Chiral recognition of epoxides by 1H NMR spectroscopy in the presence of a chiral dirhodium complex

Chirality

Volumn 9, Issue 5-6, 1997, Pages 601-603

  Wypchlo, Klaudia ^a   Duddeck, Helmut ^a  

^a LEIBNIZ UNIVERSITY HANNOVER   (Germany)

Author keywords

1H NMR; Chiral recognition; Epoxides; Mosher's acid

Indexed keywords

EPOXIDE; ETHYLENE OXIDE; LANTHANIDE; PHENYLACETIC ACID DERIVATIVE; REAGENT; RHODIUM DERIVATIVE;

ANALYTIC METHOD; ARTICLE; CHIRALITY; INTERMETHOD COMPARISON; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE;

EID: 0030883543     PISSN: 08990042     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1520-636X(1997)9:5/6<601::AID-CHIR30>3.0.CO;2-Q     Document Type: Article

References (9)

1. 1H NMR spectroscopy in the presence of a chiral dirhodium complex. Tetrahedron:Asymmetry 5:27-30, 1994.
2. 13C NMR. Org. Magn. Reson. 22:355-363, 1984, and references cited therein.
3. (a) Kainosho, M., Ajisaka, K., Pirkle, W.H., Beare, S.D. The use of chiral solvents or lanthanide shift reagents to distinguish meso from d or l diastereomers. J. Am. Chem. Soc. 94:5924-5926, 1972;
4. (b) Colonna, S., Fornasier, R., Pfeiffer, U. Asymmetric induction in the darzens reaction by means of chiral phase-transfer in a two-phase system. The effect of binding the catalyst to a solid polymeric support. J. Chem. Soc., Perkin Trans. 1:8-11, 1978;
5. (c) Pluim, H., Wynberg, H. Catalytic asymmetric induction in oxidation reactions. Synthesis of optically active epoxynaphthoquinones. J. Org. Chem. 45:2498-2502, 1980.
6. Brandes, A. Ph.D. thesis. Universität Hannover, Germany, 1994.
7. Minkner, D. Ph.D. thesis. Ruhr-Universität Bochum, Germany, 1994.
8. 4]. Tetrahedron:Asymmetry 1:221-236, 1990.
9. Duddeck, H., Ahmad, R., Hameed, S., in preparation.