. Brard, M.R. Gagné, T.J. Marks, J. Am. Chem. Soc. 116 (1994) 10241. (f) G.A. Molander, J.O. Hoberg, J. Am. Chem. Soc. 114 (1992) 3123. (g) G. Jeske, H. Lauke, H. Mauermann, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8111. (h) W.J. Evans, I. Bloom, W.E. Hunter, J.L. Atwood, J. Am. Chem. Soc. 105 (1983) 1401.
17. For examples of catalytic activity of organolanthanides in a variety of alkene and alkyne transformations including hydrogenation see: (a) P.W. Roesky, U. Denninger, C.L. Stern, T.J. Marks, Organometallics 16 (1997) 4486. (b) P.W. Roesky, C.L. Stern, T.J. Marks, Organometallics 16 (1997) 4705. (c) C.M. Haar C.L. Stern, T.J. Marks, Organometallics 15 (1996) 1765. (d) G.A. Molander, J. Winterfeld, J. Organomet. Chem. 524 (1996) 275. (e) M.A. Giardello, V.P. Conticello, L. Brard, M.R. Gagné, T.J. Marks, J. Am. Chem. Soc. 116 (1994) 10241. (f) G.A. Molander, J.O. Hoberg, J. Am. Chem. Soc. 114 (1992) 3123. (g) G. Jeske, H. Lauke, H. Mauermann, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8111. (h) W.J. Evans, I. Bloom, W.E. Hunter, J.L. Atwood, J. Am. Chem. Soc. 105 (1983) 1401.
18. For examples of catalytic activity of organolanthanides in a variety of alkene and alkyne transformations including hydrogenation see: (a) P.W. Roesky, U. Denninger, C.L. Stern, T.J. Marks, Organometallics 16 (1997) 4486. (b) P.W. Roesky, C.L. Stern, T.J. Marks, Organometallics 16 (1997) 4705. (c) C.M. Haar C.L. Stern, T.J. Marks, Organometallics 15 (1996) 1765. (d) G.A. Molander, J. Winterfeld, J. Organomet. Chem. 524 (1996) 275. (e) M.A. Giardello, V.P. Conticello, L. Brard, M.R. Gagné, T.J. Marks, J. Am. Chem. Soc. 116 (1994) 10241. (f) G.A. Molander, J.O. Hoberg, J. Am. Chem. Soc. 114 (1992) 3123. (g) G. Jeske, H. Lauke, H. Mauermann, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8111. (h) W.J. Evans, I. Bloom, W.E. Hunter, J.L. Atwood, J. Am. Chem. Soc. 105 (1983) 1401.
19. For examples of catalytic activity of organolanthanides in a variety of alkene and alkyne transformations including hydrogenation see: (a) P.W. Roesky, U. Denninger, C.L. Stern, T.J. Marks, Organometallics 16 (1997) 4486. (b) P.W. Roesky, C.L. Stern, T.J. Marks, Organometallics 16 (1997) 4705. (c) C.M. Haar C.L. Stern, T.J. Marks, Organometallics 15 (1996) 1765. (d) G.A. Molander, J. Winterfeld, J. Organomet. Chem. 524 (1996) 275. (e) M.A. Giardello, V.P. Conticello, L. Brard, M.R. Gagné, T.J. Marks, J. Am. Chem. Soc. 116 (1994) 10241. (f) G.A. Molander, J.O. Hoberg, J. Am. Chem. Soc. 114 (1992) 3123. (g) G. Jeske, H. Lauke, H. Mauermann, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8111. (h) W.J. Evans, I. Bloom, W.E. Hunter, J.L. Atwood, J. Am. Chem. Soc. 105 (1983) 1401.
20. For examples of catalytic activity of organolanthanides in dimerization, oligomerization or polymerization, see: (a) L.S. Boff, B.M. Novak, Macromolecules 30 (1997) 3494. (b) W.J. Evans, P.M. DeCoster, J. Greaves, Macromolecules 28 (1995) 7929. (c) H.J. Heeres, A. Heeres, J.H.Teuben, Organometallics 9 (1990) 1508. (d) J.P. Mitchell, S. Hajela, S.K. Brookhart, K.I. Hardcastle, L.M. Henling, J.E. Bercaw, J. Am. Chem. Soc. 118 (1996) 1045. (e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 197 (1996) 1909. (f) P.-F. Fu, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 10747. (g) C.J. Schaverien, Organometallics 13 (1994) 69. (h) H.J. Heeres, J.H. Teuben, Organometallics 10 (1991) 1980. (i) H.J. Heeres, J. Renkema, M. Booij, A. Meetsma, J.H. Teuben, Organometallics 7 (1988) 2495 and references therein. (j) G. Jeske, L.E. Schock, P.N. Swepson, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8091. (k) P.L. Watson, G.W. Parshall, Acc. Chem. Res. 18 (1985) 51.
21. For examples of catalytic activity of organolanthanides in dimerization, oligomerization or polymerization, see: (a) L.S. Boff, B.M. Novak, Macromolecules 30 (1997) 3494. (b) W.J. Evans, P.M. DeCoster, J. Greaves, Macromolecules 28 (1995) 7929. (c) H.J. Heeres, A. Heeres, J.H.Teuben, Organometallics 9 (1990) 1508. (d) J.P. Mitchell, S. Hajela, S.K. Brookhart, K.I. Hardcastle, L.M. Henling, J.E. Bercaw, J. Am. Chem. Soc. 118 (1996) 1045. (e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 197 (1996) 1909. (f) P.-F. Fu, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 10747. (g) C.J. Schaverien, Organometallics 13 (1994) 69. (h) H.J. Heeres, J.H. Teuben, Organometallics 10 (1991) 1980. (i) H.J. Heeres, J. Renkema, M. Booij, A. Meetsma, J.H. Teuben, Organometallics 7 (1988) 2495 and references therein. (j) G. Jeske, L.E. Schock, P.N. Swepson, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8091. (k) P.L. Watson, G.W. Parshall, Acc. Chem. Res. 18 (1985) 51.
22. For examples of catalytic activity of organolanthanides in dimerization, oligomerization or polymerization, see: (a) L.S. Boff, B.M. Novak, Macromolecules 30 (1997) 3494. (b) W.J. Evans, P.M. DeCoster, J. Greaves, Macromolecules 28 (1995) 7929. (c) H.J. Heeres, A. Heeres, J.H.Teuben, Organometallics 9 (1990) 1508. (d) J.P. Mitchell, S. Hajela, S.K. Brookhart, K.I. Hardcastle, L.M. Henling, J.E. Bercaw, J. Am. Chem. Soc. 118 (1996) 1045. (e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 197 (1996) 1909. (f) P.-F. Fu, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 10747. (g) C.J. Schaverien, Organometallics 13 (1994) 69. (h) H.J. Heeres, J.H. Teuben, Organometallics 10 (1991) 1980. (i) H.J. Heeres, J. Renkema, M. Booij, A. Meetsma, J.H. Teuben, Organometallics 7 (1988) 2495 and references therein. (j) G. Jeske, L.E. Schock, P.N. Swepson, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8091. (k) P.L. Watson, G.W. Parshall, Acc. Chem. Res. 18 (1985) 51.
23. For examples of catalytic activity of organolanthanides in dimerization, oligomerization or polymerization, see: (a) L.S. Boff, B.M. Novak, Macromolecules 30 (1997) 3494. (b) W.J. Evans, P.M. DeCoster, J. Greaves, Macromolecules 28 (1995) 7929. (c) H.J. Heeres, A. Heeres, J.H.Teuben, Organometallics 9 (1990) 1508. (d) J.P. Mitchell, S. Hajela, S.K. Brookhart, K.I. Hardcastle, L.M. Henling, J.E. Bercaw, J. Am. Chem. Soc. 118 (1996) 1045. (e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 197 (1996) 1909. (f) P.-F. Fu, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 10747. (g) C.J. Schaverien, Organometallics 13 (1994) 69. (h) H.J. Heeres, J.H. Teuben, Organometallics 10 (1991) 1980. (i) H.J. Heeres, J. Renkema, M. Booij, A. Meetsma, J.H. Teuben, Organometallics 7 (1988) 2495 and references therein. (j) G. Jeske, L.E. Schock, P.N. Swepson, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8091. (k) P.L. Watson, G.W. Parshall, Acc. Chem. Res. 18 (1985) 51.
24. For examples of catalytic activity of organolanthanides in dimerization, oligomerization or polymerization, see: (a) L.S. Boff, B.M. Novak, Macromolecules 30 (1997) 3494. (b) W.J. Evans, P.M. DeCoster, J. Greaves, Macromolecules 28 (1995) 7929. (c) H.J. Heeres, A. Heeres, J.H.Teuben, Organometallics 9 (1990) 1508. (d) J.P. Mitchell, S. Hajela, S.K. Brookhart, K.I. Hardcastle, L.M. Henling, J.E. Bercaw, J. Am. Chem. Soc. 118 (1996) 1045. (e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 197 (1996) 1909. (f) P.-F. Fu, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 10747. (g) C.J. Schaverien, Organometallics 13 (1994) 69. (h) H.J. Heeres, J.H. Teuben, Organometallics 10 (1991) 1980. (i) H.J. Heeres, J. Renkema, M. Booij, A. Meetsma, J.H. Teuben, Organometallics 7 (1988) 2495 and references therein. (j) G. Jeske, L.E. Schock, P.N. Swepson, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8091. (k) P.L. Watson, G.W. Parshall, Acc. Chem. Res. 18 (1985) 51.
25. For examples of catalytic activity of organolanthanides in dimerization, oligomerization or polymerization, see: (a) L.S. Boff, B.M. Novak, Macromolecules 30 (1997) 3494. (b) W.J. Evans, P.M. DeCoster, J. Greaves, Macromolecules 28 (1995) 7929. (c) H.J. Heeres, A. Heeres, J.H.Teuben, Organometallics 9 (1990) 1508. (d) J.P. Mitchell, S. Hajela, S.K. Brookhart, K.I. Hardcastle, L.M. Henling, J.E. Bercaw, J. Am. Chem. Soc. 118 (1996) 1045. (e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 197 (1996) 1909. (f) P.-F. Fu, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 10747. (g) C.J. Schaverien, Organometallics 13 (1994) 69. (h) H.J. Heeres, J.H. Teuben, Organometallics 10 (1991) 1980. (i) H.J. Heeres, J. Renkema, M. Booij, A. Meetsma, J.H. Teuben, Organometallics 7 (1988) 2495 and references therein. (j) G. Jeske, L.E. Schock, P.N. Swepson, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8091. (k) P.L. Watson, G.W. Parshall, Acc. Chem. Res. 18 (1985) 51.
26. For examples of catalytic activity of organolanthanides in dimerization, oligomerization or polymerization, see: (a) L.S. Boff, B.M. Novak, Macromolecules 30 (1997) 3494. (b) W.J. Evans, P.M. DeCoster, J. Greaves, Macromolecules 28 (1995) 7929. (c) H.J. Heeres, A. Heeres, J.H.Teuben, Organometallics 9 (1990) 1508. (d) J.P. Mitchell, S. Hajela, S.K. Brookhart, K.I. Hardcastle, L.M. Henling, J.E. Bercaw, J. Am. Chem. Soc. 118 (1996) 1045. (e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 197 (1996) 1909. (f) P.-F. Fu, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 10747. (g) C.J. Schaverien, Organometallics 13 (1994) 69. (h) H.J. Heeres, J.H. Teuben, Organometallics 10 (1991) 1980. (i) H.J. Heeres, J. Renkema, M. Booij, A. Meetsma, J.H. Teuben, Organometallics 7 (1988) 2495 and references therein. (j) G. Jeske, L.E. Schock, P.N. Swepson, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8091. (k) P.L. Watson, G.W. Parshall, Acc. Chem. Res. 18 (1985) 51.
27. For examples of catalytic activity of organolanthanides in dimerization, oligomerization or polymerization, see: (a) L.S. Boff, B.M. Novak, Macromolecules 30 (1997) 3494. (b) W.J. Evans, P.M. DeCoster, J. Greaves, Macromolecules 28 (1995) 7929. (c) H.J. Heeres, A. Heeres, J.H.Teuben, Organometallics 9 (1990) 1508. (d) J.P. Mitchell, S. Hajela, S.K. Brookhart, K.I. Hardcastle, L.M. Henling, J.E. Bercaw, J. Am. Chem. Soc. 118 (1996) 1045. (e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 197 (1996) 1909. (f) P.-F. Fu, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 10747. (g) C.J. Schaverien, Organometallics 13 (1994) 69. (h) H.J. Heeres, J.H. Teuben, Organometallics 10 (1991) 1980. (i) H.J. Heeres, J. Renkema, M. Booij, A. Meetsma, J.H. Teuben, Organometallics 7 (1988) 2495 and references therein. (j) G. Jeske, L.E. Schock, P.N. Swepson, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8091. (k) P.L. Watson, G.W. Parshall, Acc. Chem. Res. 18 (1985) 51.
28. For examples of catalytic activity of organolanthanides in dimerization, oligomerization or polymerization, see: (a) L.S. Boff, B.M. Novak, Macromolecules 30 (1997) 3494. (b) W.J. Evans, P.M. DeCoster, J. Greaves, Macromolecules 28 (1995) 7929. (c) H.J. Heeres, A. Heeres, J.H.Teuben, Organometallics 9 (1990) 1508. (d) J.P. Mitchell, S. Hajela, S.K. Brookhart, K.I. Hardcastle, L.M. Henling, J.E. Bercaw, J. Am. Chem. Soc. 118 (1996) 1045. (e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 197 (1996) 1909. (f) P.-F. Fu, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 10747. (g) C.J. Schaverien, Organometallics 13 (1994) 69. (h) H.J. Heeres, J.H. Teuben, Organometallics 10 (1991) 1980. (i) H.J. Heeres, J. Renkema, M. Booij, A. Meetsma, J.H. Teuben, Organometallics 7 (1988) 2495 and references therein. (j) G. Jeske, L.E. Schock, P.N. Swepson, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8091. (k) P.L. Watson, G.W. Parshall, Acc. Chem. Res. 18 (1985) 51.
29. For examples of catalytic activity of organolanthanides in dimerization, oligomerization or polymerization, see: (a) L.S. Boff, B.M. Novak, Macromolecules 30 (1997) 3494. (b) W.J. Evans, P.M. DeCoster, J. Greaves, Macromolecules 28 (1995) 7929. (c) H.J. Heeres, A. Heeres, J.H.Teuben, Organometallics 9 (1990) 1508. (d) J.P. Mitchell, S. Hajela, S.K. Brookhart, K.I. Hardcastle, L.M. Henling, J.E. Bercaw, J. Am. Chem. Soc. 118 (1996) 1045. (e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 197 (1996) 1909. (f) P.-F. Fu, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 10747. (g) C.J. Schaverien, Organometallics 13 (1994) 69. (h) H.J. Heeres, J.H. Teuben, Organometallics 10 (1991) 1980. (i) H.J. Heeres, J. Renkema, M. Booij, A. Meetsma, J.H. Teuben, Organometallics 7 (1988) 2495 and references therein. (j) G. Jeske, L.E. Schock, P.N. Swepson, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8091. (k) P.L. Watson, G.W. Parshall, Acc. Chem. Res. 18 (1985) 51.
30. For examples of catalytic activity of organolanthanides in dimerization, oligomerization or polymerization, see: (a) L.S. Boff, B.M. Novak, Macromolecules 30 (1997) 3494. (b) W.J. Evans, P.M. DeCoster, J. Greaves, Macromolecules 28 (1995) 7929. (c) H.J. Heeres, A. Heeres, J.H.Teuben, Organometallics 9 (1990) 1508. (d) J.P. Mitchell, S. Hajela, S.K. Brookhart, K.I. Hardcastle, L.M. Henling, J.E. Bercaw, J. Am. Chem. Soc. 118 (1996) 1045. (e) E. Ihara, M. Nodono, H. Yasuda, N. Kanehisa, Y. Kai, Macromol. Chem. Phys. 197 (1996) 1909. (f) P.-F. Fu, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 10747. (g) C.J. Schaverien, Organometallics 13 (1994) 69. (h) H.J. Heeres, J.H. Teuben, Organometallics 10 (1991) 1980. (i) H.J. Heeres, J. Renkema, M. Booij, A. Meetsma, J.H. Teuben, Organometallics 7 (1988) 2495 and references therein. (j) G. Jeske, L.E. Schock, P.N. Swepson, H. Schumann, T.J. Marks, J. Am. Chem. Soc. 107 (1985) 8091. (k) P.L. Watson, G.W. Parshall, Acc. Chem. Res. 18 (1985) 51.
31. For examples of catalytic activity of organolanthanides in hydroamination, see: (a) V.M. Arredondo, F.E. McDonald, T.J. Marks, J. Am. Chem. Soc. 120 (1998) 4871. (b) Y. Li, T.J. Marks, J. Am. Chem. Soc. 118 (1996) 9295. (c) Y. Li, T.J. Marks, Organometallics 15 (1996) 3770. (d) Y. Li, T.J. Marks, J. Am. Chem. Soc. 118 (1996) 707. (e) Y. Li, P.-F. Fu, T.J. Marks, Organometallics 13 (1994) 439. (f) M.A. Giardello, V.P. Conticello, L. Brard, M.R. Gagné, T.J. Marks, J. Am. Chem. Soc. 116 (1994) 10241 and references therein.
32. For examples of catalytic activity of organolanthanides in hydroamination, see: (a) V.M. Arredondo, F.E. McDonald, T.J. Marks, J. Am. Chem. Soc. 120 (1998) 4871. (b) Y. Li, T.J. Marks, J. Am. Chem. Soc. 118 (1996) 9295. (c) Y. Li, T.J. Marks, Organometallics 15 (1996) 3770. (d) Y. Li, T.J. Marks, J. Am. Chem. Soc. 118 (1996) 707. (e) Y. Li, P.-F. Fu, T.J. Marks, Organometallics 13 (1994) 439. (f) M.A. Giardello, V.P. Conticello, L. Brard, M.R. Gagné, T.J. Marks, J. Am. Chem. Soc. 116 (1994) 10241 and references therein.
33. For examples of catalytic activity of organolanthanides in hydroamination, see: (a) V.M. Arredondo, F.E. McDonald, T.J. Marks, J. Am. Chem. Soc. 120 (1998) 4871. (b) Y. Li, T.J. Marks, J. Am. Chem. Soc. 118 (1996) 9295. (c) Y. Li, T.J. Marks, Organometallics 15 (1996) 3770. (d) Y. Li, T.J. Marks, J. Am. Chem. Soc. 118 (1996) 707. (e) Y. Li, P.-F. Fu, T.J. Marks, Organometallics 13 (1994) 439. (f) M.A. Giardello, V.P. Conticello, L. Brard, M.R. Gagné, T.J. Marks, J. Am. Chem. Soc. 116 (1994) 10241 and references therein.
34. For examples of catalytic activity of organolanthanides in hydroamination, see: (a) V.M. Arredondo, F.E. McDonald, T.J. Marks, J. Am. Chem. Soc. 120 (1998) 4871. (b) Y. Li, T.J. Marks, J. Am. Chem. Soc. 118 (1996) 9295. (c) Y. Li, T.J. Marks, Organometallics 15 (1996) 3770. (d) Y. Li, T.J. Marks, J. Am. Chem. Soc. 118 (1996) 707. (e) Y. Li, P.-F. Fu, T.J. Marks, Organometallics 13 (1994) 439. (f) M.A. Giardello, V.P. Conticello, L. Brard, M.R. Gagné, T.J. Marks, J. Am. Chem. Soc. 116 (1994) 10241 and references therein.
35. For examples of catalytic activity of organolanthanides in hydroamination, see: (a) V.M. Arredondo, F.E. McDonald, T.J. Marks, J. Am. Chem. Soc. 120 (1998) 4871. (b) Y. Li, T.J. Marks, J. Am. Chem. Soc. 118 (1996) 9295. (c) Y. Li, T.J. Marks, Organometallics 15 (1996) 3770. (d) Y. Li, T.J. Marks, J. Am. Chem. Soc. 118 (1996) 707. (e) Y. Li, P.-F. Fu, T.J. Marks, Organometallics 13 (1994) 439. (f) M.A. Giardello, V.P. Conticello, L. Brard, M.R. Gagné, T.J. Marks, J. Am. Chem. Soc. 116 (1994) 10241 and references therein.
36. For examples of catalytic activity of organolanthanides in hydroamination, see: (a) V.M. Arredondo, F.E. McDonald, T.J. Marks, J. Am. Chem. Soc. 120 (1998) 4871. (b) Y. Li, T.J. Marks, J. Am. Chem. Soc. 118 (1996) 9295. (c) Y. Li, T.J. Marks, Organometallics 15 (1996) 3770. (d) Y. Li, T.J. Marks, J. Am. Chem. Soc. 118 (1996) 707. (e) Y. Li, P.-F. Fu, T.J. Marks, Organometallics 13 (1994) 439. (f) M.A. Giardello, V.P. Conticello, L. Brard, M.R. Gagné, T.J. Marks, J. Am. Chem. Soc. 116 (1994) 10241 and references therein.
37. For examples of catalytic activity of organolanthanides in hydrosilylation see: (a) P.-F. Fu, L. Brard, Y. Li, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 7157. (b) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. (c) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (d) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (e) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (f) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754.
38. For examples of catalytic activity of organolanthanides in hydrosilylation see: (a) P.-F. Fu, L. Brard, Y. Li, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 7157. (b) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. (c) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (d) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (e) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (f) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754.
39. For examples of catalytic activity of organolanthanides in hydrosilylation see: (a) P.-F. Fu, L. Brard, Y. Li, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 7157. (b) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. (c) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (d) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (e) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (f) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754.
40. For examples of catalytic activity of organolanthanides in hydrosilylation see: (a) P.-F. Fu, L. Brard, Y. Li, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 7157. (b) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. (c) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (d) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (e) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (f) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754.
41. For examples of catalytic activity of organolanthanides in hydrosilylation see: (a) P.-F. Fu, L. Brard, Y. Li, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 7157. (b) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. (c) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (d) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (e) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (f) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754.
42. For examples of catalytic activity of organolanthanides in hydrosilylation see: (a) P.-F. Fu, L. Brard, Y. Li, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 7157. (b) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. (c) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (d) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (e) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (f) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754.
43. For examples of catalytic activity of organolanthanides in hydrophosphination, see: M.A. Giardello, W.A. King, S.P. Nolan, M. Porchia, C. Sishta, T.J. Marks, in: J.A. Martinho Simoes (Ed.), Energetics of Organometallic Species, Kluwer, Dodrecht, The Netherlands, 1992, pp. 35-54.
44. For examples of catalytic activity of organolanthanides in hydroboration, see: (a) R. Anwander, in: B. Cornils, W. Hermann (Eds.), Applied Homogeneous Catalysis with Organometallic Compounds, vol. 2, VCH, Weinheim, Germany, 1997, pp. 866-892. (b) E.A. Bijpost, R. Duchateau, J.H. Teuben, J. Mol. Catal. 95 (1995) 121. (c) K.N. Harrison, T.J. Marks, J. Am. Chem. Soc. 114 (1992) 9220.
45. For examples of catalytic activity of organolanthanides in hydroboration, see: (a) R. Anwander, in: B. Cornils, W. Hermann (Eds.), Applied Homogeneous Catalysis with Organometallic Compounds, vol. 2, VCH, Weinheim, Germany, 1997, pp. 866-892. (b) E.A. Bijpost, R. Duchateau, J.H. Teuben, J. Mol. Catal. 95 (1995) 121. (c) K.N. Harrison, T.J. Marks, J. Am. Chem. Soc. 114 (1992) 9220.
46. For examples of catalytic activity of organolanthanides in hydroboration, see: (a) R. Anwander, in: B. Cornils, W. Hermann (Eds.), Applied Homogeneous Catalysis with Organometallic Compounds, vol. 2, VCH, Weinheim, Germany, 1997, pp. 866-892. (b) E.A. Bijpost, R. Duchateau, J.H. Teuben, J. Mol. Catal. 95 (1995) 121. (c) K.N. Harrison, T.J. Marks, J. Am. Chem. Soc. 114 (1992) 9220.
47. For examples of catalytic activity of organolanthanides in ring opening Ziegler polymerizations, see: (a) L. Jia, X. Yang, A.M. Seyam, I.D.L. Albert, P.-F. Fu, S. Yang, T.J. Marks, J. Am. Chem. Soc. 118 (1996) 7900. (b) X. Yang, A.M. Seyam, P.-F. Fu, T.J. Marks, Macromolecules 27 (1994) 4625.
48. For examples of catalytic activity of organolanthanides in ring opening Ziegler polymerizations, see: (a) L. Jia, X. Yang, A.M. Seyam, I.D.L. Albert, P.-F. Fu, S. Yang, T.J. Marks, J. Am. Chem. Soc. 118 (1996) 7900. (b) X. Yang, A.M. Seyam, P.-F. Fu, T.J. Marks, Macromolecules 27 (1994) 4625.
49. For examples of catalytic activity of organoactinides in C-H activation processes, see: (a) G.M. Smith, J.D. Carpenter, T.J. Marks, J. Am. Chem. Soc. 108 (1986) 6805. (b) J.W. Bruno, G.M. Smith T.J. Marks, J. Am. Chem. Soc. 108 (1986) 40. (c) C.M. Fendrick, L.D. Schertz, V.W. Day, T.J. Marks, J. Am. Chem. Soc. 7 (1988) 1828.
50. For examples of catalytic activity of organoactinides in C-H activation processes, see: (a) G.M. Smith, J.D. Carpenter, T.J. Marks, J. Am. Chem. Soc. 108 (1986) 6805. (b) J.W. Bruno, G.M. Smith T.J. Marks, J. Am. Chem. Soc. 108 (1986) 40. (c) C.M. Fendrick, L.D. Schertz, V.W. Day, T.J. Marks, J. Am. Chem. Soc. 7 (1988) 1828.
51. For examples of catalytic activity of organoactinides in C-H activation processes, see: (a) G.M. Smith, J.D. Carpenter, T.J. Marks, J. Am. Chem. Soc. 108 (1986) 6805. (b) J.W. Bruno, G.M. Smith T.J. Marks, J. Am. Chem. Soc. 108 (1986) 40. (c) C.M. Fendrick, L.D. Schertz, V.W. Day, T.J. Marks, J. Am. Chem. Soc. 7 (1988) 1828.
52. For examples of catalytic activity of organoactinides in hydrogenation, see: Z. Lin, T.J. Marks, J. Am. Chem. Soc. 112 (1990) 5515 and references therein.
53. For examples of catalytic activity of organoactinides in hydroamination, see: (a) A. Haskel, T. Straub, M.S. Eisen, Organometallics 15 (1996) 3773. (b) T. Straub, W. Frank, G.J. Reiß, M.S. Eisen. J. Chem. Soc. Dalton Trans. (1996) 2541.
54. For examples of catalytic activity of organoactinides in hydroamination, see: (a) A. Haskel, T. Straub, M.S. Eisen, Organometallics 15 (1996) 3773. (b) T. Straub, W. Frank, G.J. Reiß, M.S. Eisen. J. Chem. Soc. Dalton Trans. (1996) 2541.
55. For examples of catalytic activity of organoactinides in hydrosilylation, see: (a) M.S. Eisen, Proceedings of the XVIIth International Conference on Organometallic Chemistry, Munich, Germany, 1998, p. BI1. (b) J.Q. Wang, M.S. Eisen, Proceedings of the 11th International Symposium on Homogeneous Catalysis, St. Andrews, Scotland, UK, 1998, p. 82.
56. For examples of catalytic activity of organoactinides in hydrosilylation, see: (a) M.S. Eisen, Proceedings of the XVIIth International Conference on Organometallic Chemistry, Munich, Germany, 1998, p. BI1. (b) J.Q. Wang, M.S. Eisen, Proceedings of the 11th International Symposium on Homogeneous Catalysis, St. Andrews, Scotland, UK, 1998, p. 82.
57. For examples of catalytic activity of organoactinides in oligomerizations, see: (a) A. Haskel, T. Straub, A.K. Dash, M.S. Eisen, J. Am. Chem. Soc. 121 (1999) 3014. (b) A. Haskel, J.Q. Wang, T. Straub, T. Gueta Neyroud, M.S. Eisen, J. Am. Chem. Soc. 121 (1999) 3025. (c) M. Brookhart, B.E. Grant, J. Am. Chem. Soc. 115 (1993) 2151.
58. For examples of catalytic activity of organoactinides in oligomerizations, see: (a) A. Haskel, T. Straub, A.K. Dash, M.S. Eisen, J. Am. Chem. Soc. 121 (1999) 3014. (b) A. Haskel, J.Q. Wang, T. Straub, T. Gueta Neyroud, M.S. Eisen, J. Am. Chem. Soc. 121 (1999) 3025. (c) M. Brookhart, B.E. Grant, J. Am. Chem. Soc. 115 (1993) 2151.
59. For examples of catalytic activity of organoactinides in oligomerizations, see: (a) A. Haskel, T. Straub, A.K. Dash, M.S. Eisen, J. Am. Chem. Soc. 121 (1999) 3014. (b) A. Haskel, J.Q. Wang, T. Straub, T. Gueta Neyroud, M.S. Eisen, J. Am. Chem. Soc. 121 (1999) 3025. (c) M. Brookhart, B.E. Grant, J. Am. Chem. Soc. 115 (1993) 2151.
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74. Speier J.L., Webster J.A., Bernes G.H. J. Am. Chem. Soc. 79:1959;974.
75. (a) H. Bruner, H. Nishiyama, K. Itoh, in: H. Ojima (Ed.), Catalytic Asymmetric Synthesis, VCP, New York, 1993, p. 303.
76. (b) R. Noyori, Asymmetric Catalysis in Organic Synthesis, Wiley, New York, 1994.
77. (a) M. Brookhart, B.E. Grant, J. Am. Chem. Soc. 115 (1993) 2151
78. (b) Y. Maruyama, K. Yamamura, I. Nakayama, K. Yoshiuchi, F. Ozawa, J. Am. Chem. Soc. 120 (1998) 1421.
79. (c) A.M. LaPonte, F.C. Rix, M. Brookhart, J. Am. Chem. Soc. 119 (1997) 906.
80. (d) M.A. Esteruelas, L.A. Oro, C. Valero, Organometallics 10 (1991) 462.
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82. (f) R.D. Adams, T.S. Barnard, Organometallics 17 (1998) 2567.
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88. (l) A.M. Caporusso, S. Barontini, P. Pertici, G. Vitulli, P Salvadori, J. Organomet. Chem. 564 (1998) 57.
89. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman, R.M. Waymouth, J. Organomet. Chem. 417 (1991) C12. (f) J.Y. Corey, X.H. Zhu, Organometallics 11 (1992) 672. (g) J.F. Harrod, S.S. Yun, Organometallics 6 (1987) 1381. For Group 3 complexes, see: (h) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (i) G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570. (j) G.A. Molander, P.J. Nichols, B.C. Noll, J. Org. Chem. 63 (1998) 2292. (k) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. For organolanthanides in hydrosilylation, see: Ref. [6] and: (l) H. Schumann, M.R. Keitsch, J. Winterfeld, S. Muhle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181. (m) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (n) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (o) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754. (p) S. Onozawa, T. Sakakura, M. Tanaka, Tetrahedron Lett. 35 (1994) 8177. For actinides see: (q) A.K. Dash, J.Q.Wang, M.S. Eisen, Organometallics 18 (1999) 4724.
90. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman, R.M. Waymouth, J. Organomet. Chem. 417 (1991) C12. (f) J.Y. Corey, X.H. Zhu, Organometallics 11 (1992) 672. (g) J.F. Harrod, S.S. Yun, Organometallics 6 (1987) 1381. For Group 3 complexes, see: (h) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (i) G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570. (j) G.A. Molander, P.J. Nichols, B.C. Noll, J. Org. Chem. 63 (1998) 2292. (k) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. For organolanthanides in hydrosilylation, see: Ref. [6] and: (l) H. Schumann, M.R. Keitsch, J. Winterfeld, S. Muhle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181. (m) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (n) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (o) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754. (p) S. Onozawa, T. Sakakura, M. Tanaka, Tetrahedron Lett. 35 (1994) 8177. For actinides see: (q) A.K. Dash, J.Q.Wang, M.S. Eisen, Organometallics 18 (1999) 4724.
91. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman, R.M. Waymouth, J. Organomet. Chem. 417 (1991) C12. (f) J.Y. Corey, X.H. Zhu, Organometallics 11 (1992) 672. (g) J.F. Harrod, S.S. Yun, Organometallics 6 (1987) 1381. For Group 3 complexes, see: (h) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (i) G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570. (j) G.A. Molander, P.J. Nichols, B.C. Noll, J. Org. Chem. 63 (1998) 2292. (k) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. For organolanthanides in hydrosilylation, see: Ref. [6] and: (l) H. Schumann, M.R. Keitsch, J. Winterfeld, S. Muhle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181. (m) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (n) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (o) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754. (p) S. Onozawa, T. Sakakura, M. Tanaka, Tetrahedron Lett. 35 (1994) 8177. For actinides see: (q) A.K. Dash, J.Q.Wang, M.S. Eisen, Organometallics 18 (1999) 4724.
92. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman, R.M. Waymouth, J. Organomet. Chem. 417 (1991) C12. (f) J.Y. Corey, X.H. Zhu, Organometallics 11 (1992) 672. (g) J.F. Harrod, S.S. Yun, Organometallics 6 (1987) 1381. For Group 3 complexes, see: (h) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (i) G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570. (j) G.A. Molander, P.J. Nichols, B.C. Noll, J. Org. Chem. 63 (1998) 2292. (k) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. For organolanthanides in hydrosilylation, see: Ref. [6] and: (l) H. Schumann, M.R. Keitsch, J. Winterfeld, S. Muhle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181. (m) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (n) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (o) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754. (p) S. Onozawa, T. Sakakura, M. Tanaka, Tetrahedron Lett. 35 (1994) 8177. For actinides see: (q) A.K. Dash, J.Q.Wang, M.S. Eisen, Organometallics 18 (1999) 4724.
93. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman, R.M. Waymouth, J. Organomet. Chem. 417 (1991) C12. (f) J.Y. Corey, X.H. Zhu, Organometallics 11 (1992) 672. (g) J.F. Harrod, S.S. Yun, Organometallics 6 (1987) 1381. For Group 3 complexes, see: (h) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (i) G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570. (j) G.A. Molander, P.J. Nichols, B.C. Noll, J. Org. Chem. 63 (1998) 2292. (k) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. For organolanthanides in hydrosilylation, see: Ref. [6] and: (l) H. Schumann, M.R. Keitsch, J. Winterfeld, S. Muhle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181. (m) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (n) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (o) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754. (p) S. Onozawa, T. Sakakura, M. Tanaka, Tetrahedron Lett. 35 (1994) 8177. For actinides see: (q) A.K. Dash, J.Q.Wang, M.S. Eisen, Organometallics 18 (1999) 4724.
94. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman, R.M. Waymouth, J. Organomet. Chem. 417 (1991) C12. (f) J.Y. Corey, X.H. Zhu, Organometallics 11 (1992) 672. (g) J.F. Harrod, S.S. Yun, Organometallics 6 (1987) 1381. For Group 3 complexes, see: (h) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (i) G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570. (j) G.A. Molander, P.J. Nichols, B.C. Noll, J. Org. Chem. 63 (1998) 2292. (k) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. For organolanthanides in hydrosilylation, see: Ref. [6] and: (l) H. Schumann, M.R. Keitsch, J. Winterfeld, S. Muhle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181. (m) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (n) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (o) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754. (p) S. Onozawa, T. Sakakura, M. Tanaka, Tetrahedron Lett. 35 (1994) 8177. For actinides see: (q) A.K. Dash, J.Q.Wang, M.S. Eisen, Organometallics 18 (1999) 4724.
95. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman, R.M. Waymouth, J. Organomet. Chem. 417 (1991) C12. (f) J.Y. Corey, X.H. Zhu, Organometallics 11 (1992) 672. (g) J.F. Harrod, S.S. Yun, Organometallics 6 (1987) 1381. For Group 3 complexes, see: (h) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (i) G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570. (j) G.A. Molander, P.J. Nichols, B.C. Noll, J. Org. Chem. 63 (1998) 2292. (k) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. For organolanthanides in hydrosilylation, see: Ref. [6] and: (l) H. Schumann, M.R. Keitsch, J. Winterfeld, S. Muhle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181. (m) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (n) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (o) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754. (p) S. Onozawa, T. Sakakura, M. Tanaka, Tetrahedron Lett. 35 (1994) 8177. For actinides see: (q) A.K. Dash, J.Q.Wang, M.S. Eisen, Organometallics 18 (1999) 4724.
96. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman,
97. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman, R.M. Waymouth, J. Organomet. Chem. 417 (1991) C12. (f) J.Y. Corey, X.H. Zhu, Organometallics 11 (1992) 672. (g) J.F. Harrod, S.S. Yun, Organometallics 6 (1987) 1381. For Group 3 complexes, see: (h) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (i) G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570. (j) G.A. Molander, P.J. Nichols, B.C. Noll, J. Org. Chem. 63 (1998) 2292. (k) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. For organolanthanides in hydrosilylation, see: Ref. [6] and: (l) H. Schumann, M.R. Keitsch, J. Winterfeld, S. Muhle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181. (m) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (n) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (o) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754. (p) S. Onozawa, T. Sakakura, M. Tanaka, Tetrahedron Lett. 35 (1994) 8177. For actinides see: (q) A.K. Dash, J.Q.Wang, M.S. Eisen, Organometallics 18 (1999) 4724.
98. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman, R.M. Waymouth, J. Organomet. Chem. 417 (1991) C12. (f) J.Y. Corey, X.H. Zhu, Organometallics 11 (1992) 672. (g) J.F. Harrod, S.S. Yun, Organometallics 6 (1987) 1381. For Group 3 complexes, see: (h) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (i) G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570. (j) G.A. Molander, P.J. Nichols, B.C. Noll, J. Org. Chem. 63 (1998) 2292. (k) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. For organolanthanides in hydrosilylation, see: Ref. [6] and: (l) H. Schumann, M.R. Keitsch, J. Winterfeld, S. Muhle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181. (m) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (n) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (o) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754. (p) S. Onozawa, T. Sakakura, M. Tanaka, Tetrahedron Lett. 35 (1994) 8177. For actinides see: (q) A.K. Dash, J.Q.Wang, M.S. Eisen, Organometallics 18 (1999) 4724.
99. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman, R.M. Waymouth, J. Organomet. Chem. 417 (1991) C12. (f) J.Y. Corey, X.H. Zhu, Organometallics 11 (1992) 672. (g) J.F. Harrod, S.S. Yun, Organometallics 6 (1987) 1381. For Group 3 complexes, see: (h) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (i) G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570. (j) G.A. Molander, P.J. Nichols, B.C. Noll, J. Org. Chem. 63 (1998) 2292. (k) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. For organolanthanides in hydrosilylation, see: Ref. [6] and: (l) H. Schumann, M.R. Keitsch, J. Winterfeld, S. Muhle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181. (m) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (n) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (o) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754. (p) S. Onozawa, T. Sakakura, M. Tanaka, Tetrahedron Lett. 35 (1994) 8177. For actinides see: (q) A.K. Dash, J.Q.Wang, M.S. Eisen, Organometallics 18 (1999) 4724.
100. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman, R.M. Waymouth, J. Organomet. Chem. 417 (1991) C12. (f) J.Y. Corey, X.H. Zhu, Organometallics 11 (1992) 672. (g) J.F. Harrod, S.S. Yun, Organometallics 6 (1987) 1381. For Group 3 complexes, see: (h) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (i) G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570. (j) G.A. Molander, P.J. Nichols, B.C. Noll, J. Org. Chem. 63 (1998) 2292. (k) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. For organolanthanides in hydrosilylation, see: Ref. [6] and: (l) H. Schumann, M.R. Keitsch, J. Winterfeld, S. Muhle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181. (m) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (n) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (o) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754. (p) S. Onozawa, T. Sakakura, M. Tanaka, Tetrahedron Lett. 35 (1994) 8177. For actinides see: (q) A.K. Dash, J.Q.Wang, M.S. Eisen, Organometallics 18 (1999) 4724.
101. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman, R.M. Waymouth, J. Organomet. Chem. 417 (1991) C12. (f) J.Y. Corey, X.H. Zhu, Organometallics 11 (1992) 672. (g) J.F. Harrod, S.S. Yun, Organometallics 6 (1987) 1381. For Group 3 complexes, see: (h) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (i) G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570. (j) G.A. Molander, P.J. Nichols, B.C. Noll, J. Org. Chem. 63 (1998) 2292. (k) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. For organolanthanides in hydrosilylation, see: Ref. [6] and: (l) H. Schumann, M.R. Keitsch, J. Winterfeld, S. Muhle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181. (m) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (n) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (o) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754. (p) S. Onozawa, T. Sakakura, M. Tanaka, Tetrahedron Lett. 35 (1994) 8177. For actinides see: (q) A.K. Dash, J.Q.Wang, M.S. Eisen, Organometallics 18 (1999) 4724.
102. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman, R.M. Waymouth, J. Organomet. Chem. 417 (1991) C12. (f) J.Y. Corey, X.H. Zhu, Organometallics 11 (1992) 672. (g) J.F. Harrod, S.S. Yun, Organometallics 6 (1987) 1381. For Group 3 complexes, see: (h) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (i) G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570. (j) G.A. Molander, P.J. Nichols, B.C. Noll, J. Org. Chem. 63 (1998) 2292. (k) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. For organolanthanides in hydrosilylation, see: Ref. [6] and: (l) H. Schumann, M.R. Keitsch, J. Winterfeld, S. Muhle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181. (m) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (n) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (o) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754. (p) S. Onozawa, T. Sakakura, M. Tanaka, Tetrahedron Lett. 35 (1994) 8177. For actinides see: (q) A.K. Dash, J.Q.Wang, M.S. Eisen, Organometallics 18 (1999) 4724.
103. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman, R.M. Waymouth, J. Organomet. Chem. 417 (1991) C12. (f) J.Y. Corey, X.H. Zhu, Organometallics 11 (1992) 672. (g) J.F. Harrod, S.S. Yun, Organometallics 6 (1987) 1381. For Group 3 complexes, see: (h) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (i) G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570. (j) G.A. Molander, P.J. Nichols, B.C. Noll, J. Org. Chem. 63 (1998) 2292. (k) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. For organolanthanides in hydrosilylation, see: Ref. [6] and: (l) H. Schumann, M.R. Keitsch, J. Winterfeld, S. Muhle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181. (m) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (n) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (o) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754. (p) S. Onozawa, T. Sakakura, M. Tanaka, Tetrahedron Lett. 35 (1994) 8177. For actinides see: (q) A.K. Dash, J.Q.Wang, M.S. Eisen, Organometallics 18 (1999) 4724.
104. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman, R.M. Waymouth, J. Organomet. Chem. 417 (1991) C12. (f) J.Y. Corey, X.H. Zhu, Organometallics 11 (1992) 672. (g) J.F. Harrod, S.S. Yun, Organometallics 6 (1987) 1381. For Group 3 complexes, see: (h) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (i) G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570. (j) G.A. Molander, P.J. Nichols, B.C. Noll, J. Org. Chem. 63 (1998) 2292. (k) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. For organolanthanides in hydrosilylation, see: Ref. [6] and: (l) H. Schumann, M.R. Keitsch, J. Winterfeld, S. Muhle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181. (m) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (n) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (o) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754. (p) S. Onozawa, T. Sakakura, M. Tanaka, Tetrahedron Lett. 35 (1994) 8177. For actinides see: (q) A.K. Dash, J.Q.Wang, M.S. Eisen, Organometallics 18 (1999) 4724.
105. For Group 4 complexes, see: (a) M.S. Eisen, in: Y. Apeloig, Z. Rappoport (Eds.), The Chemistry of Organosilicon Compounds Part 3, vol. 2, Wiley, Chichester, 1998, pp. 2038-2122 (Chapter 35). (b) M.S. Eisen, Rev. Inorg. Chem. 17 (1997) 25. (c) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8564. (d) M.R. Kesti, R.M. Waymouth, Organometallics 11 (1992) 1095. (e) M.R. Kesti, M. Abdulrahman, R.M. Waymouth, J. Organomet. Chem. 417 (1991) C12. (f) J.Y. Corey, X.H. Zhu, Organometallics 11 (1992) 672. (g) J.F. Harrod, S.S. Yun, Organometallics 6 (1987) 1381. For Group 3 complexes, see: (h) G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347. (i) G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570. (j) G.A. Molander, P.J. Nichols, B.C. Noll, J. Org. Chem. 63 (1998) 2292. (k) G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415. For organolanthanides in hydrosilylation, see: Ref. [6] and: (l) H. Schumann, M.R. Keitsch, J. Winterfeld, S. Muhle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181. (m) T. Sakakura, H. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40. (n) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C.J. Rousset, P.E. Fanwick, E.J. Negishi, J. Am. Chem. Soc. 113 (1991) 8664. (o) G.A. Molander, E.D. Dowdy, B.C. Noll, Organometallics 17 (1998) 3754. (p) S. Onozawa, T. Sakakura, M. Tanaka, Tetrahedron Lett. 35 (1994) 8177. For actinides see: (q) A.K. Dash, J.Q.Wang, M.S. Eisen, Organometallics 18 (1999) 4724.
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138. The addition of external amine to the reaction mixture containing MeCCD allows the formation of the geminal dimer [1f] together with the scrambled H/D gem-dimer corroborating the slow equilibrium exchanging the amido and the acetylide protons
139. 2 replace all the three ethylamine groups.
140. In the proposed catalytic cycle, an intermediate (reactive isomer of B could also appear between A and C, which is at a steady state, before the insertion of the second alkyne.
141. 2) were observed.
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