Stable Rh2(MTPA)4 phosphane adducts - The first example of P-chirality recognition by 103Rh NMR spectroscopy

European Journal of Inorganic Chemistry

Volumn , Issue 12, 2002, Pages 3253-3257

  Magiera, Damian ^a   Baumann, Wolfgang ^b   Podkorytov, Ivan S ^c   Omelanczuk, Jan ^d   Duddeck, Helmut ^a  

^a LEIBNIZ UNIVERSITY HANNOVER   (Germany)

^b UNIVERSITY OF ROSTOCK   (Germany)

^c SVL Ctrl Synt Rub Res Inst   (Russian Federation)

^d CENTRE OF MOLECULAR AND MACROMOLECULAR STUDIES   (Poland)

Author keywords

Chiral discrimination; Chirality; NMR spectroscopy; Phosphanes; Rhodium

Indexed keywords

CHIRALITY; RHODIUM; RHODIUM COMPOUNDS;

CHIRAL DISCRIMINATION; LATTER COMPLEXES; NMR-SPECTROSCOPY; OPTIMAL PARAMETER; P-CHIRALITY; PHOSPHANES; SPIN SYSTEMS; SPIN-S SYSTEMS;

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

PHOSPHORUS DERIVATIVE;

ANALYTIC METHOD; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHIRALITY; DIASTEREOISOMER; MOLECULAR RECOGNITION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE; RHODIUM 103 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SOLUBILITY;

EID: 0036898383     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200212)2002:12<3253::AID-EJIC3253>3.0.CO;2-I     Document Type: Article

References (38)

1. [1a] K. Wypchlo, H. Duddeck, Tetrahedron: Asymmetry 1994, 5, 27.
2. [1b] K. Wypchlo, H. Duddeck, Chirality 1997, 9, 601.
3. [1c] S. Hameed, R. Ahmad, H. Duddeck, Heteroatom Chem. 1998, 9, 471.
4. [1d] S. Hameed, R. Ahmad, H. Duddeck, Magn. Reson. Chem. 1998, 36, S47.
5. [1e] C. Meyer, H. Duddeck, Magn. Reson. Chem. 2000, 38, 29;
6. see also: C. Meyer, PhD thesis, Hannover University, 1999.
7. 31P NMR spectroscopy using a mononuclear bdpp-containing rhodium complex: J. M. Buriak, J. A. Osborn, J. Chem. Soc., Chem. Commun. 1995, 689.
8. [3a] G. R. Sullivan, Top. Stereochem. 1978, 10, 287.
9. [3b] P. L. Rinaldi, Progr. N M R Spectrosc. 1983, 15, 291.
10. [3c] D. Parker, Chem. Rev. 1991, 91, 1441.
11. C. Brevard, P. Granger, Handbook of High Resolution Multinuclear N M R, John Wiley & Sons, Toronto 1981, p. 158.
12. B. E. Mann, in Transition Metal Nuclear Magnetic Resonance (Ed.: P. S. Pregosin), Elsevier Science Publishers, Amsterdam 1991, p. 177ff.
13. W. V. Philipsborn, Chem. Soc. Rev. 1999, 28, 95.
14. E. B. Boyar, S. D. Robinson, Inorg. Chim. Acta 1982, 64, L193.
15. S. Rockitt, H. Duddeck, J. Omelanczuk, Chirality 2001, 13, 214.
16. Some examples: [9a] C. Brevard, R. Schimpf, J. Magn. Reson. 1982, 47, 528.
17. [9b] C. J. Elsevier, J. M. Ernsting, W. G. J. de Lange, J. Chem. Soc., Chem. Commun. 1989, 585.
18. [9c] J. M. Ernsting, C. J. Elsevier, W. G. J. de Lange, K. Timmer, Magn. Reson. Chem. 1991, 29, S118.
19. [9d] C. J. Elsevier, B. Kowall, H. Kragten, Inorg. Chem. 1995, 34, 4836.
20. [9e] L. Carlton, Magn. Reson. Chem. 1997, 35, 153.
21. [9f] K. Angermund, W. Baumann, E. Dinjus, R. Fornika, H. Görls, M. Kessler, C. Krüger, W. Leitner, F. Lutz, Chem. Eur. J. 1997, 3, 755.
22. [9g] N. Feiken, P. Pregosin, G. Trabesinger, Organometallics 1998, 17, 4510.
23. [9h] J. G. Donkervoort, M. Bühl, J. M. Ernsting, C. J. Elsevier, Eur. J. Inorg. Chem. 1999, 27.
24. [9i] M. Bühl, W. Baumann, R. Kadyrov, A. Börner, Helv. Chim. Acta 1999, 82, 811.
25. [9j] W. Leitner, M. Bühl, R. Fornika, C. Six, W. Baumann, E. Dinjus, M. Kessler, C. Krüger, A. Rufińska, Organometallics 1999, 18, 1196.
26. [10a] D. Nanz, W. von Philipsborn, J. Magn. Reson. 1991, 92, 560.
27. [10b] H. Rüegger, D. Moskau, Magn. Reson. Chem. 1991, 29, S11.
28. B. T. Heaton, J. A. Iggo, I. S. Podkorytov, D. J. Smawfield, S. P. Tunik, R. Whyman, J. Chem. Soc., Dalton Trans. 1999, 1917.
29. T. Ohkuma, R. Noyori, Chemtracts: Org. Chem. 1993, 6, 325.
30. B. R. Bender, M. Koller, D. Nanz, W. von Philipsborn, J. Am. Chem. Soc. 1993, 115, 5889.
31. G. Ewart, D. S. Payne, A. L. Porte, A. P. Lane (in part), J. Chem. Soc. 1962, 3984.
32. N. A. Andreev, O. N. Grishina, Zh. Obshch. Khim. 1979, 49, 2230, engl. Transl. 1959.
33. H. Nöth, H.-J. Vetter, Chem. Ber. 1963, 96, 1109.
34. A. Bax, R. H. Griffey, B. L. Hawkins, J. Magn. Reson. 1983, 55, 301.
35. [18a] R. Benn, C. Brevard, J. Am. Chem. Soc. 1986, 108, 5622.
36. [18b] R. Benn, A. Rufińska, Magn. Reson. Chem. 1988, 26, 895.
37. [19a] R. G. Kidd, R. J. Goodfellow, in N M R and the Periodic Table (Eds.: R. K. Harris, B. E. Mann), Academic Press, London 1978, Chap. 8.
38. [19b] R. J. Goodfellow, in Multinuclear N M R (Ed.: J. Mason), Plenum Press, New York 1987, chapter 20.